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材料导报  2023, Vol. 37 Issue (13): 21110021-5    https://doi.org/10.11896/cldb.21110021
  金属与金属基复合材料 |
TiCNp增强高铬铸铁复合材料的制备与性能
赵吉康, 肖平安*, 顾景洪, 钟斯远
湖南大学材料科学与工程学院,长沙 410082
Preparation and Properties of TiCNp Reinforced High Chromium Cast Iron Composites
ZHAO Jikang, XIAO Ping'an*, GU Jinghong, ZHONG Siyuan
School of Materials Science and Engineering, Hunan University, Changsha 410082, China
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摘要 本工作以TiCNp和20Cr高铬铸铁粉末为原料,采用压制和超固相液相烧结(SLPS)工艺,制备含10%~30%(质量分数,下同)TiCNp的高铬铸铁复合材料,系统研究了增强相含量和烧结温度对复合材料致密化行为、显微组织、物相组成和力学性能的影响规律。研究结果表明,通过真空液相烧结可以制备出相对致密度均达到97.5%以上的各成分复合材料,物相主要由TiCN、Cr7C3碳化物、马氏体和少量奥氏体组成;随着增强相添加量逐步增加,TiCNp沿晶界分布,逐渐形成网状分布结构,而Cr7C3越来越多地在烧结过程中没有熔化的合金基体中析出和粗化;这使得复合材料的硬度线性上升,而抗弯强度和冲击韧性则降低。当TiCNp添加量为30%时复合材料的力学性能可以达到硬度87.8HRA,抗弯强度1 304 MPa,冲击韧性2.35 J/cm2
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赵吉康
肖平安
顾景洪
钟斯远
关键词:  复合材料  TiCNp  PM高铬铸铁  力学性能  显微组织    
Abstract: Taking TiCNp and 20Cr high chromium cast iron powder as raw materials, reinforced high chromium cast iron with 10wt%—30wt% TiCNp in this work was fabricated by supersolidus liquid phase sintering (SLPS) method. The influence of TiCNp addition amount and sintering temperature on its densification, constituent phase, microstructure and mechanical properties have been investigated systematically. The results show that the relative density of the TiCNp sintered through SLPS technique could reach to 97.5%, and it's phase composition containing TiCN, Cr7C3 carbides, martensite and a small amount of austenite. Besides, with the increment of TiCNp addition amount, TiCNp gradually forming a net distribution along the grain boundary. Meanwhile, more and more Cr7C3 carbides were precipitated and coarsened in the unmelted alloy matrix, which could lead to the linearly increment of the hardness of the TiCNP but decreases their bending strength and impact toughness. And in general it is worth noting that the sintered composite with 30wt% TiCNp has great mechanical properties with hardness of 87.8HRA, bending strength of 1 304 MPa and impact toughness of 2.35 J/cm2.
Key words:  composite    TiCNp    PM high chromium cast iron    mechanical property    microstructure
发布日期:  2023-07-10
ZTFLH:  TB331  
基金资助: 国家自然科学基金(51574449)
通讯作者:  *肖平安,湖南大学材料科学与工程学院教授、博士研究生导师。2003年博士毕业于中南大学粉末冶金专业,2005年至今在湖南大学材料科学与工程学院工作。目前主要从事先进粉末冶金材料制备技术研究、高性能粉末冶金铁基耐磨材料和钢结硬质合金等方面的研究工作。发表论文80余篇,先后主持国家自然科学基金、湖南省科技计划项目、湖南省自然科学基金及多个横向科研项目。changcluj@163.com   
作者简介:  赵吉康,湖南大学材料科学与工程学院材料工程专业硕士研究生。在肖平安老师的指导下进行研究,目前主要的研究方向为铁基耐磨材料。
引用本文:    
赵吉康, 肖平安, 顾景洪, 钟斯远. TiCNp增强高铬铸铁复合材料的制备与性能[J]. 材料导报, 2023, 37(13): 21110021-5.
ZHAO Jikang, XIAO Ping'an, GU Jinghong, ZHONG Siyuan. Preparation and Properties of TiCNp Reinforced High Chromium Cast Iron Composites. Materials Reports, 2023, 37(13): 21110021-5.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21110021  或          http://www.mater-rep.com/CN/Y2023/V37/I13/21110021
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