MATERIALS AND SUSTAINABLE DEVELOPMENT: ADVANCED MATERIALS FOR CLEAN ENERGY UTILIZATION |
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Construction of Nano-Au@PANI Yolk-shell Hollow Structure Electrode Material and Its Electrochemical Performance |
Yongtao TAN1,2( ),Lingbin KONG1,2,Long KANG1,2,Fen RAN1,2
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1 College of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050 2 State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050 |
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Abstract The nano-Au@PANI was prepared via a two-step method of oxidative polymerization by controlling the diffusion of oxidizing agents. The morphology of nano-Au@PANI was characterized by TEM, and the performances of supercapacitor were measured by electrochemical work-station (CHI660E). Furthermore, the relationship of reaction time and the performances of supercapacitor were also studied. The results showed that the nano-Au@PANI composites possessed yolk-shell structure, and with extension of reaction time the specific capacitance first increased and then decreased. When the reaction time was 12 h, the shell thickness of PANI was about 21 nm, the specific capacitance was up to 79 F·g -1.
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Published: 10 January 2018
Online: 2018-01-10
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Symmetric mechanism of Nano-Au@PANI yolk-shell structure
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TEM photos of (a)Nano-Au, (b)Nano-Au@PANI-6,(c)Nano-Au@PANI-12, (d)Nano-Au@PANI-36 and (e)Nano-Au@PANI-48
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Electrochemical performance of (a, b) Nano-Au@PANI-6, (c, d) Nano-Au@PANI-12, (e, f) Nano-Au@PANI-24,(g, h) Nano-Au@PANI-36, (i, j) Nano-Au@PANI-48; (k) CV curves of Nano-Au@PANI at different time (scan rate: 5 mV·s-1) and (h)Nyquist plots
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Specific capacitances of composites at different current density
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