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材料导报  2020, Vol. 34 Issue (Z1): 13-18    
  无机非金属及其复合材料 |
电荷传输层和热退火对钙钛矿薄膜电学性能的影响
左文韬, 樊正方, 刘国强, 刘江, 廖成
中国工程物理研究院成都科学技术发展中心,成都 610000
Effects of the Charge Transport Layers and Thermal Annealing on the ElectricalProperties of Perovskite Films
ZUO Wentao, FAN Zhengfang, LIU Guoqiang, LIU Jiang, LIAO Cheng
Chengdu Science and Technology Development Center, China Academy of Engineering Physics, Chengdu 610000, China
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摘要 有机-无机杂化钙钛矿(PVK)薄膜材料因具有较高的消光系数、较高的载流子迁移率、较低的激子束缚能、可控的禁带宽度等优势,近年来成为光伏研究的热点。钙钛矿太阳能电池器件结构简单、制备工艺高效、材料成本低廉,有望在未来取代传统硅电池。电荷传输层是钙钛矿太阳能电池的重要组成部分,本工作详细研究了不同底层电荷传输层对钙钛矿薄膜的表面电势、载流子复合寿命及电池性能的影响。扫描开尔文探针显微镜(SKPM)结果表明,底层电荷传输材料的导电类型会显著改变钙钛矿薄膜的表面电势,这一结果证实了钙钛矿薄膜的弱掺杂属性。当钙钛矿薄膜沉积在电子传输层衬底上时,薄膜表面电势高、功函数小,可能呈n型;反之,当薄膜沉积在空穴传输层衬底上时,薄膜表面电势低、功函数大,呈p型。进一步分析基于不同电荷传输层的钙钛矿薄膜的性能,发现表面光电压与电荷传输层性能之间存在一定联系。同时,进一步研究了钙钛矿薄膜的热稳定性与表面光电压之间的联系,发现表面光电压的变化能在一定程度上反映薄膜的热稳定性,并得出溴离子(Br-)、甲基氯化胺(MACl)和铯离子(Cs+)对钙钛矿薄膜的热稳定性具有一定提升作用。
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左文韬
樊正方
刘国强
刘江
廖成
关键词:  电荷传输层  钙钛矿  表面电势  表面光电压  热稳定性    
Abstract: Organic-inorganic hybrid perovskite (PVK) solar cells have become a promising candidate in the photovoltaic field due to their high extinction coefficient, high carrier mobility, low exciton binding energy and tunable band gap, etc. Perovskite solar cell devices have the advantages of simple structure, efficient fabrication process and low material cost, which are expected to replace traditional silicon cells in the future. The charge transport layer is a key part of perovskite solar cells. In this work, the effects of different underlying charge transport layers on the surface potential, carrier recombination and photovoltaic performance of perovskite films were investigated in detail. Scanning Kelvin probe microscopy (SKPM) results show that the conductivity type of the underlying charge transport materials an obviously change the surface potential of the perovskite films. This result confirms that perovskite film is a weak doped semiconductor films. When deposited on electron transport layer coated substrate, the perovskite film display a high surface potential and small work function, and exhibits n-type conductivity. On the contrary, when deposited on hole transport layer coated substrate, the film has a low surface potential and large work function. Based on the analysis of the properties of perovskite films on different charge transfer layers, an obvious relationship between surface photovoltage and the performance of charge transport layer can be ascertained. Moreover, we researched the correlation between the thermal stability of the perovskite film and their surface photovol-tage, and concluded that the change of surface photovoltage could partly reflect the thermal stability of thin film. It is concluded that bromide ion (Br-), methylammonium chloride (MACl) and cesium ions (Cs+) could improve thermal stability for perovskite films.
Key words:  charge transport layer    perovskite    surface photovoltage    thermal stability
                    发布日期:  2020-07-01
ZTFLH:  O469  
基金资助: 国家自然科学基金(11704425)
作者简介:  左文韬,中国工程物理研究院硕士在读研究生。主要研究方向为钙钛矿薄膜与器件。2013年9月至2017年6月,在兰州大学获得物理学学士学位,2017年9月起于中国工程物理研究院凝聚态物理专业学习;刘江,清华大学工学博士,现为中国工程物理研究院副研究员。从事薄膜光伏研究十年。博士期间主要开展CIGS薄膜的产业化应用技术研究,近年来主要从事钙钛矿薄膜的制备与光伏应用、新型光电器件与物理等研究工作,目前已发表SCI论文20余篇。
引用本文:    
左文韬, 樊正方, 刘国强, 刘江, 廖成. 电荷传输层和热退火对钙钛矿薄膜电学性能的影响[J]. 材料导报, 2020, 34(Z1): 13-18.
ZUO Wentao, FAN Zhengfang, LIU Guoqiang, LIU Jiang, LIAO Cheng. Effects of the Charge Transport Layers and Thermal Annealing on the ElectricalProperties of Perovskite Films. Materials Reports, 2020, 34(Z1): 13-18.
链接本文:  
http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2020/V34/IZ1/13
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