聚吡咯电极材料在超级电容器中的研究进展

doi:10.11896/j.issn.1005-023X.2018.03.006

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Abstract

Polypyrrole is one of conductive polymers with the best conductive stability. Because of its simple preparation, environmental friendliness, high conductivity, high conductivity and unique doping, the preparation of polypyrrole composites in order to improve the stability is becoming a hot spot in the research field of conductive polymer-based supercapacitors electrode materials. Polypyrrole electrode materials and binary, ternary composite electrode materials with the carbon materials or metal oxide materials used in the research development of supercapacitors in recent years are reviewed. The charge storage mechanism, polypyrrole polymerization mechanism and preparation methods are introduced. Meanwhile, this paper prospected the current hot research fields and development prospect of the polypyrrole and its composite electrode materials.

Key words： supercapacitors polypyrrole electrode material

Published: 10 February 2018

CLC number:

TM912

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	Articles by authors
	Miaomiao ZHANG
	Xuyan LIU
	Wei QIAN

Cite this article:

Miaomiao ZHANG,Xuyan LIU,Wei QIAN. Research Development of Polypyrrole Electrode Materials in Supercapacitors[J]. Materials Reports, 2018, 32(3): 378-383.

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http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2018.03.006 OR http://www.mater-rep.com/EN/Y2018/V32/I3/378

The molecular structure of PPy

The conduction mechanism of PPy

The mechanism of PPy synthesis:(a) formation of free radicals cation, (b) cation radicals combination and elimination of two protons, (c) formation of free radicals dication, (d,e) growth of the chain

Schematic illustration of the formation of PPy nanotube embedded nanopore array

The process of synthesis of PPy/MWNTs composite materials with PPy coating on carbon nanotubes

Schematic illustration of synthesis process of the PPy-RGO-fabric composite materials

(a) Charge-discharge curves and (b) cyclic voltammetry curves of PPy/HCA

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