纳米有机杂化材料(NOHMs)用于CO2捕集的研究进展

doi:10.11896/cldb.21120114

材料导报

2023, Vol. 37

Issue (16): 21120114-11 https://doi.org/10.11896/cldb.21120114

高分子与聚合物基复合材料

纳米有机杂化材料(NOHMs)用于CO₂捕集的研究进展

邱汉宇, 刘红晶^*, 姚辉, 刘雪莉, 高洁

沈阳工业大学石油化工学院,辽宁辽阳111003

Research Progress of Nano Organic Hybrid Materials (NOHMs) for CO₂ Capture

QIU Hanyu, LIU Hongjing^*, YAO Hui, LIU Xueli, GAO Jie

School of Petrochemical Engineering, Shenyang University of Technology, Liaoyang 111003, Liaoning, China

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摘要近年来,纳米有机杂化材料(NOHMs)引起了广泛的研究。不同于捕集CO₂的传统胺基溶剂,NOHMs可以在不含任何溶剂的条件下保持类液性,具有可忽略蒸汽压和高热稳定性的特点,因此可以减少溶剂挥发带来的损失以及环保问题,同时减少了对设备的腐蚀,是一种有潜力的替代传统胺基溶剂的吸收剂。同时NOHMs可直接作为吸附剂吸附CO₂,也可作为添加剂和其他材料产生协同作用,比如作为分离膜中的掺杂剂加入到聚合物基质中制备混合基质膜,可以显著强化CO₂在膜内的传质速率,实现CO₂的高效捕集。本文概括了NOHMs在碳捕集领域的研究进展,分别针对共价键和离子键连接的两类NOHMs阐述其核心、内冠、外冠三部分对CO₂吸附性能的影响,探讨和归纳了核心的尺寸、孔隙率、含量以及冠层的密度、链长和结构等对NOHMs碳捕集能力的影响机制,总结了以上因素与焓效应和熵效应的对应关系,以及对碳捕集性能的作用。本文将为拓宽NOHMs在CO₂捕集领域的应用提供参考与新的研究思路。

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	邱汉宇
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关键词: 纳米有机杂化材料 CO₂捕集核壳结构焓效应熵效应

Abstract: In recent years, nano organic hybrid materials (NOHMs) have attracted widespread attention. Different from the traditional amine based solvents that capture CO₂, NOHMs can maintain liquid like properties without any solvent, with negligible vapor pressure and high thermal stability. Therefore, it is a potential substitute for traditional amine absorption because the loss caused by solvent volatilization and environmental protection problems can be reduced, and the corrosion of equipment can be avoided. At the same time, NOHMs not only are used as absorbents to absorb CO₂ directly,andbut also play a more significant role in CO₂ capture as an additive. For example, as a kind of dopant in membrane separation methods, it will play a significant role in enhancing mass transfer in CO₂ capture. This paper outlines the research progress of NOHMs in the field of carbon capture, and describes the effects of their core, corona and canopy on the CO₂ adsorption performance for two types of NOHMs connected by covalent and ionic bonds, respectively. The effects of core size, porosity, content and canopy density, chain length and structure on the capture of CO₂ by NOHMs have been discussed, and the role of enthalpy effect and entropy effect on carbon capture performance has also been summarized. The paper is expected to provide new insights and ideas in broadending applications of NOHMs in the field of CO₂ capture.

Key words: nano organic hybrid materials (NOHMs) CO₂ capture core-shell structure enthalpy effect entropy effect

出版日期: 2023-08-25 发布日期: 2023-08-14

ZTFLH:

TQ028.8

基金资助: 辽宁省自然科学基金(20170540685;2014020117);辽宁百千万人才项目;辽宁省教育厅重点攻关项目(LZGD2019004)

通讯作者: ^*刘红晶,工学博士,沈阳工业大学教授、博士研究生导师。研究方向为膜分离,主要研究膜的制备和膜应用,尤其是膜技术在碳捕集领域的应用。在国内外科技期刊公开发表论文40余篇,被SCI、EI检索20余篇。liuhongjing_101@126.com

作者简介: 邱汉宇,2019 年 9月于太原工业学院获得工学学士学位。现为沈阳工业大学石油化工学院硕士研究生,在刘红晶教授的指导下进行研究。目前主要研究领域为CO₂的捕集与利用。

引用本文:

邱汉宇, 刘红晶, 姚辉, 刘雪莉, 高洁. 纳米有机杂化材料(NOHMs)用于CO₂捕集的研究进展[J]. 材料导报, 2023, 37(16): 21120114-11.
QIU Hanyu, LIU Hongjing, YAO Hui, LIU Xueli, GAO Jie. Research Progress of Nano Organic Hybrid Materials (NOHMs) for CO₂ Capture. Materials Reports, 2023, 37(16): 21120114-11.

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http://www.mater-rep.com/CN/10.11896/cldb.21120114 或 http://www.mater-rep.com/CN/Y2023/V37/I16/21120114

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