多孔非晶合金及其复合材料的制备技术研究进展

doi:10.11896/j.issn.1005-023X.2018.03.019

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Abstract

Porous amorphous alloy is an emerging structural and/or functional material combined the both advantages of metallic foams and glassy alloys, which has reflected the light-weight, high-strength, and large-toughness are unified. Recently,porous amorphous alloys and their composites have exert tremendous fascination on researchers at home and abroad because of their excellent physical and chemical properties,such as high strength, low elastic modulus,high elastic strains,high corrosion resistance, and so on. In this paper,the research progress of porous amorphous alloys and their composites have been summarized.

Key words： porous amorphous alloys melt infiltration amorphous powder powder sintering dealloying supercooled li-quid region

Published: 10 February 2018 Online: 2018-02-10

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TG14

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	Zhengrong FU
	Xiuchang WANG
	Qinglin JIN
	Jun TAN

Cite this article:

Zhengrong FU,Xiuchang WANG,Qinglin JIN, et al. A Review of the Preparation Techniques for Porous Amorphous Alloys and Their Composites[J]. Materials Reports, 2018, 32(3): 473-482.

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https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2018.03.019 OR https://www.mater-rep.com/EN/Y2018/V32/I3/473

Ingredient	Porosity/%	Aperture/μm	E/GPa	σ/MPa	ε/%	Year	Reference
Pd₄₃Ni₁₀Cu₂₇P₂₀	84	100—1 000				2003	[11]
Pd_42.5Cu₃₀Ni_7.5P₂₀	65	125—250	5.2	75	1.8	2003	[12]
Zr₅₇Nb₅Cu_15.4Ni_12.6Al₁₀	60	25—50				2004	[26]
Pd₃₅Pt₁₅Cu₃₀P₂₀	45	200	27	400	>30	2005	[15]
Ti₃₆Y₂₀Al₂₄Co₂₀		0.015—0.155				2006	[45]
Ni₅₉Zr₂₀Ti₁₆Si₂Sn₃	40	10—50		350	3.25	2006	[49]
Cu₄₇Ti₃₃Zr₁₁Ni₈Si₁	25	0.02—0.5				2006	[52]
Zr₅₅Cu₃₀Al₁₀Ni₅	33.5		16	93	>3	2006	[30]
Zr₄₇Ti₁₃Cu₁₁Ni₁₀Be₁₆Nb₃	80	150-200		820	1.3	2007	[31]
Fe₄₈Cr₁₅Mo₁₄Y₂C₁₅B₆	65					2007	[53]
Zr₅₇Nb₅Al₁₀Ni_12.6Cu_15.4	60.4	50	17	180	>16	2007	[33]
Mg₆₀Cu₂₁Ag₇Gd₁₂	57.5	2 000	8.5	109	90	2007	[56]
Zr₄₈Cu₃₆Al₈Ag₈	13		71	1 390	0.02	2008	[34]
Zr_58.5Nb_2.8Cu_15.6Ni_12.8Al_10.3	60	45—106		62	70	2009	[25]
Hf_44.5Cu₂₇Ni_13.5Ti₅Al₁₀	62	45—106			80	2012	[57]
Zr_41.25Ti_13.75Cu_12.5Ni₁₀Be_22.5	65			30	0.29	2012	[37]
Pd₄₀Cu₃₀Ni₁₀P₂₀		20—550				2012	[22]
Zr_56.3Nb_5.1Cu_15.6Ni_12.9Al₁₀	70	45-106				2013	[39]
Zr₃₅Ti₃₀Be_26.75Cu_8.25		20—550				2013	[44]
Ti₄₅Zr₁₀Cu₃₁Pd₁₀Sn₄	60	125—250				2014	[46]
Ti₄₂Zr₄₀Ta₃Si₁₅	14		337	52	0.67	2016	[47]
Fe₈₂Nb₆B₁₂	23—38	0.12				2017	[55]

The first reported year,pore structure parameters and mechanical properties of various amorphous alloy foams and their composites

The process of porous amorphous alloys prepared by melting with foaming agent

The process of porous amorphous alloys prepared by gas injection

The process of porous amorphous alloys prepared by infiltration casting method with easily soluble particle

The process of porous amorphous alloys prepared by powder sintering

SEM images of porous Zr₅₅Cu₃₀Al₁₀Ni₅ bulk metallic glasses with porosity of 70%^[32]:(a) the as-produced foam synthesized by hot pressing;(b) the cellular structure of the as-produced foam;(c) magnified view of the inner wall of the foam (the arrows representing bonding region between particles)

The compressive stress-strain curve of an 86% porosity foam deformed toward full densification^[17]

SEM micrographs of the transverse cross section of the sintered porous Zr₅₅Cu₃₀Al₁₀Ni₅ bulk glassy alloys with porosities of (a) 4.7% and (b) 33.5%^[30]

SEM images of porous Cu₄₇Ti₃₃Zr₁₁Ni₈Si₁ metallic glass with porosity of 25%^[52]:(a) transverse polished cross section of precursor before dissolution of the Cu;(b) macrostructure of porous metallic glass;(c) transverse cross-sectional microstructure metallic glass; (d) enlarged image of (c)

Uniaxial compressive stress-strain curves of Zr_58.5Nb_2.8Cu_15.6Ni_12.8Al_10.3 foam^[25]:(a)porosities of 57% and 64% from Vit/Cu;(b)porosities of 57% and 59% from Vit/Ni;(c)porosities of 59.5% and 63% from Vit/W

The process of porous amorphous alloys prepared by dealloying

The process of porous amorphous alloys prepared by processing in supercooled liquid region

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