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材料导报  2023, Vol. 37 Issue (16): 22010110-12    https://doi.org/10.11896/cldb.22010110
  无机非金属及其复合材料 |
磷石膏材料化综合利用研究进展
张峻1,2, 解维闵1,2, 董雄波3,4,5, 杨华明1,2,3,4,5,*
1 中南大学资源加工与生物工程学院, 长沙 410083
2 中南大学矿物材料及其应用湖南省重点实验室, 长沙 410083
3 中国地质大学(武汉)纳米矿物材料及应用教育部工程研究中心, 武汉 430074
4 中国地质大学(武汉)材料与化学学院, 武汉 430074
5 中国地质大学(武汉)中国非金属矿行业矿物功能材料重点实验室, 武汉 430074
Research Progress on Comprehensive Utilization of Phosphogypsum for Materials: a Review
ZHANG Jun1,2, XIE Weimin1,2, DONG Xiongbo3,4,5, YANG Huaming1,2,3,4,5,*
1 School of Minerals Processing and Bioengineering, Central South University, Changsha 410083,China
2 Key Laboratory for Mineral Materials and Application of Hunan Province, Central South University, Changsha 410083, China
3 Engineering Research Center of Nano-Geomaterials of Ministry of Education, China University of Geosciences, Wuhan 430074, China
4 Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China
5 Key Laboratory of Functional Geomaterials in China Nonmetallic Minerals Industry, China University of Geosciences, Wuhan 430074, China
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摘要 磷石膏是湿法磷酸浸出工艺中产生的固体废弃物,其主要成分为二水硫酸钙,具有产量大、组分复杂等特征。目前,国内磷石膏存量高达6亿t,其大量堆放造成土地资源浪费、江河水质劣化及大气污染等生态环境问题。然而,我国磷石膏综合利用率较低,其主要用于生产附加值较低的建筑材料,对此,加快推进磷石膏新技术、新产品的研发具有重要意义。本文通过分析磷石膏综合利用研究现状,总结了磷石膏在建筑、稀土提取、农业、化工以及生物医疗行业领域的研究进展,提出了现阶段磷石膏综合利用研究及产业化应用中的问题,展望了未来磷石膏高值化加工基础理论及技术研究的发展趋势,以期为磷石膏大宗化、高值化利用研究基础及产业化应用提供参考。
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张峻
解维闵
董雄波
杨华明
关键词:  磷石膏  材料化  除杂  高值化综合利用    
Abstract: Phosphogypsum is a solid-waste byproduct of the wet-acid process used for producing phosphoric acid. Its main component is calcium sulfate dihydrate, characterized by its high yield and complexity. At present, with stocks of phosphogypsum in China reaching 600 million tons, the massive piling up has led to waste of land resources, deterioration of river water quality, air pollution, and other ecological and environmental problems. However, the comprehensive utilization of phosphogypsum is quite low in China, where it is primarily used to produce low-value-added construction materials. Thus, the research and development of new phosphogypsum-based technologies and products must be accelerated. This paper summarizes the progress of phosphogypsum research in the fields of construction, rare earth extraction, agriculture, chemical industry, and biomedical industry. This was done by analyzing the status quo of studies on comprehensive phosphogypsum utilization and its industrial applications,highlighting issues in the current stage of studies, revealing insights into future developments, and providing a reference for theoretical and technological research on the bulk and high-value utilization of phosphogypsum and its industrial applications.
Key words:  phosphogypsum    materialization    impurity removal    high-value utilization
出版日期:  2023-08-25      发布日期:  2023-08-14
ZTFLH:  TD989  
基金资助: 国家重点研发计划 (2017YFB0310903);中南大学研究生自主探索创新项目(2020zzts728; 2022zzts565)
通讯作者:  *杨华明,工学博士,中南大学、中国地质大学(武汉)教授、博士生导师,中组部国家“万人计划”领军人才、国家杰出青年科学基金获得者、科技部中青年科技创新领军人才。在中南工业大学获博士学位,先后在英国布里斯托大学和澳大利亚昆士兰大学任访问学者。担任矿物材料及其应用湖南省重点实验室主任、纳米矿物材料及应用教育部工程研究中心主任、中国非金属矿行业矿物功能材料重点实验室主任。主要从事矿物材料、能源与环境材料、生物医药材料、材料计算、固废资源化等研究,致力于材料、矿物、化学、物理、生物医学等多学科交叉。在Adv. Funct. Mater.、Nano Energy、Environ. Sci. Technol.、Chem. Mater.、Appl. Catal. B、J. Mater. Chem. A、J. Phys. Chem. Lett.、ChemComm、Am. Mineral.、Clay Clay Miner.、Appl. Clay Sci.等发表SCI论文200多篇(其中自然指数期刊17篇、封面和综述21篇、ESI高被引8篇),SCI引用7 600余次,制定国家/行业标准4项,授权专利40余项,申请国际发明专利10项(授权4项),撰写Elsevier著作章节,出版学术专著5部、教材3部。hmyang@csu.edu.cn   
作者简介:  张峻,2021年6月本科毕业于武汉工程大学矿物加工工程专业,获工学学士学位。现为中南大学资源加工与生物工程学院硕士研究生,在杨华明教授的指导下进行研究工作。
引用本文:    
张峻, 解维闵, 董雄波, 杨华明. 磷石膏材料化综合利用研究进展[J]. 材料导报, 2023, 37(16): 22010110-12.
ZHANG Jun, XIE Weimin, DONG Xiongbo, YANG Huaming. Research Progress on Comprehensive Utilization of Phosphogypsum for Materials: a Review. Materials Reports, 2023, 37(16): 22010110-12.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22010110  或          http://www.mater-rep.com/CN/Y2023/V37/I16/22010110
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