C-S-H Nano-seed and Its Promoting Effect on Cement Hydration and Hardening:a Review
TANG Ruifeng1, ZHANG Jiale1, WANG Ziming1,*, CUI Suping1, WANG Zhaojia1,2, LAN Mingzhang1
1 College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China 2 State Key Laboratory of Soild Waste Utilization and Energy-Saving Building Materials, Beijing Building Materials Research Institute Co., Ltd., Beijing 100041, China
Abstract: In recent years, several nanoparticles have been studied as potential nucleation seeds for cement hydration. Synthetic nano-calcium silicate hydrate (C-S-H), nano-SiO2, nano-CaCO3, nano-TiO2, and carbon nanotubes are investigated to determine their abilities to reduce the nucleation barrier by providing nucleation sites for hydration products, thereby accelerating cement hydration. Among them, the nano C-S-H seeds are found to be a good nucleation substrate for C-S-H gel, and provided the most significant cement-hydration acceleration. Thus, nano C-S-H seeds are attracting increasing attention from both academia and industry. To date, methods of synthesizing nano C-S-H seeds, as well as the seed nucleation process and mechanism of cement hydration, have all been studied. In many studies, the nano C-S-H suspension is prepared by co-precipitating in the presence of polymer that exhibited nanoscale-sized grains and good dispersion stability which followed a non-classical nucleation mode. After applying it to cement, nano C-S-H seeds, with a high surface area, acted as additional nucleation sites for C-S-H gel, which reduced the nucleation barrier of the C-S-H gel. Thus, the nano C-S-H seeds effectively accelerated the cement hydration rate. The nano C-S-H seeds also enhanced the early strength development of the cement, particularly within the first day of aging. In contrast to traditional cement accelerators, nano C-S-H seeds have the advantages of low dosing requirements, good effect on early strength, and no impact on cement and concrete durability. To a certain extent, these seeds also compensate for the slow early-strength growth of supplementary cementitious materials (SCMs). Therefore, nano C-S-H seeds have promising applications in low-temperature and slipform construction, the production of precast-concrete products, and other projects that require high levels of early strength. Nano C-S-H seeds have the potential to become a widely used hydration accelerator for cement and concrete. In this review, many studies about nano C-S-H seeds are analyzed and summarized. Including the methods for synthesizing C-S-H seeds, as well their nucleation process, mechanism of interaction with polymers, and effects on the cement-hydration process. Based on theoretical principles and experimental results, current shortcomings are evaluated, and the problems that still need to be addressed are identified. This review provides a theoretical basis and future direction for scientific research and engineering applications of nano C-S-H seeds.
唐芮枫, 张佳乐, 王子明, 崔素萍, 王肇嘉, 兰明章. C-S-H纳米晶种及其对水泥水化硬化的促进作用综述[J]. 材料导报, 2023, 37(9): 21090259-16.
TANG Ruifeng, ZHANG Jiale, WANG Ziming, CUI Suping, WANG Zhaojia, LAN Mingzhang. C-S-H Nano-seed and Its Promoting Effect on Cement Hydration and Hardening:a Review. Materials Reports, 2023, 37(9): 21090259-16.
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