缓凝剂对磷酸镁水泥性能及其水化机制影响研究进展

doi:10.11896/cldb.20050027

材料导报

2022, Vol. 36

Issue (4): 20050027-7 https://doi.org/10.11896/cldb.20050027

无机非金属及其复合材料

缓凝剂对磷酸镁水泥性能及其水化机制影响研究进展

韦宇¹, 周新涛¹, 黄静², 罗中秋^1,*, 马越¹, 母维宏¹, 刘钦¹, 雒云龙¹

1 昆明理工大学化学工程学院,昆明 650500
2 西昌学院机械与电气工程学院,四川西昌 615000

Research Progress on the Effects of Retarders on the Properties and Hydration Mechanism of Magnesium Phosphate Cement

WEI Yu¹, ZHOU Xintao¹, HUANG Jing², LUO Zhongqiu^1,*, MA Yue¹, MU Weihong¹, LIU Qin¹, LUO Yunlong¹

1 Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China
2 Faculty of Mechanical and Electrical Engineering, Xichang University, Xichang 615000, Sichuan, China

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摘要磷酸镁水泥(MPC)作为一种新型无机胶凝材料,具有早期强度高、干缩小、耐久性好等优良性能,在土木结构工程的快速修补和危废快速固化处理等领域有着极大优势。但磷酸镁水泥因强烈的放热反应,凝结速度过快,可施工操作性较低,所以其缓凝技术研究成为了该类材料规模化应用需解决的关键技术之一。缓凝剂的添加,可有效延缓磷酸镁水泥的凝结速度,改善其可施工操作性。本文基于国内外磷酸镁水泥缓凝剂研究,综述了几种常用的缓凝剂(硼砂(B)、硼酸(BA)和三聚磷酸钠(STP))对磷酸镁水泥性能(水化热、抗压强度、凝结特性)及其水化机制的影响,对其缓凝机理进行了分析讨论。就当前缓凝剂改性MPC研究中的优势及不足,并结合实际应用需求展望其今后研究和发展方向,为MPC后续缓凝研究提供文献支撑。

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	韦宇
	周新涛
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	罗中秋
	马越
	母维宏
	刘钦
	雒云龙

关键词: 磷酸镁水泥无机胶凝材料缓凝剂水化机理

Abstract: Magnesium phosphate cement (MPC), a new type of inorganic cementitious material, has tremendous advantages in the fields of rapid repairment of civil structures and solidification/stabilization of hazardous wastes due to its superior performances, such as high early strength, small dry shrinkage and good durability. However, MPC often shows low workability due to its fast setting caused by the high exothermic acid-base reaction. So the research on the retardation of MPC will be a key direction for its scale application. The addition of retarders into MPC can efficiently retard the setting, thus to improve its workability. Based on the comprehensive literatures on the retarder researches of MPC, the effects of some commonly used retarders (borax (B), boric acid (BA) and sodium tripolyphosphate (STP)) on the properties (hydration heat, compressive strengths and setting behaviors) and hydration mechanism of MPC were reviewed in this paper. Finally, the advantages and shortcomings of the current retarders in the application of MPC were discussed, and the research orientation and prospect of MPC retardation are pointed out. We believe that this review can provide a literature support for the retarding research of MPC.

Key words: magnesium phosphate cement inorganic cementitious material retarder hydration mechanism

出版日期: 2022-02-25 发布日期: 2022-02-28

ZTFLH:

TU528

基金资助: 国家自然科学基金地区基金(21866018;51662024)

通讯作者: luozhongq@126.com

作者简介: 韦宇,2019年6月毕业于宜宾学院,获得应用化学的学士学位。现为昆明理工大学化学工程学院硕士研究生,目前主要研究领域为固体物资资源化利用与安全化处理。
罗中秋,2015年12月取得昆明理工大学环境工程博士学位。主要从事工业固体废弃物资源化和危险废物处理研究工作,包括粉煤灰、磷渣、赤泥、钢铁冶金渣等工业废渣的深度活化方法,制备低温陶瓷胶凝材料,建立化学键合陶瓷胶凝材料性能评价体系并将其应用于危险废物处理方面。

引用本文:

韦宇, 周新涛, 黄静, 罗中秋, 马越, 母维宏, 刘钦, 雒云龙. 缓凝剂对磷酸镁水泥性能及其水化机制影响研究进展[J]. 材料导报, 2022, 36(4): 20050027-7.
WEI Yu, ZHOU Xintao, HUANG Jing, LUO Zhongqiu, MA Yue, MU Weihong, LIU Qin, LUO Yunlong. Research Progress on the Effects of Retarders on the Properties and Hydration Mechanism of Magnesium Phosphate Cement. Materials Reports, 2022, 36(4): 20050027-7.

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http://www.mater-rep.com/CN/10.11896/cldb.20050027 或 http://www.mater-rep.com/CN/Y2022/V36/I4/20050027

1 Mechtcherine V. Construction and Building Materials, 2013, 41,365.
2 Qin G X, Jiao B X. Bulletin of the Chinese Ceramic Society, 2019, 38(4),1075(in Chinese).
秦国新, 焦宝祥. 硅酸盐通报, 2019, 38(4),1075.
3 Ismailov A, Merilaita N, Solismaa S, et al. Construction and Building Materials, 2020, 231, 117098.
4 Péra J, Ambroise J. Cement and Concrete Composites, 1998, 20(1),31.
5 Walling S A, Provis J L. Chemical Reviews, 2016, 116(7),4170.
6 Chau C K, Qiao F, Li Z. Construction & Building Materials, 2011, 25(6),2911.
7 Mechtcherine V. Construction & Building Materials, 2013, 41,365.
8 Yang Q B. Advanced Materials Research, 2013, 857,81.
9 Long Z Q, Wang Z L. Journal of Chongqing University of Technology(Natural Science), 2014, 28(8),44(in Chinses).
龙志强, 王振林. 重庆理工大学学报(自然科学), 2014, 28 (8),44.
10 Haque M A, Chen B. Construction & Building Materials, 2019, 211,885.
11 Dai J, Qian C X, Chen J, et al. Materials Reports B:Research Papers, 2020, 34(3),6066(in Chinses).
戴俊, 钱春香, 陈竞, 等. 材料导报:研究篇, 2020, 34(3), 6066.
12 Zhu Y, Wang Z, Li Z, et al. Chemistry Select, 2020, 5(17),5156.
13 Arora A, Singh B, & Kaur P. Materials Today: Proceedings, 2019, 17,70.
14 You C, Qian J, Qin J, et al. Cement and Concrete Research, 2015, 78, 179.
15 Hall D A, Stevens R, El-Jazairi B. Cement and Concrete Research, 2001, 31(3),455.
16 Fan S, Chen B. Construction and Building Materials, 2014, 65,480.
17 Yang J M, Qian C X, Jiao B X, et al. Journal of Materials Science and Engineering, 2010, 28(1),31(in Chinese).
杨建明, 钱春香, 焦宝祥, 等. 材料科学与工程学报, 2010, 28(1), 31.
18 Song X Y, Yan L H, Hang J Y, et al. Non-Metallic Mines, 2018, 41(6),33(in Chinese).
宋旭艳, 严良海, 韩静云, 等. 非金属矿, 2018, 41(6),33.
19 Qiao F, Chau C K, Li Z. Materials and Structures, 2012, 45(3),447.
20 Ribeiro D V, Paula G R, Morelli M R. Construction & Building Mate-rials, 2019, 214,557.
21 Yang Q, Wu X. Cement & Concrete Research, 1999, 29(3),389.
22 Iyencar S R, Al-Tabbaa A. Environmental Technology, 2007, 28(12),1387.
23 Winbow H D. The chemistry and properties of magnesia-phosphate cement systems. Ph.D. Thesis, University of Sheffield, USA, 1988.
24 Formosa J, Chimenos J M, Lacasta A M, et al. Ceramics International, 2012, 38(3), 2483.
25 Qi H L. Factors affecting the mechanics and water resistance of magne-sium phosphate cement. Master's Thesis, University of Science and Technology Liaoning, China, 2018(in Chinese).
齐浩霖. 磷酸镁水泥力学及抗水性能影响因素. 硕士学位论文, 辽宁科技大学, 2018.
26 Wang Q Z, Qian J S, Qin J H, et al. Journal of the Chinese Ceramic Society, 2013, 41(11), 1493(in Chinese).
王庆珍, 钱觉时, 秦继辉, 等. 硅酸盐学报, 2013, 41(11),1493.
27 Li P X, Du L B, Li D X. Bulletin of the Chinese Ceramic Society, 2008(1),20(in Chinese).
李鹏晓, 杜亮波, 李东旭. 硅酸盐通报, 2008(1), 20.
28 Abdelrazig B E I. In Process British Ceramic Society. 1984, 35,141.
29 Gupta P S, Swihart G H, Dimitrijevic R, et al. American Mineralogist, 1991,76(7-8),1400.
30 Ling W, Sun W, Li Z J. Industrial Construction, 2011, 41(4),75(in Chinese).
林玮, 孙伟, 李宗津. 工业建筑, 2011, 41(4),75.
31 Wang H T.Study on high performance Magnesium phosphate cement based materials. Ph.D. Thesis, Chongqing University, China, 2006(in Chinese).
汪宏涛. 高性能磷酸镁水泥基材料研究. 博士学位论文, 重庆大学, 2006.
32 Ahmad M R, Chen B, Yu J. Composites Part B: Engineering, 2019, 168,204.
33 Yang J M, Shi C J, Chang Y, et al. Journal of Building Materials, 2013, 16(1),43(in Chinese).
杨建明, 史才军, 常远, 等. 建筑材料学报, 2013, 16(1), 43.
34 Lahalle Hugo, Céline Cau Dit Coumes, et al. Cement & Concrete Research, 2018, 109,159.
35 Lahalle Hugo, Céline Cau Dit Coumes, et al. Cement & Concrete Research, 2016, 87,776.
36 Li C M, Wang P M, Wang A, et al. Concrete, 2015(1), 115(in Chinese).
李春梅, 王培铭, 王安, 等. 混凝土, 2015(1),115.
37 Yang J M, Shao Y X, Liu H,Journal of Building Materials,2013(6), 923(in Chinese).
杨建明, 邵云霞, 刘海. 建筑材料学报, 2013(6),923.
38 Yang N, Shi C, Yang J, et al. Journal of Materials in Civil Engineering, 2014, 26(10),4014071.
39 Sarkar A K. Ceramic Transactions, 1993, 40, 281.
40 Soudée E, Péra J. Cement & Concrete Research, 2000, 30(2),315.
41 Abdelrazig B E I, Sharp J H, El-Jazairi B. Cement & Concrete Research, 1988, 18(3),415.
42 Sarkar A K. Journal of Materials Science, 1991, 26(9),2514.
43 Wagh A S, Jeong S Y. Journal of the American Ceramic Society, 2003, 86(11),1838.
44 Blesa M A, Maroto A J G, Regazzoni A E. Journal of Colloid and Interface Science, 1984, 99(1), 32.
45 Soudée E.Liants phosphomagnésiens: mécanisme de prise et durabilité. Ph.D. Thesis, Lyon, INSA, 1999.
46 Momii R K, Nachtrieb N H. Inorganic Chemistry, 1967, 6(6),1189.
47 Ingri N, Dahlen J, Buchardt O, et al. Acta Chemica Scandinavica, 1963, 17,573.
48 Maya L. Inorganic Chemistry, 1976, 15(9),2179.
49 Sugama T, Kukacka L E. Cement & Concrete Research, 1983, 13(3),407.
50 Sugama T, Kukacka L E. Cement & Concrete Research, 1983, 13(4),499.

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