磷酸镁水泥性能的研究进展

doi:10.11896/cldb.20070106

材料导报

2021, Vol. 35

Issue (23): 23068-23075 https://doi.org/10.11896/cldb.20070106

无机非金属及其复合材料

磷酸镁水泥性能的研究进展

刘进, 呙润华, 张增起

清华大学土木工程系,北京 100084

Research Progress of Properties of Magnesium Phosphate Cement

LIU Jin, GUO Runhua, ZHANG Zengqi

Department of Civil Engineering, Tsinghua University, Beijing 100084,China

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摘要磷酸镁水泥由过烧氧化镁和可溶性磷酸盐组成,是一种新型的水硬性胶凝材料。它早期强度高、收缩小、抗硫酸盐侵蚀能力强,能够与硅酸盐水泥基材料形成较强的粘结力,但其耐水性较差,原材料成本较高。因此,各类矿物掺合料如矿渣、粉煤灰、偏高岭土等被尝试用来取代部分原材料。在适当的掺量与取代方式下,矿物掺合料能够延缓凝结时间,提高抗压强度,并且能够改善耐水性。此外,氧化镁与磷酸盐的物质的量比、水胶比等也决定着磷酸镁水泥的性能。本文对磷酸镁水泥的水化机理、抗压强度、粘结强度、耐久性、体积稳定性进行了总结,指出了现有研究中的不足,并给出了建议与展望。

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关键词: 矿物掺合料水化机理粘结强度耐久性

Abstract: Magnesium phosphate cement (MPC),composed of dead burned MgO and soluble phosphate, is a new cement material. The advantages of MPC are high early strength, low shrinkage, strong sulfate resistance and strong bonding with Portland cement-based materials. Howe-ver, the water resistance of MPC is weak and the cost of raw materials is high. Therefore, mineral admixtures such as GGBS, fly ash and metakaolin are used to replace a part of raw materials. At suitable replacement ratio, mineral admixtures could retard setting time, elevate compressive strength and enhance water resistance of MPC. Besides, the MgO to phosphate mole ratio and water to binder ratio have an important influence on the property of MPC. In this paper, the hydration mechanism, compressive strength, bonding strength, durability and volume stability of MPC are summarized. Finally, the limitations of current researches and suggestions as well as perspectives for the future are provided.

Key words: mineral admixture hydration mechanism bond strength durability

出版日期: 2021-12-10 发布日期: 2021-12-23

ZTFLH:

TU528.31

基金资助: 国家自然科学基金项目(51568063);中国博士后科学基金项目(2019M660037; 2020T130355)

通讯作者: guorh@tsinghua.edu.cn

作者简介: 刘进,现为清华大学土木工程系博士研究生,曾在Powder Technology、Journal of Thermal Analysis and Calorimetry、Construction and Building Materials等国际期刊发表数篇学术论文,目前研究方向为路面快速修补材料。
呙润华,清华大学土木工程系副教授、博士研究生导师。2007年于德克萨斯大学奥斯汀分校土木、环境与建筑工程系获博士学位。主持多项国家自然科学基金及日本、刚果等国际合作项目,主要从事交通基础设施性能检测监测及资产管理、道路功能材料等方面研究。

引用本文:

刘进, 呙润华, 张增起. 磷酸镁水泥性能的研究进展[J]. 材料导报, 2021, 35(23): 23068-23075.
LIU Jin, GUO Runhua, ZHANG Zengqi. Research Progress of Properties of Magnesium Phosphate Cement. Materials Reports, 2021, 35(23): 23068-23075.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.20070106 或 http://www.mater-rep.com/CN/Y2021/V35/I23/23068

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