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材料导报  2021, Vol. 35 Issue (13): 13215-13226    https://doi.org/10.11896/cldb.19080093
  高分子与聚合物基复合材料 |
共价有机骨架材料的合成及应用
张关印1, 关清卿1, 庙荣荣1, 宁平1, 何亮2,*
1 昆明理工大学环境科学与工程学院,昆明 650500
2 昆明理工大学化学工程学院,昆明 650500
Synthesis and Application of Covalent Organic Frameworks
ZHANG Guanyin1, GUAN Qingqing1, MIAO Rongrong1, NING Ping1, HE Liang2,*
1 Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China
2 Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China
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摘要 共价有机骨架材料(Covalent organic frameworks,COFs)是有机单体通过可逆共价键连接形成的晶型有机多孔材料。自2005年首例COFs报道以来,大量新型COFs应运而生。COFs具有质量轻、密度低、结构规整、孔道结构可调、比表面积大、化学稳定性高的优势,在生命科学、环境保护和能源化工等方向具有巨大的应用潜力。由于功能化的COFs易实现不同物质在其内部的传输,目前研究人员已经成功将大量COFs应用于气体的吸附和分离与存储、催化剂、药物传递、有机电子器件和选择性分离薄膜等领域并取得了丰硕的研究成果。大量研究表明,COFs是高效存储CO2、H2和CH4的多孔材料,并且也可以作为催化剂载体,甚至可以直接作为催化剂用于催化各种化学反应。COFs的水分散度高且不会对细胞产生毒性,对布洛芬、5-氟尿嘧啶和槲皮素等药物表现出高效的负载和释放性能。2D COFs的π阵列型结构孔道高度规整,容易形成良好的载流子传导路径,可作为半导体元器件、超级电容器和质子交换膜等有机电子器件的理想候选材料。由于其高度有序且稳定的纳米孔道结构特性,2D COFs还可作为性能良好的纳滤薄膜,以高效分离溶剂中的染料分子。本文总结了COFs的各种特性并概述了COFs的结构设计、功能化和合成方法,综述了COFs在气体吸附与存储、催化剂、药物传递、有机电子器件和选择性分子筛薄膜领域的应用进展,并对其发展的新趋势进行了展望。
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张关印
关清卿
庙荣荣
宁平
何亮
关键词:  共价有机骨架  结构设计  功能化    
Abstract: Covalent organic frameworks (COFs) are crystalline organic porous materials, which are constructed with organic building blocks through reversible covalent bonds. Since the first case of COFs was reported in 2005, a large number of new COFs have emerged. COFs have the advantages of light weight, low density, regular structure, adjustable pore structure, high specific surface area, and high chemical stability, which have great application potential in life science, environmental protection and energy chemical industries. Owning to functional COFs facilitate the transportation of different substances within them, researchers have successfully applied them to many fields, such as gas adsorption and storage, catalysis, drug delivery, organic electronic devices, and selective separation membrane, etc., and achieved fruitful research results. Many reports indicate that COFs are highly-efficient porous materials for storing CO2, H2 and CH4. Further, COFs can be also used as catalyst support or be as catalysts directly to imporve many chemical reactions. COFs have good water dispersibility, no toxicity to cells, and show high loading and release capacities for ibuprofen, 5-fluorouracil and quercetin, etc. The highly regular π-array pores of 2D COFs are easy to form good carrier conduction paths, which make them have great potential to be the ideal candidates for semiconductor devices, supercapacitors and proton exchange membrane materials. Owning to their highly-ordered and stable nanopores, 2D COFs also can be used as nanofiltration membranes for efficient separation of dye molecules in solvents. In this work, the characteristics of COFs are summarized, and the structural design, functionalization and synthesis methods of COFs are also described in detail. Finally, the applications of COFs in gas adsorption and storage, catalysis, drug delivery, organic electronic devices and selective separation membrane are reviewed. The development trend of COFs are also prospected.
Key words:  covalent organic frameworks    structural design    functionalization
               出版日期:  2021-07-10      发布日期:  2021-07-14
ZTFLH:  TB34  
基金资助: 国家自然科学基金项目(21767015);国家重点研发计划(2018YFC1902105)
作者简介:  张关印,2017年6月毕业于昆明理工大学,获得工学学士学位。现为昆明理工大学环境科学与工程学院硕士研究生,在关清清教授、何亮副教授的指导下进行研究。目前主要研究领域为共价有机骨架材料的合成及其催化应用。何亮,昆明理工大学化学工程学院副教授,硕士研究生导师。2007—2014年,本科、硕士就读于天津科技大学轻化工程专业;2017年,博士毕业于华南理工大学制浆造纸工程专业;同年7月就职于昆明理工大学,获得云南省“高层次人才引进计划”青年人才称号。近年来在生物质化工与材料、烟草与卷烟新材料、造纸过程监测与环境保护等方面开展研究,在 ACS Catal.、 J. Catal.、 Anal. Chem.、 Cellulose等国际权威期刊上发表论文30余篇,授权国家发明专利4项。受邀担任 Cellulose、 Bioresource Technol.等多个国际权威期刊的审稿人。
引用本文:    
张关印, 关清卿, 庙荣荣, 宁平, 何亮. 共价有机骨架材料的合成及应用[J]. 材料导报, 2021, 35(13): 13215-13226.
ZHANG Guanyin, GUAN Qingqing, MIAO Rongrong, NING Ping, HE Liang. Synthesis and Application of Covalent Organic Frameworks. Materials Reports, 2021, 35(13): 13215-13226.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19080093  或          http://www.mater-rep.com/CN/Y2021/V35/I13/13215
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