高温应用钼及钼合金表面改性研究进展*

doi:10.11896/j.issn.1005-023X.2017.07.013

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (1315KB)
Export: BibTeX | EndNote (RIS)

Abstract Molybdenum and molybdenum alloys have been widely used in military, aerospace and other fields because of their high melting point, high hardness and excellent mechanical properties. However, the high temperature application properties of molybdenum and molybdenum alloys has been seriously affected by the defects such as bad oxidation resistance, low ablation resistance and poor wear resistance at elevated temperature. It is found that the surface modification can effectively solve the above problems. In this paper, the basic requirements of surface modification coating for high temperature application molybdenum and molybdenum alloy are proposed firstly. The main research progress on the improved oxidation resistance, ablation resistance and wear resistance of surface modified molybdenum and molybdenum alloys at elevated temperature is systematically reviewed. The coating preparation me-thods are introduced, and the existing problems and development prospects of research in this field are also proposed.

Key words： high temperature application molybdenum and molybdenum alloys surface modification

Published: 10 April 2017 Online: 2018-05-08

CLC number:

TG146.4

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHANG Yong
	WANG Xiongyu
	YU Jing
	CAO Weicheng
	FENG Pengfa
	JIAO Shengjie

Cite this article:

ZHANG Yong,WANG Xiongyu,YU Jing, et al. Advances in Surface Modification of Molybdenum and Molybdenum Alloys at Elevated Temperature[J]. Materials Reports, 2017, 31(7): 83-87.

URL:

https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.07.013 OR https://www.mater-rep.com/EN/Y2017/V31/I7/83

1 Ju Yanpeng, Wang Aiqin. Current research status of Mo alloys[J]. Powder Metall Ind,2015, 25(4):58(in Chinese).
居炎鹏, 王爱琴. 钼合金研究现状[J]. 粉末冶金工业,2015,25(4):58.
2 Gao Mingchuan,Tong Xiangyang,Wang Hongsheng.Research progress of Mo-based coatings fabricated by thermal spray technology[J].China Molybdenum Ind,2014,38(6):41(in Chinese).
高名传,童向阳,汪洪生. 热喷涂法制备钼系涂层的研究进展[J]. 中国钼业,2014,38(6):41.
3 Shi Jun, Liu Ning, et al. Progress of research on molybdenum and its alloy[J]. Thermal Treat,2014,29(5):19(in Chinese).
石俊, 刘宁, 等. 钼及钼合金研究的进展[J]. 热处理,2014,29(5):19.
4 Fan Jinglian, Lu Mingyuan, Cheng Huichao. Effect of alloying elements Ti, Zr on the property and microstructure of molybdenum[J]. Int J Refractory Met Hard Mater,2009,27:78.
5 Wang Jiteng, Wang Juan, Li Yajiang, et al. Progress of research on welding for molybdenum alloys [J]. High Temperature Mater Prog,2014,33(3):193.
6 Cheng Huichao, Fan Jinglian, Li Pengfei, et al. Oxidation resis-tance and ablation behavior of refractory alloy at high temperature[J]. Chin J Nonferrous Met,2011,21(3):570(in Chinese).
成会朝, 范景莲, 李鹏飞, 等. 难熔钼合金的高温抗氧化和烧蚀行为[J]. 中国有色金属学报,2011,21(3):570.
7 Chen Chuang, Wei Shizhong, Zhang Guoshang, et al. Current research and application development of molybdenum alloy[J]. Rare Met Cem Carbides,2012,40(5):45(in Chinese).
陈闯, 魏世忠, 张国赏, 等. 钼合金的研究现状与应用进展[J]. 稀有金属与硬质合金, 2012,40(5):45.
8 Riedl H, Vieweg A, Limbeck A, et al. Thermal stability and mechanical properties of boron enhanced Mo-Si coatings[J]. Surf Coat Technol,2015,280:282.
9 Qu Jianglong. Study of B, Y-modified pack Si deposition coating on molybdenum[D]. Xi’an: Chang’an University,2014(in Chinese).
曲江龙. 钼表面B, Y改性包埋渗Si涂层研究[D]. 西安: 长安大学,2014.
10 李美栓. 金属的高温腐蚀[M]. 北京: 冶金工业出版社, 2001.
11 Wang Yi, Wang Dezhi, Sun Aokui, et al. The advance on the oxidation resistance coating of molybdenum and its alloys[J].Mater Rev: Rev,2012,26(1):137(in Chinese).
汪异, 王德志, 孙翱魁, 等. 钼及其合金氧化防护涂层的研究进展[J]. 材料导报: 综述篇,2012,26(1):137.
12 Xie Nengping. Study on preparation and properties of silicides coa-ting on the molybdenum surface by in-situ synthesizing[D]. Xiangtan: Hunnan University of Science and Technology,2011(in Chinese).
谢能平. 钼表面原位合成硅化物涂层的制备工艺与性能研究[D]. 湘潭: 湖南科技大学,2011.
13 Song Rui, Wang Kuaishe, Hu Ping, et al. Present situation of anti-oxidation coatings preparation on molybdenum and its alloys[J]. Mater Rev: Rev,2016,30(5):69(in Chinese).
宋瑞, 王快社, 胡平, 等. 钼及钼合金表面高温抗氧化涂层研究现状[J]. 材料导报: 综述篇,2016,30(5):69.
14 Chakraborty S P, Banerjee S, Sharma I G, et al. Development of sili-cide coating over molybdenum based refractory alloy and its characterization [J]. J Nuclear Mater,2010, 403(1-3):152.
15 Wu Heng, Li Hejun, Wang Yongjie, et al. Effect of deposition temperature on microstructures and properties of MoSi2 coatings prepared by low pressure chemical vapor deposition[J]. J Inorg Mater,2009,24(2):392(in Chinese).
吴恒, 李贺军, 王永杰, 等. 低压沉积温度对MoSi2涂层微观结构与性能影响[J]. 无机材料学报,2009,24(2):392.
16 Gu Siyong, Zhang Houan, Xie Nengping. Oxidation property of MoSi2/Si3N4 coating on Mo substrate[J]. J Xiamen University of Technology,2011,19(2):18(in Chinese).
古思勇, 张厚安, 谢能平. 金属钼表面MoSi2/Si3N4涂层的氧化性能研究[J]. 厦门理工学院学报,2011,19(2):18.
17 Nicholls J R, Simms N J, Chan W Y, et al. Smart overlay coatings-concept and practice[J]. Surf Coat Technol,2002,149(2-3):236.
18 Huang Can, Zhang Yongzhong, Rui Vilar. Microstructure and anti-oxidation behavior of laser clad Ni-20Cr coating on molybdenum surface[J]. Surf Coat Technol,2010,205(3):835.
19 Zhang Wei, Gao Lianze, Xie Qitian. The experimental study of the effect of the structural factors of the nozzle on the nozzle throat depo-sition[J]. J Harbin Shipbuilding Engineering Institute,1983,4(1):25(in Chinese).
张唯, 高连泽, 谢其钿. 喷管结构因素对喉衬沉积影响的实验研究[J]. 哈尔滨船舶工程学院学报,1983,4(1):25.
20 Wei Yanjun. Research on ablation charateristics of extended range projectile engine nozzle[D]. Shenyang: Shenyang Ligong University,2014(in Chinese).
魏岩峻. 增程弹发动机喷管烧蚀特性研究[D]. 沈阳: 沈阳理工大学,2014.
21 Jiang Fan, Gao Xinyi. The SEM examination of molybdenum nozzle and the investigation of erosion mechanism[J]. Acta Armam,1984 (3):31(in Chinese).
蒋凡, 高新宜. 钼喷管的SEM检验及烧蚀机理的探讨[J]. 兵工学报,1984(3):31.
22 Chang Chun, Yu Dajiang, Liu Shaobin, et al. Microstructures and corrosion resistance of molybdenum-alumina materials[J]. J Chin Ceram Soc,2008,36(8):1124(in Chinese).
常春, 余大江, 刘少斌, 等. Mo/Al2O3材料的微观结构和抗腐蚀性[J]. 硅酸盐学报,2008,36(8):1124.
23 Carreri F C, Oliveira R M, Oliveira A C, et al. Phase formation and mechanical/tribological modification induced by nitrogen high temperature plasma based ion implantation into molybdenum[J]. Appl Surf Sci,2014,310:305.
24 Sun Jia, Fu Qiangang, Guo Liping, et al. Effect of filler on the oxidation protective ability of MoSi2 coating for Mo ubstrate by halide activated pack cementation[J]. Mater Des,2016, 92:602.
25 Yoon J K, Kim G H, Byun J Y, et al. Effect of Cl/H input ratio on the growth rate of MoSi2 coatings formed by chemical vapor deposition of Si on Mo substrate from SiCl4-H2 precursor gases[J]. Surf Coat Technol,2003,172(2-3):176.
26 Weis S, Uhlig T, Wagner G, et al. High-temperature corrosion and radiation characteristics of thermal sprayed molybdenum disilicide-based coatings[C]//18th Chemnitz Seminar on Materials Enginee-ring. Chemnitz,2016.
27 Hou Fengliang, Ni Feng, Cui Yansui, et al. Abrasive wear properties of Al2O3/Mo composite[J].Acta Mater Compos Sin,2011,28(4):136(in Chinese).
侯风亮, 倪峰, 崔延遂, 等. Al2O3/Mo复合材料的磨料磨损性能[J]. 复合材料学报, 2011,28(4):136.
28 Gu Siyong, Zhang Houan, Wu Yihui, et al. Preparation of Mo-C-N-Si coating on Mo substrate and its oxidation property at high tempe-rature[J]. Rare Met Mater Eng,2014,43(5):1219(in Chinese).
古思勇, 张厚安, 吴艺辉, 等. 金属钼表面Mo-C-N-Si涂层的制备及其高温氧化特性[J]. 稀有金属材料与工程,2014,43(5):1219.