Abstract: Cement-based materials are indispensable materials in engineering construction, but the problems of environment and resource consumption caused by their production have been paid more and more attention. Meanwhile the output of industrial wastes is increasing year by year, and the environmental pollution caused by industrial wastes is becoming more and more serious. Considering environmental protection and sustainable development, silicon-aluminium industrial wastes can be used in cement-based materials. This approach can solve the environmental problems caused by the production of cement clinker and the emissions of industrial wastes at the same time. However, the lower activity of some silicon-aluminium industrial wastes used extensively in cement concrete will reduce the early strength of cement-based materials and also limit their utilization. The properties of ultrafine silicon-aluminium materials are not fully released due to their agglomeration and poor dispersivity, which will affect the efficient use of silicon-aluminium materials in cement-based materials. The performances of modern cement concrete are no longer only judged by the mechanical properties, and good workability, durability and functionality are its trend to develop. Finding ways to combine functional materials with cement-based materials in order to better play their functions is also one of the research hotspots in the field of cement concrete. Surface modification technologies have achieved good results in improving the properties of silicon-aluminium materials. The modification of some inert or less active silicon-aluminium industrial wastes can improve their activity on a degree, and reduce the decline of early strength of cement-based materials caused by their use as admixtures, which can also increase their quantities used in cement-based materials and improve the comprehensive utilization of industrial wastes. The technologies of surface modification including acid-base micro-corrosion and calcined with calcareous materials are common methods to improve the activity of silicon-aluminium materials (fly ash, quartz sand tailings, etc.). Surface modification by using functional additives can reduce the agglomeration of ultrafine silicon-aluminium materials and increase their dispersivity in cement-based materials, which can make the properties of silicon-aluminium materials develop more fully and improve the workability of cement-based materials. Loading materials with environmental cleaning function on the surface of silicon-aluminium materials can not only meet the basic properties of admixtures, but also play a role in protecting environment, and the utilization of silicon-aluminium industrial wastes modified by surface modification technologies will play a dual environmental benefit of “treating pollution by using wastes”. This paper summarizes the research progress on improving the properties of silicon-aluminium materials include activity, dispersivity and functionality by using the technologies of surface modification. Some problems still exist in the application of surface modification technologies in cement-based materials are put forward in order to provide reference suggestions for the efficient utilization of industrial wastes.
王爱国, 朱愿愿, 李燕, 刘开伟, 徐海燕, 孙道胜, 范良朝. 表面改性硅/铝质材料及其在水泥基材料中应用的研究进展[J]. 材料导报, 2019, 33(15): 2538-2545.
WANG Aiguo, ZHU Yuanyuan, LI Yan, LIU Kaiwei, XU Haiyan, SUN Daosheng, FAN Liangchao. Research Progress on Surface Modification of Silicon-Aluminum Materials and Their Applications in Cement-based Materials. Materials Reports, 2019, 33(15): 2538-2545.
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2019, Vol. 33 
