Research Progress of Building Materials Prepared from the Carbonized Curing Steel Slag
WANG Aiguo1, HE Maocan1, MO Liwu2, LIU Kaiwei1, LI Yan1, ZHOU Ying3, SUN Daosheng1
1 Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei 230022 2 State Key Laboratory of Material-Oriented Chemical Engineering, College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009 3 Jiangsu Subote New Materials Ltd. Co., Nanjing 211103
Abstract: Steel slag is a kind of solid waste produced during the process of steelmaking, the emissionis huge, while the utilization rate is low in China. Huge amount of steel slag is produced caused which not only occupies land, but also causes environmental pollution and resource waste. In recent years, steel slag has been used as cement mixtures, concrete admixtures or coarse and fine aggregates in building materials to a certain extent. However, Both domestic and overseas researchers reported that the formation of Ca(OH)2 and Mg(OH)2 from free calcium oxide and magnesium oxide in steel slag by later hydration reaction will cause volume expansion, which resulting in poor stability of building materials containing steel slag. Solving the problem of poor stability of steel slag is the key point to large-scale development and utilization of steel slag resources. In recent years, many steel industry continuously develop steel slag pretreatment by optimizing smelting technology, forming a variety of steel slag treatment technology, improving the comprehensive utilization rate of steel slag, but different treatments of steel slag lead to different stability, uniformity, particle size and activity of steel slag. In addition to the traditional method of steel slag pretreatment to improve its stability, some researchers have proposed high temperature reconstruction method to eliminate free calcium oxide to promote its volume stability, but the process requirements are relatively high. Also some researches find that steel slag has shown high reactivity in CO2-rich atmosphere, Preparation of construction materials via accelerated carbonation is a novel approach to recycle the steel slag. In this paper the current research progress on the carbonated steel slag construction materials was reviewed. The chemical and mineral compositions of steel slag, thermodynamic and kinetic of the accelerated carbonation reaction of steel slag were analyzed. The effects of mineral composition, particle size and gradation of steel slag, mix proportions of raw materials, pre-curing and initial casting pressure, moisture content, CO2 concentration and pressure, carbonation temperature and time, on the composition, structure and properties of the carbonated steel slag building construction were comprehensively discussed. The improvement of carbonation on the steel slag construction materials and the relevant mechanism were discussed. Finally, based on the current research state and existing problems, some suggestions were put forward for the further study in and extending the application of the carbonated steel slag construction materials.
作者简介: 王爱国,安徽建筑大学,副教授,硕士生导师。2010年毕业于南京工业大学,获材料学博士学位。2017年于澳大利亚University of Southern Queensland, Centre for Future Materials作访问学者。主持和参与国家自然科学基金项目、安徽省高校自然科学研究重点研究项目、高性能土木工程材料国家重点实验室开放课题和材料化学工程国家重点实验室开放课题等省部级以上项目10项。Construction and Building Materials、Cement and Concrete Composites、《材料导报》《硅酸盐通报》等学术期刊审稿人,中国建筑学会建筑材料分会化学激发胶凝材料专业委员会委员。主要研究方向为高性能水泥基材料/建筑功能材料/固体废弃物综合利用。 莫立武,男,1981年9月生,博士,材料化学工程国家重点实验室、南京工业大学材料学院教授。2011年至2012年在加拿大多伦多大学从事博士后研究,2013年至2014年在英国剑桥大学从事合作研究。主要从事镁质特种工程材料(MgO膨胀材料与膨胀水泥、混凝土快速修补加固与防护材料、污染土与水处理环境材料)、含钙、镁、铝工业废弃物资源化利用、混凝土防裂与防腐、CO2利用与低碳胶凝材料等方面的研究。主持国家自然科学基金面上项目、国家自然科学青年基金、国家自然科学基金国际合作项目(合作负责人)、江苏省自然科学基金面上项目和青年基金项目等20余科研项目。发表论文100余篇,授权国家发明专利2项,获省部级奖项2项。长期担任国际著名学术期刊Chemical Reviews、Cement and Concrete Research、Cement and Concrete Composites、Construction and Building Materials、Journal of Cleaner Production等审稿人,担任欧洲研究委员会(European Research Council)项目评审专家。
引用本文:
王爱国,何懋灿,莫立武,刘开伟,李燕,周莹,孙道胜. 碳化养护钢渣制备建筑材料的研究进展[J]. 材料导报, 2019, 33(17): 2939-2948.
WANG Aiguo, HE Maocan, MO Liwu, LIU Kaiwei, LI Yan, ZHOU Ying, SUN Daosheng. Research Progress of Building Materials Prepared from the Carbonized Curing Steel Slag. Materials Reports, 2019, 33(17): 2939-2948.
Xu K D. Steel, 2010, 45(3), 1 (in Chinese).徐匡迪. 钢铁, 2010, 45(3), 1.2 Zhang C H, Liao J L, Ju J T, et al. Journal of Iron and Steel Research, 2013, 25(7), 1 (in Chinese).张朝晖, 廖杰龙, 巨建涛, 等. 钢铁研究学报, 2013, 25(7), 1.3 Song Q J, Ning X J, Zhang J L, et al. In: The 11th CSM Steel Congress. Beijing, 2017, pp. 1(in Chinese).宋强建, 宁晓钧, 张建良, 等. 第十一届中国钢铁年会. 北京, 2017, pp. 1.4 Wang L, Sun B L, Li C W. Energy Formetallurg Ical Industry, 2007, 26(4), 54 (in Chinese).王琳, 孙本良, 李成威. 冶金能源, 2007, 26(4), 54.5 Zhou X Y, Xiang X D, Li C H. Multipurpose Utilization of Mineral Resources, 2014(3), 8 (in Chinese).周溪滢, 向晓东, 李灿华. 矿产综合利用, 2014(3), 8.6 Proctor D M, Fenling K A, Shay E C, et al. Environmental Science and Technology, 2000, 34(8), 1576.7 Motz H, Geiseler J. Waste Management, 2001, 21(3), 285.8 Morales F V, Santos A, Lemus A, et al. Chemical Engineering Journal, 2011, 166(1), 132.9 Li C, Chen Z W, Xie J, et al. Materials Review A: Review Papers, 2017, 31(3), 86 (in Chinese).李超, 陈宗武, 谢君, 等. 材料导报:综述篇, 2017, 31(3), 86.10 陈恩义, 汪爱萍, 黄海, 等. 中国专利, CN105399349A, 2016.11 Zhao J H, Yan P Y. Bulletin of the Chinese Ceramic Society, 2017, 36(2), 477 (in Chinese).赵计辉, 阎培渝. 硅酸盐通报, 2017, 36(2), 477.12 Ren Q, Wang Y J, Li S L. Research on Iron and Steel, 2012, 40(1), 54 (in Chinese).任奇, 王颖杰, 李双林. 钢铁研究, 2012, 40(1), 54.13 Zhao H J, Yu Q J, Wei J X, et al. Bulletin of the Chinese Ceramic Society, 2010, 29(3), 572 (in Chinese).赵海晋, 余其俊, 韦江雄, 等. 硅酸盐通报, 2010, 29(3), 572.14 Li Z F. Study on distribution and mechanism for controlling mgo in steel slag by optimizing the mineral composition. Master's Thesis, University of Jinan, China, 2011 (in Chinese).李召峰. 优化钢渣物相组成、控制MgO分布及其机理研究. 硕士学位论文, 济南大学, 2011.15 Wang Q. China Concrete, 2016(2), 90 (in Chinese).王强. 混凝土世界, 2016(2), 90.16 Wang Q, Cao F Z, Yu C, et al. Bulletin of the Chinese Ceramic Society, 2015, 34(4), 1004 (in Chinese).王强, 曹丰泽, 于超, 等. 硅酸盐通报, 2015, 34(4), 1004.17 Liu G W, Zhu L J, Jin Q, et al. Multipurpose Utilization of Mineral Resources, 2016(2), 11 (in Chinese).刘国威, 朱李俊, 金强, 等. 矿产综合利用, 2016(2), 11.18 Huijgen W J J, Comans R N J, Witkamp G J. Environmental Science & Technology, 2005,39(24),9676.19 Bukowski J M, Berger R L. Cement and Concrete Research, 1979, 9(2), 57.20 Ghouleh Z, Guthrie R I L, Shao Y. Construction and Building Materials, 2015, 99, 175.21 Mahoutian M, Ghouleh Z, Shao Y. Construction and Building Materials, 2014, 66(1), 214.22 Boone M A, Nielsen P, De K T, et al. Environmental Science and Technology, 2014, 48(1), 674.23 Bao W J, Li H Q, Zhang Y. Journal of Chemical Industry and Enginee-ring, 2007, 58(1), 1 (in Chinese).包炜军, 李会泉, 张懿. 化工学报, 2007, 58(1), 1.24 Wu H Z, Tan W J, Ding L, et al. China Concrete and Cement Products, 2010(2), 24 (in Chinese).吴昊泽, 谭文杰, 丁亮, 等. 混凝土与水泥制品, 2010(2), 24.25 Li J. Shanxi Metallurgy, 2005, 28(3), 32 (in Chinese).李婕. 山西冶金, 2005, 28(3), 32.26 Shi C. Journal of Materials in Civil Engineering, 2005, 36(22), 230.27 Pan S Y, Adhikari R, Chen Y H, et al. Journal of Cleaner Production, 2016, 137, 617.28 Shi C, Qian J. Resources, Conservation and Recycling, 2000, 29(3), 195.29 Tufekci M, Demirbas A, Genc H. Cement and Concrete Research, 1997, 27(11), 1713.30 Wang Y J, Ye G X. Journal of the Chinese Ceramic Society, 1981(3), 60 (in Chinese).王玉吉, 叶贡欣. 硅酸盐学报, 1981(3), 60.31 Ou Y D, Xie Y P, He J Y. Journal of the Chinese Ceramic Society, 1991(6), 488 (in Chinese).欧阳东, 谢宇平, 何俊元. 硅酸盐学报, 1991(6), 488.32 Huang Z F, Zhou Y Q, Yang Z. Nonferrous Metals Design, 2005, 32(2), 50 (in Chinese).黄志芳, 周永强, 杨钊. 有色金属设计, 2005, 32(2), 50.33 Yi L S, Wen J. Bulletin of the Chinese Ceramic Society, 2013, 32(10), 2057 (in Chinese).易龙生, 温建. 硅酸盐通报, 2013, 32(10), 2057.34 Zhao H J, Yu Q J, Wei J X, et al. Journal of Wuhan University of Technology, 2010(15), 22 (in Chinese).赵海晋, 余其俊, 韦江雄, 等. 武汉理工大学学报, 2010(15), 22.35 Hou G H, Li W F, Guo W, et al. Journal of the Chinese Ceramic Society, 2008, 36(4), 16 (in Chinese).侯贵华, 李伟峰, 郭伟, 等. 硅酸盐学报, 2008, 36(4), 16.36 Wang Q, Yan P Y. Journal of the Chinese Ceramic Society, 2008, 36(10), 1406 (in Chinese).王强, 阎培渝. 硅酸盐学报, 2008, 36(10), 1406.37 Mason B. Journal of Iron and Steel Institute, 1994(11), 69.38 Tang M S, Yuan M X, Hang S F, et al. Journal of the Chinese Ceramic Society, 1979(1), 37 (in Chinese).唐明述, 袁美栖, 韩苏芬, 等. 硅酸盐学报, 1979(1), 37.39 Kourounis S, Tsivilis S, Tsakiridis P E, et al. Cement and Concrete Research, 2007, 37(6), 815.40 Shi C. Cement and Concrete Research, 2002, 32(3), 459.41 Xiang C X, Yang S F, Wu J Y. Tianjin Metal, 1996(4), 4 (in Chinese).项长祥, 杨斯馥, 吴静一. 天津冶金, 1996(4), 4.42 Wu L, Zhang N, Li H X, et al. Metal Mine, 2017(11), 200 (in Chinese).吴乐, 张娜, 李宏煦, 等. 金属矿山, 2017 (11), 200.43 Qian G R, Xu G L, Li H Y, et al. Journal of Southwest Institute Techno-logy, 1997 (1), 35 (in Chinese).钱光人, 徐光亮, 李和玉, 等. 西南工学院学报, 1997(1), 35.44 Huang Y, Xu G P, Cheng H G, et al. Bulletin of the Chinese Ceramic Society, 2014, 33(8), 1902 (in Chinese).黄毅, 徐国平, 程慧高, 等. 硅酸盐通报, 2014, 33(8), 1902.45 Salman M, Ozlem Cizer, Pontiks Y, et al. Chemical Engineering Journal, 2014, 246(4), 39.46 Mu Y D, Xue G R, Zhao S X, et al. Journal of the Chinese Ceramic So-ciety, 2017, 45(8), 1197 (in Chinese).穆元冬, 雪高瑞, 赵思雪, 等. 硅酸盐学报, 2017, 45(8), 1197.47 Wang Z H, Zhang J Y, Xu J, et al. Journal of Engineering Thermophy-sics, 2008, 29(6), 1063 (in Chinese).王宗华, 张军营, 徐俊, 等. 工程热物理学报, 2008, 29(6), 1063.48 Lackner K S. Annual Review of Energy and the Environment, 2002, 27(1), 193.49 Chang J, Wu H Z. Journal of the Chinese Ceramic Society, 2010, 38(7), 1185 (in Chinese).常钧, 吴昊泽. 硅酸盐学报, 2010, 38(7), 1185.50 Yao Xiao, Tang Mingshu. Oilfield Chemistry, 1999, 16(1), 10 (in Chinese).姚晓, 唐明述. 油田化学, 1999, 16(1), 10.51 Yin Y J. Physical Chemistry Concise Course Third Edition, Beijing Higher Education Press, China, 1992 (in Chinese).印永嘉. 物理化学简明教程第三版, 北京高等教育出版社, 1992.52 Wu J C S, Sheen J D, Shyanyeh C A, et al. Industrial and Enginee-ring Chemistry Research, 2001, 40(18), 3902.53 Pan S Y, Chiang P C, Chen Y H, et al. Critical Reviews in Environmental Science and Technology, 2013, 47(7), 3308.54 Mun M, Cho H, Kwon J. Journal of Environmental Chemical Enginee-ring, 2017, 5(4), 3803.55 Mikkelsen M. The teraton challenge. Energy and Environmental Science, 2010, 3(1), 43.56 Zhu B R, Yang Q B. Journal of Building Materials, 2011, 14(4), 560 (in Chinese).朱蓓蓉, 杨全兵. 建筑材料学报, 2011, 14(4), 560.57 Kakizawa M, Yamasaki A, Yanagisawa Y. Energy, 2001, 26(4), 341.58 Bao W J, Li H Q, Zhang Y. Journal of Chemistry Engineering, 2009, 60(9), 2332 (in Chinese).包炜军, 李会泉, 张懿. 化工学报, 2009, 60(9), 2332.59 Doucet F J, Reuter M A, Heiskanen K. Minerals Engineering, 2010, 23(3), 262.60 Huijgen W J J, Geertjan W. Environmental Science & Technology, 2005, 39(24), 9676.61 Polettini A, Pomi R, Stramazzo A. Journal of Environmental Management, 2016, 167, 185.62 Ukwattage N L, Ranjith P G, Xin L. Measure, 2017, 97, 15.63 Bodor M, SantosR M, Kriskova L, et al. Home European Journal of Mineralogy, 2013, 25(4), 533.64 Fang Y F,Zhang T T, Chang J. Journal of Chinese Electron Microscopy Society, 2015(6), 464 (in Chinese).房延凤, 张婷婷, 常钧. 电子显微学报, 2015(6), 464.65 Berryman E J, Williamsjones A E, Migdisov A A. Journal of Environmental Sciences, 2015, 27(1), 266.66 Tu M X, Lei Z, Lu X F, et al. Techniques and Equipment for Environmental Pollution Control, 2015, 9(9), 4514(in Chinese).涂茂霞, 雷泽, 吕晓芳, 等. 环境工程学报, 2015, 9(9), 4514.67 Chu J. Fly Ash, 1998(2), 26(in Chinese).储健. 粉煤灰, 1998(2), 26.68 Wu H Z, Zhao H L, Tan W J, et al. Journal of Jinan University: Science and Technology, 2010, 24(1), 21 (in Chinese).吴昊泽, 赵华磊, 谭文杰, 等. 济南大学学报: 自然科学版, 2010, 24(1), 21.69 Zhang F, Mo L W, Deng M. Concrete Journal of the Chinese Ceramic Society, 2016, 44(5), 640 (in Chinese).张丰, 莫立武, 邓敏. 硅酸盐学报, 2016, 44(5), 640.70 Mo L, Zhang F, Deng M. Cement and Concrete Research, 2016, 88, 217.71 Wu H Z, Zhao H L, Tan W J, et al. Cement Engineering, 2009(6), 18 (in Chinese).吴昊泽, 赵华磊, 谭文杰, 等. 水泥工程, 2009(6), 18.72 Feng M, Guo P, Wang R Y. Journal of Chongqing Jiaotong University: Natural Science, 2011, 30(2), 246 (in Chinese).冯敏, 郭鹏, 王瑞燕. 重庆交通大学学报: 自然科学版, 2011, 30(2), 246.73 Shi D. Study on properties and influencing factors of steel slag carbonated brick. Master's Thesis, China General Academy of Building Materials Science, China, 2012 (in Chinese).史迪. 钢渣碳化砖的性能及其影响因素研究. 硕士学位论文, 中国建筑材料科学研究总院, 2012.74 Wu H Z, Zhao H L, Ding L, et al. Cement, 2010(2), 6 (in Chinese).吴昊泽, 赵华磊, 丁亮, 等. 水泥, 2010(2), 6.75 Wu H Z, Ding L, Zheng W J, et al. Fly Ash, 2011, 23(2), 24 (in Chinese).吴昊泽, 丁亮, 郑文军, 等. 粉煤灰, 2011, 23(2), 24.76 Hu Y F. Shandong Science, 2015, 28(1), 97 (in Chinese).胡玉芬. 山东科学, 2015, 28(1), 97.77 Pang B. Preparation and properties of carbonated steel slag aggregate and concrete. Master's Thesis, Jinan University,China, 2016 (in Chinese).逄博. 碳化钢渣骨料及混凝土的制备和性能研究. 硕士学位论文, 济南大学, 2016.78 Hao Y Y, Mo L W, Hui J J. Bulletin of the Chinese Ceramic Society, 2016, 35(9), 3047(in Chinese).郝园园, 莫立武, 恽进进. 硅酸盐通报, 2016, 35(9), 3047.79 Wu H Z, Zhang L J, Ye Z M, et al. Journal of Jinan University (Natural Science Edition), 2009, 23(3), 221 (in Chinese).吴昊泽, 张林菊, 叶正茂, 等. 济南大学学报(自然科学版), 2009, 23(3), 221.80 Mo L, Zhang F, Deng M, et al. Cement & Concrete Composites, 2017, 83, 138.81 Chang J. Journal of the Chinese Ceramic Society, 2007, 35(9), 1264 (in Chinese).常钧. 硅酸盐学报, 2007, 35(9), 1264.82 Zhang B, Poon C, Shi C. Cement & Concrete Composites, 2013, 42(9), 1.83 Chang E E, Pan S Y, Chen Y H, et al. Journal of Hazardous Materials, 2011, 195(1), 107.84 Zhang F, Mo L W, Deng M. Journal of the Chinese Ceramic Society, 2015, 43(8), 1032 (in Chinese).张丰, 莫立武, 邓敏. 硅酸盐学报, 2015, 43(8), 1032.85 Hao X J, Lu B, Jiang W L, et al. Materials Review B:Research Papers, 2016, 30(2), 106 (in Chinese).郜效娇, 卢豹, 蒋伟丽, 等. 材料导报:研究篇, 2016, 30(2), 106.86 Fernández B M , Simons S J R, Hills C D, et al. Journal of Hazardous Materials, 2004, 112(3), 193.87 Back M, Bauer M, Stanjek H, et al. Applied Geochemistry, 2011, 26(7), 1097.88 Mo L W, Panesar, Daman K. Cement & Concrete Composites, 2013, 43, 69.89 Zhang F, Mo L W, Deng M, et al. Journal of Building Materials, 2017(6), 854 (in Chinese).张丰, 莫立武, 邓敏, 等. 建筑材料学报, 2017(6), 854.90 Zhao H L, Wu H Z, Chang J, et al. Journal of Jinan University (Natural Science Edition), 2010, 24(3), 221 (in Chinese).赵华磊, 吴昊泽, 常钧, 等. 济南大学学报(自然科学版), 2010, 24(3), 221.91 Cao W D, Yang Q B. Journal of the Chinese Ceramic Society, 2013(10), 1395 (in Chinese).曹伟达, 杨全兵. 硅酸盐学报, 2013(10), 1395.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2019, Vol. 33 
