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材料导报  2018, Vol. 32 Issue (6): 1000-1003    https://doi.org/10.11896/j.issn.1005-023X.2018.06.027
  材料研究 |
钢渣的表面改性及其在橡胶中应用研究
沈海洋1, 王正洲1, 2
1 同济大学材料科学与工程学院,上海 201804;
2 先进土木工程材料教育部重点实验室(同济大学),上海 201804
Surface Modification of Steel Slag and Its Application in Compounded Rubber
SHEN Haiyang1, WANG Zhengzhou1, 2
1 School of Materials Science and Engineering, Tongji University, Shanghai 201804;
2 Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804
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摘要 研究了钢渣对天然橡胶、丁苯橡胶和顺丁橡胶复合橡胶的硫化性能和力学性能的影响。结果表明:钢渣的加入使得复合橡胶的焦烧时间(t10)和正硫化时间(t90)缩短,对复合橡胶的硫化具有一定的促进作用。添加适量(10份)的钢渣可以提高复合橡胶的拉伸强度和扯断伸长率,随着钢渣用量继续增加,复合橡胶的拉伸强度和扯断伸长率逐渐降低。复合橡胶的硬度和磨耗量随钢渣添加量的增加而逐渐增大。与未改性钢渣相比,添加硅烷偶联剂KH-550改性钢渣的复合橡胶的t10t90均有一定缩短;添加硅烷偶联剂Si-69和钛酸酯偶联剂CS-105改性钢渣的复合橡胶的t10t90均有一定延长;改性钢渣填充的复合橡胶的拉伸强度和扯断伸长率都有所提高、磨耗量降低。SEM结果表明,改性钢渣与复合橡胶的相容性得到提高。
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沈海洋
王正洲
关键词:  钢渣  复合橡胶  表面改性    
Abstract: The influence of steel slag on curing characteristics and mechanical properties of a compounded rubber i.e. natural rubber, styrene-butadiene rubber and butadiene rubber was studied. The results show that the addition of steel slag can promote the vulcanization of the compounded rubber by shortened the scorch time (t10) and curing time (t90). Addition of an appropriate amount of steel slag (10 phr) leads to an increase in the tensile strength and elongation at break of the compounded rubber. As the amount of steel slag further increased, the tensile strength and elongation at break of the compounded rubber decreased gradually, whereas the hardness and volume fraction of abrasion of compounded rubber increased. Compared with the compounded rubber without steel slag filled,the t10 and t90 of KH-550 modified steel slag filled compounded rubber decreased; the t10 and t90 of the compounded rubber with Si-69 and CS-105 modified steel slag improved. The tensile strength and the elongation at break of the compounded rubber filled with the modified steel slag increased and the volume fraction of abrasion decreased compared with the compounded rubber filled with the unmodified steel slag. The SEM results elaborate that the compatibility of modified steel slag and compounded rubber is improved.
Key words:  steel slag    compounded rubber    surface modification
               出版日期:  2018-03-25      发布日期:  2018-03-25
ZTFLH:  X757  
通讯作者:  王正洲,男,1963年生,博士,教授,博士研究生导师,主要从事聚合物阻燃、聚合物纳米复合材料等方面研究 E-mail:zwang@tongji.edu.cn   
作者简介:  沈海洋:男,1991年生,硕士研究生,主要从事有机/无机复合材料的研究 E-mail:1531556@tongji.edu.cn
引用本文:    
沈海洋, 王正洲. 钢渣的表面改性及其在橡胶中应用研究[J]. 材料导报, 2018, 32(6): 1000-1003.
SHEN Haiyang, WANG Zhengzhou. Surface Modification of Steel Slag and Its Application in Compounded Rubber. Materials Reports, 2018, 32(6): 1000-1003.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.06.027  或          http://www.mater-rep.com/CN/Y2018/V32/I6/1000
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