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材料导报  2018, Vol. 32 Issue (6): 1000-1003    https://doi.org/10.11896/j.issn.1005-023X.2018.06.027
  材料研究 |
钢渣的表面改性及其在橡胶中应用研究
沈海洋1, 王正洲1, 2
1 同济大学材料科学与工程学院,上海 201804;
2 先进土木工程材料教育部重点实验室(同济大学),上海 201804
Surface Modification of Steel Slag and Its Application in Compounded Rubber
SHEN Haiyang1, WANG Zhengzhou1, 2
1 School of Materials Science and Engineering, Tongji University, Shanghai 201804;
2 Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804
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摘要 研究了钢渣对天然橡胶、丁苯橡胶和顺丁橡胶复合橡胶的硫化性能和力学性能的影响。结果表明:钢渣的加入使得复合橡胶的焦烧时间(t10)和正硫化时间(t90)缩短,对复合橡胶的硫化具有一定的促进作用。添加适量(10份)的钢渣可以提高复合橡胶的拉伸强度和扯断伸长率,随着钢渣用量继续增加,复合橡胶的拉伸强度和扯断伸长率逐渐降低。复合橡胶的硬度和磨耗量随钢渣添加量的增加而逐渐增大。与未改性钢渣相比,添加硅烷偶联剂KH-550改性钢渣的复合橡胶的t10t90均有一定缩短;添加硅烷偶联剂Si-69和钛酸酯偶联剂CS-105改性钢渣的复合橡胶的t10t90均有一定延长;改性钢渣填充的复合橡胶的拉伸强度和扯断伸长率都有所提高、磨耗量降低。SEM结果表明,改性钢渣与复合橡胶的相容性得到提高。
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沈海洋
王正洲
关键词:  钢渣  复合橡胶  表面改性    
Abstract: The influence of steel slag on curing characteristics and mechanical properties of a compounded rubber i.e. natural rubber, styrene-butadiene rubber and butadiene rubber was studied. The results show that the addition of steel slag can promote the vulcanization of the compounded rubber by shortened the scorch time (t10) and curing time (t90). Addition of an appropriate amount of steel slag (10 phr) leads to an increase in the tensile strength and elongation at break of the compounded rubber. As the amount of steel slag further increased, the tensile strength and elongation at break of the compounded rubber decreased gradually, whereas the hardness and volume fraction of abrasion of compounded rubber increased. Compared with the compounded rubber without steel slag filled,the t10 and t90 of KH-550 modified steel slag filled compounded rubber decreased; the t10 and t90 of the compounded rubber with Si-69 and CS-105 modified steel slag improved. The tensile strength and the elongation at break of the compounded rubber filled with the modified steel slag increased and the volume fraction of abrasion decreased compared with the compounded rubber filled with the unmodified steel slag. The SEM results elaborate that the compatibility of modified steel slag and compounded rubber is improved.
Key words:  steel slag    compounded rubber    surface modification
出版日期:  2018-03-25      发布日期:  2018-03-25
ZTFLH:  X757  
通讯作者:  王正洲,男,1963年生,博士,教授,博士研究生导师,主要从事聚合物阻燃、聚合物纳米复合材料等方面研究 E-mail:zwang@tongji.edu.cn   
作者简介:  沈海洋:男,1991年生,硕士研究生,主要从事有机/无机复合材料的研究 E-mail:1531556@tongji.edu.cn
引用本文:    
沈海洋, 王正洲. 钢渣的表面改性及其在橡胶中应用研究[J]. 材料导报, 2018, 32(6): 1000-1003.
SHEN Haiyang, WANG Zhengzhou. Surface Modification of Steel Slag and Its Application in Compounded Rubber. Materials Reports, 2018, 32(6): 1000-1003.
链接本文:  
https://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.06.027  或          https://www.mater-rep.com/CN/Y2018/V32/I6/1000
1 Wang Q, Yan P, Wang Q, et al. Hydration properties of basic oxygen furnace steel slag[J].Construction & Building Materials,2010,24(7):1134.
2 Yi H, Xu G, Cheng H, et al. An overview of utilization of steel slag[J].Procedia Environmental Sciences,2012,16(4):791.
3 Yang Y L, Wu J M, Zhang J Q. Research on mix design and pavement performance of SMA-13 asphalt mixture with steel slag[J].Road Machinery & Construction Mechanization,2016(7):36(in Chinese).
杨永利,武建民,张建强.钢渣SMA-13型沥青混合料配合比设计及路用性能研究[J].筑路机械与施工机械化,2016(7):36.
4 Pan S Y, Adhikari R, Chen Y H, et al. Integrated and innovative steel slag utilization for iron reclamation, green material production and CO2, fixation via accelerated carbonation[J].Journal of Cleaner Production,2016,137:617.
5 Yang Q L, Yao Y F, Gao L, et al. Application of the coupling agent on SLAG/GF/PVC composites[J].Journal of Zhejiang Sci-Tech University,2009,26(1):12(in Chinese).
杨琼丽,姚跃飞,高磊,等.偶联剂在SlAG/GF/PVC复合材料中的应用[J].浙江理工大学学报,2009,26(1):12.
6 Guzel G, Deveci H. Properties of polymer composites based on bisphenol a epoxy resins with original/modified steel slag[J].Polymer Composites,http:∥onlinelibrary.wiley.com/doi/10.1002/pc.23962/full.
7 Tong Z, Ma G, Cai X, et al. Characterization and valorization of kanbara reactor desulfurization waste slag of hot metal pretreatment[J].Waste and Biomass Valorization,2016,7(1):1.
8 Wang X M, Wu W B, Wang Y, et al. Study on application of nano-magnesium hydroxide in SBR/NR blend[J].Special Purpose Rubber Products,2008,29(2):20(in Chinese).
王晓明,吴文彪,王雅,等.纳米氢氧化镁在SBR/NR并用胶中的应用研究[J].特种橡胶制品,2008,29(2):20.
9 Bansod N D, Kapgate B P, Das C, et al. Compatibilization of natural rubber/nitrile rubber blends by sol-gel nano-silica generated by in situ method[J].Journal of Sol-Gel Science and Technology,2016,80(2):1.
10 Wang S, Zhang Y, Ren W, et al. Morphology, mechanical and optical properties of transparent BR/clay nanocomposites[J].Polymer Testing,2005,24(6):766.
11 Li Z Q. Study on effect of coupling agent modified CeO2 on reinforcing natural rubber[D].Baotou:Inner Mongolia University of Science and Technology, 2015(in Chinese).
李志强. 偶联剂改性氧化铈补强天然橡胶的研究[D].包头:内蒙古科技大学,2015.
12 Chen J, Xu K, Yang R M, et al. Study on properties of NR reinforced by modified graphite gangue powder[J].China Rubber Industry,2013,60(1):29(in Chinese).
陈静,许逵,杨日敏,等.改性石墨矸石粉补强天然橡胶性能的研究[J].橡胶工业,2013,60(1):29.
13 Ismail H, Othman N, Komethi M. Curing characteristics and mechanical properties of rattan-powder-filled natural rubber composites as a function of filler loading and silane coupling agent[J].Journal of Applied Polymer Science,2012,123(5):2805.
14 Li X X, Yang C Y, Li N, et al. Application of wet modified kaolin and different fillers in SBR[J].Special Purpose Rubber Products,2016(5):33(in Chinese).
李晓晓,杨春影,李楠,等.湿法改性高岭土与不同填料在SBR中的应用[J].特种橡胶制品,2016(5):33.
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