Microwave Hydrothermal Synthesis of Sulfonate Gemini Surfactant and Its Characterization
LYU Bin1,2, YU Yajin1,2, GAO Dangge1,2, MA Jianzhong1,2, SU Jiaojiao1
1 College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi’an 710021 2 National Educational Reform Experimental Demonstration Center, Xi’an 710021
Abstract: Dodecanoic monoethanolamide maleate diester was firstly synthesized by microwave hydrothermal method with dodecanoic acid monoethanolamide and maleic acid monoester as raw materials. Then, dicarboxylic acid monoethanolamide sulfosuccinic diester was obtained after sulfonation treatment by NaHSO3. Finally, Gemini surfactant was achieved via tertiary amination of-CH2ClCOOH. Single factor experiments were conducted for the sake of optimizing synthetic process parameters. Moreover, FT-IR and 1H NMR were employed to characterized the structure of the sulfonate Gemini surfactant. The surface tension, wettability and emulsifying properties of the surfactant were also investigated. The results revealed that the prepared sulfonate Gemini surfactant was endowed with a critical micelle concentration of 1.61×10-4 mol/L, γCMC of 36.7 mN/m, wetting time of 8.87 s, and emulsification time of 415 s. Compared with the traditional methods, microwave hydrothermal synthesis of sulfo-nate Gemini surfactant featured by short reaction time and Simple operation.
1 Hou L. Synthesis and properties of dissymmetry nonionic-anionic Gemini surfactants. Master’s thesis, North University of China, China,2014(in Chinese). 侯璐.阴离子-非离子型不对称Gemini表面活性剂的合成与性能研究.硕士学位论文,中北大学,2014. 2 Lai L, Mei P, Wu X M, et al. Colloid & Polymer Science,2014,292(11),2821. 3 Ma J, Yun C, Liu L. Journal of the Society of Leather Technologists & Chemists,2005,89(2),80. 4 Naveen Kumar, Rashmi Tyagi. Journal of Dispersion Science & Techno-logy,2014,35(2),205. 5 Ma J Z. Synthetic principles and application technology of leather chemicals, China Light Industry Press,China,2009(in Chinese). 马建中.皮革化学品的合成原理与应用技术.中国轻工业出版社,2009. 6 Bin L, Wang H D, Jian-Zhong M A, et al. China Surfactant Detergent & Cosmetics,2014,44(6),343. 7 Mei P, Lai L, Zheng C Y. Synthesis and properties of Gemini surfactants, Chemical Industry Press, China,2014(in Chinese) 梅平,赖璐,郑延成.Gemini表面活性剂的合成及性能研究,化学工业出版社,2014. 8 Mei P, Lai L, Chen W, et al. Chemistry & Bioengineering,2009,26(2),1(in Chinese). 梅平,赖璐,陈武,等.化学与生物工程,2009,26(2),1. 9 Ge L. Chemical Enterprise Management,2017(20),127(in Chinese) 葛蕾.化工管理,2017(20),127. 10 Zheng M, Mo L, Qin R, et al. In:2016 International Conference on Materials Science, Resource and Environmental Engineering. Xi’an,2017,pp.030008. 11 Wang P, Shen Y. Dyeing & Finishing,2015(22),52(in Chinese). 汪萍,沈勇.印染,2015(22),52. 12 Ye J, Hua P, Fang L. Guangdong Chemical Industry,2011,38(5),7(in Chinese). 叶俊,华平,方略韬.广东化工,2011,38(5),7. 13 Hu X, Hou M, Hu W. Chemical Engineering of Oil & Gas,2011,40(5),494. 14 Zhou M, Zhao J, Liu J, et al. Chinese Journal of Applied Chemistry,2011,28(8),15023. 15 Zhang Q, Tian M, Han Y, et al. Journal of Colloid & Interface Science,2011,362(2),406. 16 Jia J Y. Synthesis and properties of succinate sulfonate Gemini surfactant. Master’s thesis, Liaoning Normal University,China,2012(in Chinese). 贾金英.琥珀酸酯磺酸盐型Gemini表面活性剂的合成及性能研究,硕士学位论文,辽宁师范大学,2012. 17 Zhou M, Xia L, He Y, et al. Journal of Surfactants & Detergents,2015,18(2),303. 18 Wei S I, Huang M Y, Ding S Q, et al. Bulletin of the Chinese Ceramic Society,2013,32(5),868. 19 Guo N N. Chemical Research & Application,2017,29(4),441(in Chinese). 郭乃妮.化学研究与应用,2017,29(4),441. 20 Zheng X. Inorganic Chemicals Industry,2009,41(8),9(in Chinese). 郑兴芳.无机盐工业,2009,41(8),9. 21 吕斌,王泓棣,马建中,等.中国,CN106117090,2016. 22 Chen H, Zhu B. Journal of Surfactants & Detergents,2014,17(5),937.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2019, Vol. 33 
