Research Progress on Chemical Modification and Application of Zein
XU Qunna1,2,3, BAI Zhongxue1,2,3, MA Jianzhong1,2,3
1 National Demonstration Center for Experimental Light Chemistry Engineering Education, College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi'an 710021, China; 2 Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry & Technology, Shaanxi University of Science & Technology, Xi'an 710021, China; 3 Shaanxi Research Institute of Agricultural Products Processing Technology, Xi'an 710021, China;
Abstract: As the main protein in corn, zein is widely available and renewable. Zein owns a large number of hydrophobic amino acids and its structure changes with the change of environment. Zein has unique solubility, good film-forming property, good biocompatibility, and good self-assembly property, but it also has certain defects, including:(Ⅰ) the mechanical properties of zein films are poor; (Ⅱ) the hydrophilicity of zein nano/micro particles is not good; (Ⅲ) the stability of zein nano/micro particles need to be improved, etc. These defects have limited the development and application of zein, therefore many researchers have carried out the studies of modification on zein in the past decades. Now, the modification methods of zein include physical and chemical modifications. Chemistry modification changes the molecular composition or structure of zein to improve its properties, but it requires the addition of exogenous substances and the accurate operations. Zein has been modified in series to improve its existing defects and provide certain functions, making zein gradually applied in many industries, including: (Ⅰ) it can be used in degradable films, fibers and adhesives in chemical field; (Ⅱ) it can be used as food ingredients and food packaging in food field; (Ⅲ) it can also be used as corn active peptides, drug carriers and scaffolds in medical field. This article briefly discusses the advantages and disadvantages of chemical modification in the functionalization research of zein. What's more, this article summarizes the chemical modification research progress of zein, and its application in food, pharmaceutical and chemical industries. Finally, based on our previous research, the future functionalization and application prospects of zein are prospected.
徐群娜, 白忠薛, 马建中. 玉米醇溶蛋白的化学改性及应用研究进展[J]. 材料导报, 2021, 35(3): 3194-3203.
XU Qunna, BAI Zhongxue, MA Jianzhong. Research Progress on Chemical Modification and Application of Zein. Materials Reports, 2021, 35(3): 3194-3203.
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2021, Vol. 35 
