N-杂环卡宾活化二氧化碳的研究进展

doi:10.11896/cldb.20020109

材料导报

2021, Vol. 35

Issue (9): 9196-9209 https://doi.org/10.11896/cldb.20020109

高分子与聚合物基复合材料

N-杂环卡宾活化二氧化碳的研究进展

陈恩丽, 段俊新^*, 谢智中

武汉理工大学化学化工与生命科学学院,武汉 430070

Research Progress on N-heterocyclic Carbene Activating Carbon Dioxide

CHEN Enli, DUAN Junxin^*, XIE Zhizhong

School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, China

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摘要随着经济的快速发展,二氧化碳的排放量越来越大,温室效应日益明显。为降低空气中二氧化碳含量甚至有效开发利用二氧化碳,化学工作者们尝试了各种策略并取得了一定成果。其中之一就是使用N-杂环卡宾金属配合物将二氧化碳活化,使之转化为高附加值的化工原料或燃料,从而实现能量存储和碳资源的循环利用。本文总结了利用N-杂环卡宾(NHCs, N-Heterocyclic Carbenes)与Cu、Pd、Ag等过渡金属的配合物活化二氧化碳和催化二氧化碳与有机物的反应方面的研究进展,并对其发展和应用前景进行了展望。

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	陈恩丽
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关键词: N-杂环卡宾 CO₂活化过渡金属

Abstract: The continuously increasing CO₂ emission, as all known harmful to the global environment and responsible for the greenhouse effect, have raised worldwide researches aiming to reduce CO₂ content in the atmosphere or even to effectively utilize CO₂. One of the various potential approaches is using N-heterocyclic Carbenes (NHCs) and its metal complexes to activate CO₂, and convert it into chemical raw materials or fuels so as to achieve the purpose of recycling carbon resources. This review gives a summary of the research progress in applying NHC and its complexes with transition metals Cu, Pd and Ag to the activating CO₂ and catalyzing reactions of CO₂ and organic compounds such as alkenes and alkynes. It ends with a critical analysis of the developmental prospects of this field.

Key words: N-heterocyclic Carbene carbon dioxide activation transition metal

出版日期: 2021-05-10 发布日期: 2021-05-31

ZTFLH:	O621.3
	O657.3

基金资助: 武汉理工大学自主创新研究基金项目(2019-IB-025)

通讯作者: duanjunxin994@163.com

作者简介: 陈恩丽,2015年6月毕业于武汉理工大学,获得理学学士学位。现为武汉理工大学化学化工与生命科学学院研究生,在谢智中教授的指导下进行研究。目前主要从事金属卡宾催化二氧化碳还原机理的理论研究。
谢智中,武汉理工大学化学化工与生命科学学院教授、博士研究生导师。2001年7月毕业于安徽师范大学化学系,2006年7月在北京师范大学化学学院物理化学专业取得博士学位,2006—2009年在新加坡南洋理工大学进行博士后研究工作。2009年4月进入武汉理工大学化学系工作,主要从事化学反应机理的理论研究。近年来在金属有机和能源领域发表论文70余篇,包括 Organometallics、 Physical Chemistry Chemical Physics、 Chemistry-A European Journal等。
段俊新,武汉理工大学化学化工与生命科学学院教师。2008年7月毕业于长治大学化学系,2019年1月在武汉理工大学材料科学与工程学院材料化学专业取得博士学位,并留校任教,主要从事化学反应机理的理论研究。近年来在金属有机和能源领域发表论文6篇,包括Organometallics、 Physical Chemistry Chemical Physics等。

引用本文:

陈恩丽, 段俊新, 谢智中. N-杂环卡宾活化二氧化碳的研究进展[J]. 材料导报, 2021, 35(9): 9196-9209.
CHEN Enli, DUAN Junxin, XIE Zhizhong. Research Progress on N-heterocyclic Carbene Activating Carbon Dioxide. Materials Reports, 2021, 35(9): 9196-9209.

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http://www.mater-rep.com/CN/10.11896/cldb.20020109 或 http://www.mater-rep.com/CN/Y2021/V35/I9/9196

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