Carbon Nanomaterials Supported Transition Metal Oxides as Supercapacitor Electrodes: a Review
LIU Minmin1,2,3†, CAI Chao1†, ZHANG Zhijie1, LIU Rui1,3,4
1 Ministry of Education Key Laboratory of Advanced Civil Engineering Material, College of Materials Science and Engineering, Tongji University, Shanghai 201804 2 Institute of Sustainable Energy,Shanghai University, Shanghai 200444 3 Institute for Advanced Study, Tongji University, Shanghai 200092 4 State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure, Chinese Academy of Sciences, Fuzhou 350002
Abstract: Compared with traditional energy storage devices, supercapacitors have been a research hot spot and diffusely adopted in the fields of mobile telecommunication, electric vehicle, aviation and national defense due to their high specific capacitance, high charge-discharge rate, environment-friendly and excellent cycling stability, etc. Among them, the electrode materials of the supercapacitors play a crucial role on their performances, and common electrode materials used for supercapacitors mainly include carbon materials, transition metal oxides, and conducting polymers. Different materials have diverse charge storage mechanisms. Transition metal oxides exhibit typical pseudo-capacitance behavior, which depends on reversible redox reaction and chemical adsorption/desorption process to store charge. However, transition metal oxides have poor conductivity and cycle stability. Carbon materials mainly performed the characteristics of electrochemical double layer capacitance are relied on the reversible physical adsorption/desorption process between the material surface and electrolyte ions to store energy. In addition, carbon materials possess superb rate capability, conforming to the high requirements of the device lifetime for practical application, while the specific capacitance is relatively low. The composite materials generally exhibit superior electrochemical properties than that of the single component materials. Massive studies indicated that the composite of transition metal oxides and carbon materials was an effective method to solve the above-mentioned problems. As the preferential substrate materials for the construction of pseudo-supercapacitor, carbon materials with the advantages of rich resource, low cost, light weight, high specific surface area, thermal and chemical stabilities have attracted increasingly attention. Moreover, carbon materials with various structures including zero dimensional (carbon dot and sphere), one dimensional (carbon tube and fiber), two dimensional (graphene and graphene oxide), three dimensional (graphene foam and carbon foam/sponge) carbon materials, etc, have been successfully applied to fabricate carbon-based composite electrode materials and have scored great successes, Zero-dimensional carbon nanomaterials with high specific surface area can provide flexibility to adjust porosity and obtain the optimal condition of respective electrolyte solution. One-dimensional nanostructures with high aspect ratio structure and excellent electronic or ionic transport properties can promote the charge transfer of supercapa-citor electrodes. For two-dimensional carbon nanomaterials, their high specific surface area, admirable conductivity and superb mechanical pro-perties make them a potential pseudo-supercapacitor and enhance the charge-discharge reaction kinetics between the supercapacitor electrodes. High-performance supercapacitor electrodes can be constructed by utilizing three-dimensional nanomaterials as templates and depositing pseudo-supercapacitor materials. This article summarizes the capacitive properties of transition metal oxide loaded on different dimensional carbon materials as electrode mate-rials of pseudo-supercapacitor, and overviews their disadvantages in energy storage and future research directions, in order to provide a refe-rence for preparing a high-performance, environmental-friendly and long-life supercapacitor.
Wang F, Wu X, Yuan X, et al. Chemical Society Reviews,2017,46(22),6816.2 Winter M, Brodd R J. Chemical Reviews,2004,104,4245.3 Zhang L L, Zhao X S. Chemical Society Reviews,2009,38(9),2520.4 Zhi M, Xiang C, Li J, et al. Nanoscale,2013,5(1),72.5 Dubal D P, Ayyad O, Ruiz V, et al. Chemical Society Reviews,2015,44(7),1777.6 Pan H, Li J, Feng Y P. Nanoscale Research Letters,2010,5(3),654.7 Yu Z, Tetard L, Zhai L, et al. Energy & Environmental Science,2015,8(3),702.8 Meng Q, Cai K, Chen Y, et al. Nano Energy,2017,36,268.9 Wang J, Wang J, Kong Z, et al. Advanced Materials,2017,29(45),1703044.10 Kim M, Lee C, Jang J.Advanced Functional Materials,2014,24(17),2489.11 Raj C J, Rajesh M, Manikandan R, et al. Electrochimica Acta,2017,247,949.12 Zhang Y, Zhang H, Fang L, et al. Electrochimica Acta,2017,245,32.13 Raj C R, Bag S. Journal of Materials Chemistry A,2015,4(2),587.14 Phattharasupakun N, Wutthiprom J, Chiochan P, et al. Chemical Communications,2016,52(12),2585.15 Liang K, Tang X, Hu W. Journal of Materials Chemistry,2012,22(22),11062.16 Wu Z S, Wang D W, Ren W, et al. Advanced Functional Materials,2010,20(20),3595.17 Lin J, Liu Y, Wang Y, et al. Journal of Power Sources,2017,362,64.18 Pang H, Li X, Zhao Q, et al. Nano Energy,2017,35,138.19 Nguyen V H, Shim J J. Journal of Power Sources,2015,273,110.20 Wu P, Cheng S, Yao M, et al. Advanced Functional Materials,2017,27(34),1702160.21 Shen L, Wang J, Xu G, et al. Advanced Energy Materials,2015,5(3),1400977.22 Guan C, Liu X, Ren W, et al. Advanced Energy Materials,2017,7(8),1602391.23 Mondal A, Maiti S, Mahanty S, et al. Journal of Materials Chemistry A,2017,5(32),16854.24 He S, Chen W. Nanoscale,2015,7(16),6957.25 Li L, Wu Z, Yuan S, et al. Energy & Environmental Science,2014,7(7),2101.26 Huang G, Zhang Y, Wang L, et al. Carbon,2017,125,595.27 Tseng L H, Hsiao C H, Nguyen D D, et al. Electrochimica Acta,2018,266,284.28 Borenstein A, Hanna O, Ran A, et al. Journal of Materials Chemistry A,2017,5(25),12653.29 Chen X, Paul R, Dai L. National Science Review,2017,3,453.30 Barbieri O, Hahn M, Herzog A, et al. Carbon,2005,43(6),1303.31 Liu T, Jiang C, You W, et al. Journal of Materials Chemistry A,2017,5(18),8635.32 Chang J, Jin M, Yao F, et al. Advanced Functional Materials,2013,23(40),5074.33 Lv Z, Luo Y, Tang Y, et al. Advanced Materials,2017,30(2),1704531.34 Yuan A, Zhang Q. Electrochemistry Communications,2006,8(7),1173.35 Toupin M,Brousse T,Belanger D.Chemistry of Materials,2004,16,3184.36 Lota K, Sierczynska A, Lota G. International Journal of Electrochemistry,2011,2011,321473. 37 Ma H, He J, Xiong D B, et al. ACS Applied Materials & Interfaces,2016,8(3),1992.38 Zhu S J, Li L, Liu J B, et al. ACS Nano,2018,12(2),1033.39 Guo M, Balamurugan J, Li X, et al. Small,2017,13(33),1701275.40 Li C, Balamurugan J, Kim N H, et al. Advanced Energy Materials,2017,8(8),1702014.41 Xiong T, Tan T L, Lu L, et al. Advanced Energy Materials,2018,8(14),1702630.42 Li S, Yu C, Yang J, et al. Energy & Environmentalence,2017,10(9),1958.43 Liu W W, Feng Y Q, Yan X B, et al. Advanced Functional Materials,2013,23(33),4111.44 Peng X. Chemical Society Reviews,2014,43(10),3303.45 Wang G P, Zhang L, Zhang J J. Chemical Society Reviews,2012,41(2),797.46 Li M, Zu M, Yu J, et al. Small,2017,13(12),1602994.47 Yu N, Yin H, Zhang W, et al. Advanced Energy Materials,2016,6(2),1501458.48 Sun P, Yi H, Peng T, et al. Journal of Power Sources,2017,341,27.49 Hu C C, Wang C W, Chang K H, et al. Nanotechnology,2015,26(27),274004.50 Xie L, Su F, Xie L, et al. Chemsuschem,2015,8(17),2917.51 Han Z, Pineda S, Murdock A T, et al. Journal of Materials Chemistry A,2017,5(33),17293. 52 Liu Y, Miao X, Fang J, et al. ACS Applied Materials & Interfaces,2016,8(8),5251.53 Wang X, Wan F, Zhang L, et al. Advanced Functional Materials,2018,28(18),1707247.54 Li H, Jiang L, Cheng Q, et al. Electrochimica Acta,2015,164,252.55 He S, Hou H, Chen W. Journal of Power Sources,2015,280,678.56 Chen J, Xu J, Zhou S, et al. Nano Energy,2016,25,193.57 Du P, Liu H C, Yi C, et al. ACS Applied Materials & Interfaces,2015,7(43),23932.58 Yao M, Zhao X, Jin L, et al. Chemical Engineering Journal,2017,322,582.59 Dong X C, Xu H, Wang X W, et al. ACS Nano,2012,6(4),3206.60 Lin M C, Gong M, Lu B, et al. Science Foundation in China,2015,520(4),325.61 Wang Y, Chen J, Cao J, et al. Journal of Power Sources,2014,271,269.62 Lu Z, Foroughi J, Wang C, et al. Advanced Energy Materials,2017,8(8),1702047.63 Mo M, Chen C, Gao H, et al. Electrochimica Acta,2018,269,11.64 Choi J H, Lee C, Cho S, et al. Carbon,2018,132,16.65 Li X, Tang Y, Song J, et al. Carbon,2017,129,236.66 Malik R, Zhang L, Mcconnell C, et al. Carbon,2017,116,579.67 Ma X, Liu J, Liang C, et al. Journal of Materials Chemistry A,2014,2(32),12692.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2019, Vol. 33 
