Flexibility and Microminiaturization of Electrode Materials and Devices for Supercapacitor
DONG Wenju1, KONG Lingbin1,2, KANG Long1,2, RAN Fen1,2
1 Materials Science and Engineering College, Lanzhou University of Technology, Lanzhou 730050; 2 State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050
Abstract: With the rapid development of wearable electronic devices, various kinds of flexible energy storage devices have emerged. Flexible supercapacitor has aroused extensive interests of researchers thanks to its high stability, small size and excellent electrochemical performance. It is of great significance to develop an electrode with simple process, favorable electrochemical performance and satisfactory flexibility for the preparation of flexible supercapacitors with superior performance. Material selection, electrode preparation and device miniaturization will be the main research direction in the future. This article mainly reviews the classification of electrode materials, the specific preparation methods and the primary configuration of the devices, and discusses the main development direction and research focus of electrode materials and devices for flexible supercapacitors.
董文举, 孔令斌, 康龙, 冉奋. 超级电容器电极材料及器件的柔性化与微型化[J]. 材料导报, 2018, 32(17): 2912-2919.
DONG Wenju, KONG Lingbin, KANG Long, RAN Fen. Flexibility and Microminiaturization of Electrode Materials and Devices for Supercapacitor. Materials Reports, 2018, 32(17): 2912-2919.
1 Wang X, Lu X, Liu B, et al. Flexible energy-storage devices: Design consideration and recent progress[J].Advanced Materials,2014,26(28):4763.
2 Choudhary N, Li C, Moore J, et al. Asymmetric supercapacitor electrodes and devices[J].Advanced Materials,2017,29(21):1605336.
3 Zuo W, Li R, Zhou C, et al. Battery-supercapacitor hybrid devices: Recent progress and future prospects[J].Advanced Science,2017,4(7):1600539.
4 Yu Z, Tetard L, Zhai L, et al. Supercapacitor electrode materials: Nanostructures from 0 to 3 dimensions[J].Energy & Environmental Science,2015,8(3):702.
5 Liu W, Song M S, Kong B, et al. Flexible and stretchable energy storage: Recent advances and future perspectives[J].Advanced Materials,2017,29(1):1603436.
6 Yan J, Wang Q, Wei T, et al. Recent advances in design and fabrication of electrochemical supercapacitors with high energy densities[J].Advanced Energy Materials,2014,4(4):1300816.
7 Makino S, Yamauchi Y, Sugimoto W. Synthesis of electro-deposited ordered mesoporous RuOx using lyotropic liquid crystal and application toward micro-supercapacitors[J].Journal of Power Sources,2013,227(227):153.
8 Wang F, Li G, Zhou Q, et al. One-step hydrothermal synthesis of sandwich-type NiCo2S4@reduced graphene oxide composite as active electrode material for supercapacitors[J].Applied Surface Science,2017,425:180.
9 Tan Y, Zhang Y, Kong L, et al. Nano-Au@PANI core-shell nano-particles via in-situ polymerization as electrode for supercapacitor[J].Journal of Alloys and Compounds,2017,722:1.
10 Chen T, Elabd Y A. Hybrid-capacitors with polyaniline/carbon electrodes fabricated via simultaneous electrospinning/electrospraying[J].Electrochimica Acta,2017,229:65.
11 Liu C, Tan Y, Liu Y, et al. Microporous carbon nanofibers prepared by combining electrospinning and phase separation methods for supercapacitor[J].Journal of Energy Chemistry,2016,25(4):587.
12 Lu X, Yu M, Wang G, et al. Flexible solid-state supercapacitors: Design, fabrication and applications[J].Energy & Environmental Science,2014,7(7):2160.
13 Chen X L, Paul R, Dai L M. Carbon-based supercapacitors for efficient energy storage[J].National Science Review,2017,4(3):453.
14 Xiao X, Peng X, Jin H, et al. Freestanding mesoporous VN/CNT hybrid electrodes for flexible all-solid-state supercapacitors[J].Advanced Materials,2013,25(36):5091.
15 Niu Z, Luan P, Shao Q, et al. A “skeleton/skin” strategy for preparing ultrathin free-standing single-walled carbon nanotube/polya-niline films for high performance supercapacitor electrodes[J].Energy & Environmental Science,2012,5(9):8726.
16 Benson J, Kovalenko I, Boukhalfa S, et al. Multifunctional CNT-polymer composites for ultra-tough structural supercapacitors and desalination devices[J].Advanced Materials,2013,25(45):6625.
17 Li Z, Huang T, Gao W, et al. Hydrothermally activated graphene fiber fabrics for textile electrodes of supercapacitors[J].ACS Nano,2017,11(11):11056.
18 Hu N, Zhang L, Yang C, et al. Three-dimensional skeleton networks of graphene wrapped polyaniline nanofibers: An excellent structure for high-performance flexible solid-state supercapa-citors[J].Scientific Reports,2016,6:19777.
19 Yang Y, Huang Q, Niu L, et al. Waterproof, ultrahigh areal-capacitance, wearable supercapacitor fabrics[J].Advanced Materials,2017,29(19):1606679.
20 Zhu J, Tang S, Wu J, et al. Wearable high-performance supercapa-citors based on silver-sputtered textiles with FeCo2S4-NiCo2S4 composite nanotube-built multitripod architectures as advanced flexible electrodes[J].Advanced Energy Materials,2017,7(2):1601234.
21 Jin C, Jin L N, Guo M X, et al. MnO2 nanotubes assembled on conductive graphene/polyester composite fabric as a three-dimensional porous textile electrode for flexible electrochemical capacitors[J].Journal of Colloid and Interface Science,2017,508:426.
22 Yuan L, Yao B, Hu B, et al. Polypyrrole-coated paper for flexible solid-state energy storage[J].Energy & Environmental Science,2013,6(2):470.
23 Chen Y, Cai K, Liu C, et al. High-performance and breathable polypyrrole coated air-laid paper for flexible all-solid-state supercapacitors[J].Advanced Energy Materials,2017,7(21):1701247.
24 Xia X H, Tu J P, Zhang Y Q, et al. Three-dimentional porous nano-Ni/Co(OH)2 nanoflake composite film: A pseudocapacitive material with superior performance[J].The Journal of Physical Chemistry C,2011,115(45):22662.
25 Huang Y, Li Y, Hu Z, et al. A carbon modified MnO2 nanosheet array as a stable high-capacitance supercapacitor electrode[J].Journal of Materials Chemistry A,2013,1(34):9809.
26 Fu Y, Cai X, Wu H, et al. Fiber supercapacitors utilizing pen ink for flexible/wearable energy storage[J].Advanced Materials,2012,24(42):5713.
27 Li Y, Sheng K, Yuan W, et al. A high-performance flexible fibre-shaped electrochemical capacitor based on electrochemically reduced graphene oxide[J].Chemical Communications,2013,49(3):291.
28 Liu G, Zhang Y, Ci S, et al. Research progress on flexible electrochemical energy storage devices[J].Energy Storage Science & Technology,2017,6(1):52(in Chinese).
刘冠伟,张亦弛,慈松,等.柔性电化学储能器件研究进展[J].储能科学与技术,2017,6(1):52.
29 Huang Wei, Fu Zhibing, Zhu Jiayi, et al. Research development in preparation of graphene/carbon nanotube hybrid films[J].Materials Review,2016,30(z1):24(in Chinese).
黄维,付志兵,朱家艺,等.石墨烯/碳纳米管复合薄膜的制备研究进展[J].材料导报,2016,30(专辑27):24.
30 Niu Z, Dong H, Zhu B, et al. Highly stretchable, integrated supercapacitors based on single-walled carbon nanotube films with conti-nuous reticulate architecture[J].Advanced Materials,2013,25(7):1058.
31 Zang X, Chen Q, Li P, et al. Highly flexible and adaptable, all-solid-state supercapacitors based on graphene woven-fabric film electrodes[J].Small,2014,10(13):2583.
32 Chen L, Liu C, Zhang Z. Novel [111] oriented γ-Mo2N thin films deposited by magnetron sputtering as an anode for aqueous micro-supercapacitors[J].Electrochimica Acta,2017,245:237.
33 Chen X, Lin H, Deng J, et al. Electrochromic fiber-shaped supercapacitors[J].Advanced Materials,2014,26(48):8126.
34 Li Xiang, Gan Weiping, Ma Heran. RuO2·xH2O electrode mate-rials prepared by rotation coating method and investigation on its properties[J].Journal of Functional Materials,2011,42(2):339(in Chinese).
李祥,甘卫平,马贺然.旋转涂覆法制备氧化钌电极材料及其性能研究[J].功能材料,2011,42(2):339.
35 Sundriyal P, Bhattacharya S. Inkjet-printed electrodes on A4 paper substrates for low-cost, disposable, and flexible asymmetric supercapacitors[J].ACS Applied Materials & Interfaces,2017,9(44):38507.
36 Xu Y, Schwab M G, Strudwick A J, et al. Screen-printable thin film supercapacitor device utilizing graphene/polyaniline inks[J].Advanced Energy Materials,2013,3(8):1035.
37 Li J, Shao Y, Shi Q, et al. Calligraphy-inspired brush written fol-dable supercapacitors[J].Nano Energy,2017,38:428.
38 Jeong H T, Kim B C, Higgins M J, et al. Highly stretchable reduced graphene oxide (rGO)/single-walled carbon nanotubes (SWNTs) electrodes for energy storage devices[J].Electrochimica Acta,2015,163:149.
39 Jin Yu, Yao Hui, Chen Minghai, et al. Electrospinning application in supercapacitors[J].Materials Review A: Review Papers,2011,25(8):21(in Chinese).
靳瑜,姚辉,陈名海,等.静电纺丝技术在超级电容器中的应用[J].材料导报:综述篇,2011,25(8):21.
40 Iqbal N, Wang X, Babar A A, et al. Polyaniline enriched flexible carbon nanofibers with core-shell structure for high-performance wearable supercapacitors[J].Advanced Materials Interfaces,2017,4(24):1700855.
41 Simotwo S K, DelRe C, Kalra V. Supercapacitor electrodes based on high-purity electrospun polyaniline and polyaniline-carbon nanotube nanofibers[J].ACS Applied Materials & Interfaces,2016,8(33):21261.
42 Ko Y, Kim D, Kim U J, et al. Vacuum-assisted bilayer PEDOT:PSS/cellulose nanofiber composite film for self-standing, flexible, conductive electrodes[J].Carbohydrate Polymers,2017,173:383.
43 Wu P, Cheng S, Yang L, et al. Synthesis and characterization of self-standing and highly flexible delta-MnO2@CNTs/CNTs compo-site films for direct use of supercapacitor electrodes[J].ACS Applied Materials & Interfaces,2016,8(36):23721.
44 Su Xiaohui, Yu Lin, Cheng Gao, et al. Hydrothermally synthesized manganese dioxide film as supercapacitor electrode[J].Materials Review B: Research Papers,2015,29(5):18(in Chinese).
苏小辉,余林,程高,等.热合成法制备超级电容器用二氧化锰薄膜电极[J]. 材料导报:研究篇,2015,29(5):18.
45 Wang Q, Wang X, Liu B, et al. NiCo2O4 nanowire arrays supported on Ni foam for high-performance flexible all-solid-state supercapacitors[J].Journal of Materials Chemistry A,2013,1(7):2468.
46 Ghosh D, Mandal M, Das C K. Solid state flexible asymmetric supercapacitor based on carbon fiber supported hierarchical Co(OH)xCO3 and Ni(OH)2[J].Langmuir,2015,31(28):7835.
47 Jia Y, Liu Z, Liao Z, et al. Progress in preparation and performance of conducting polyaniline[J].Development & Application of Mate-rials,2016,31(1):97(in Chinese).
贾艺凡,刘朝辉,廖梓珺,等.导电聚苯胺的聚合方法及应用研究进展[J].材料开发与应用,2016,31(1):97.
48 Wang K, Meng Q, Zhang Y, et al. High-performance two-ply yarn supercapacitors based on carbon nanotubes and polyaniline nanowire arrays[J].Advanced Materials,2013,25(10):1494.
49 Yu H, Ge X, Bulin C, et al. Facile fabrication and energy storage analysis of graphene/PANI paper electrodes for supercapacitor application[J].Electrochimica Acta,2017,253:239.
50 Wang K, Zhang X, Li C, et al. Chemically crosslinked hydrogel film leads to integrated flexible supercapacitors with superior performance[J].Advanced Materials,2015,27(45):7451.
51 Fan H, Ran F, Zhang X, et al. Easy fabrication and high electrochemical capacitive performance of hierarchical porous carbon by a method combining liquid-liquid phase separation and pyrolysis process[J].Electrochimica Acta,2014,138(25):367.
52 Zhao X, Wang N, Tan Y, et al. High rate capability and long cycle-life of nickel oxide membrane electrode incorporated with nickel and coated with carbon layer via in-situ supporting of engineering plastic for energy storage application[J].Journal of Alloys and Compounds,2017,710:72.
53 Murashko K, Nevstrueva D, Pihlajamäki A, et al. Cellulose and activated carbon based flexible electrical double-layer capacitor electrode: Preparation and characterization[J].Energy,2017,119:435.
54 Zhao X, Ran F, Shen K, et al. Facile fabrication of ultrathin hybrid membrane for highly flexible supercapacitors via in-situ phase separation of polyethersulfone[J].Journal of Power Sources,2016,329:104.
55 Ran F, Shen K, Tan Y, et al. Activated hierarchical porous carbon as electrode membrane accommodated with triblock copolymer for supercapacitors[J].Journal of Membrane Science,2016,514:366.
56 Wang Z, Tan Y, Liu Y, et al. New amphiphilic block copolymer-modified electrodes for supercapacitors[J].New Journal of Chemistry,2018,42(2):1290.
57 Han Y, Ge Y, Chao Y, et al. Recent progress in 2D materials for flexible supercapacitors[J].Journal of Energy Chemistry,2018,27(1):57.
58 Ye Xingke, Zhou Qianlong, Wan Zhongquan, et al. Research progress of electrode materials and devices in flexible supercapacitors[J].Chemistry,2017,80(1):10(in Chinese).
叶星柯,周乾隆,万中全,等.柔性超级电容器电极材料与器件研究进展[J].化学通报,2017,80(1):10.
59 Yang Z, Deng J, Chen X, et al. A highly stretchable, fiber-shaped supercapacitor[J].Angewandte Chemie International Edition,2013,52(50):13453.
60 Cai Z, Li L, Ren J, et al. Flexible, weavable and efficient microsupercapacitor wires based on polyaniline composite fibers incorporated with aligned carbon nanotubes[J].Journal of Materials Chemistry A,2013,1(2):258.
61 Yu X, Pan J, Zhang J, et al. A coaxial triboelectric nanogenerator fiber for energy harvesting and sensing under deformation[J].Journal of Materials Chemistry A,2017,5(13):6032.
62 Kyeremateng N A, Brousse T, Pech D. Microsupercapacitors as miniaturized energy-storage components for on-chip electronics[J].Nature Nanotechnology,2017,12(1):7.
63 Zhao X, Yang Y, Wu J, et al. An electrolyte-affinity hybrid membrane with the supporting of polymer and modification of amphiphilic block copolymer for superhigh-flexible and high-performance supercapacitor[J].Sustainable Energy Fuels,2017,1(5):1074.
64 Shen C, Wang X, Zhang W, et al. A high-performance three-dimensional micro supercapacitor based on self-supporting composite materials[J].Journal of Power Sources,2011,196(23):10465.
65 Peng L, Peng X, Liu B, et al. Ultrathin two-dimensional MnO2/graphene hybrid nanostructures for high-performance, flexible planar supercapacitors[J].Nano Letters,2013,13(5):2151.
66 Chen J, Jia C, Wan Z. The preparation and electrochemical properties of MnO2/poly(3,4-ethylenedioxythiophene)/multiwalled carbon nanotubes hybrid nanocomposite and its application in a novel flexible micro-supercapacitor[J].Electrochimica Acta,2014,121(3):49.
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2018, Vol. 32 
