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《材料导报》期刊社  2018, Vol. 32 Issue (5): 715-718    https://doi.org/10.11896/j.issn.1005-023X.2018.05.004
  材料与可持续发展(一)—— 面向洁净能源的先进材料 |
纤维素基多孔碳膜的制备及其电化学性能研究
吴亚鸽1, 冉奋1, 2
1 兰州理工大学材料科学与工程学院,兰州 730050;
2 省部共建有色金属先进加工与再利用国家重点实验室,兰州 730050
Preparation of Cellulose Matrix Porous Carbon Film by a Facile Process and Its Electrochemical Performance
WU Yage1, RAN Fen1,2
1 College of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050;
2 State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050
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摘要 以α-纤维素分散液为前驱体,采用简单的抽滤和热处理工艺制备多孔超薄碳膜。采用扫描电子显微镜、透射电子显微镜等方法对其结构进行了表征;采用循环伏安、恒流充放电、交流阻抗等方法研究了其电化学性能;并且研究了多级孔结构对所制备的碳膜电化学性能的影响。结果表明:制备的超薄多孔碳膜呈现多级孔结构,厚度约为1.5 μm,在电流密度为0.5 A·g-1时,容量达到169 F·g-1;在2 A·g-1的电流密度下,在循环5 000圈后,可以保持80%的容量,同时库伦效率几乎保持100%。
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吴亚鸽
冉奋
关键词:  超级电容器  α-纤维素  多孔碳膜  电极材料    
Abstract: A simple method combining extraction operation and thermo-treatment was applied to synthesize a ultra-thin porous carbon film by using α-cellulose solution as precursor. Scanning electron microscopy and transmission electron microscopy were used to characterize the structure porous carbon film, and cyclic voltammetry, charging-discharging tests and electrochemical impedance spectroscopy were used to test the electrochemical properties of the prepared film. The effect of the structure on the electrochemical performance was also investigated. The results showed that the prepared ultra-thin porous carbon film exhibits porous structure with thickness of about 1.5 μm. Moreover, the porous carbon film has a highest specific capacitance of 169 F·g-1 at the current density of 0.5 A·g-1, and a capacitance retention of 80% at 2 A·g-1 after 5 000 cycles. Notably, the Coulombic efficiency kept 100% simultaneously during the process of cyclic charge-discharge.
Key words:  supercapacitor    α-cellulose,porous carbon film,electrode material
               出版日期:  2018-03-10      发布日期:  2018-03-10
ZTFLH:  TB324  
  TQ316.3  
基金资助: 国家自然科学基金(51203071;51363014;51463012;51763014);博士后科学基金(2014M552509;2015T81064);甘肃省自然科学基金(1506RJZA098);兰州理工大学红柳杰出人才计划(J201402)
通讯作者:  冉奋:通信作者,男,1978年生,博士,副教授,主要从事高分子能源及医用材料研究 E-mail:ranfen@163.com   
作者简介:  吴亚鸽:女,1993年生,硕士研究生,主要从事高分子基能源材料研究 E-mail:493039338@qq.com
引用本文:    
吴亚鸽, 冉奋. 纤维素基多孔碳膜的制备及其电化学性能研究[J]. 《材料导报》期刊社, 2018, 32(5): 715-718.
WU Yage, RAN Fen. Preparation of Cellulose Matrix Porous Carbon Film by a Facile Process and Its Electrochemical Performance. Materials Reports, 2018, 32(5): 715-718.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.05.004  或          http://www.mater-rep.com/CN/Y2018/V32/I5/715
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