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《材料导报》期刊社  2018, Vol. 32 Issue (3): 378-383    https://doi.org/10.11896/j.issn.1005-023X.2018.03.006
     材料综述 ｜ |
聚吡咯电极材料在超级电容器中的研究进展
张苗苗,刘旭燕,钱炜
上海理工大学机械工程学院,上海 200093
Research Development of Polypyrrole Electrode Materials in Supercapacitors
Miaomiao ZHANG,Xuyan LIU,Wei QIAN
School of Mechanical Engineering, University of Shanghai for Science and Technology, Shanghai 200093
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摘要 

聚吡咯是导电稳定性最好的导电聚合物之一。因其制备方式简单、环境友好、导电率高、电容性好及独特的掺杂性,制备聚吡咯复合材料以提高电极材料的稳定性成为超级电容器导电聚合物基电极材料的热点研究方向。综述了近年来聚吡咯电极材料及其与碳基材料、金属氧化物材料等二元、三元复合电极材料应用于超级电容器中的研究进展,介绍了聚吡咯的电荷储存机制、聚合机理、制备方法等,指出了当前超级电容器聚吡咯及其复合电极材料的热点研究领域,并且展望了其发展前景。
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张苗苗
刘旭燕
钱炜
关键词:  超级电容器  聚吡咯  电极材料    
Abstract: 

Polypyrrole is one of conductive polymers with the best conductive stability. Because of its simple preparation, environmental friendliness, high conductivity, high conductivity and unique doping, the preparation of polypyrrole composites in order to improve the stability is becoming a hot spot in the research field of conductive polymer-based supercapacitors electrode materials. Polypyrrole electrode materials and binary, ternary composite electrode materials with the carbon materials or metal oxide materials used in the research development of supercapacitors in recent years are reviewed. The charge storage mechanism, polypyrrole polymerization mechanism and preparation methods are introduced. Meanwhile, this paper prospected the current hot research fields and development prospect of the polypyrrole and its composite electrode materials.
Key words:  supercapacitors    polypyrrole    electrode material
               出版日期:  2018-02-10      发布日期:  2018-02-10
ZTFLH:  TM912  
基金资助: 国家自然科学基金青年基金(61504080)
作者简介:  张苗苗:女,1993年生,硕士研究生,研究方向为超级电容器电极材料 E-mail: zhangmiaomiao1219@126.com|刘旭燕:通信作者,女,1981年生,博士,硕士研究生导师,研究方向为新能源器件的开发 E-mail: lxuyan@163.com
引用本文:    
张苗苗,刘旭燕,钱炜. 聚吡咯电极材料在超级电容器中的研究进展[J]. 《材料导报》期刊社, 2018, 32(3): 378-383.
Miaomiao ZHANG,Xuyan LIU,Wei QIAN. Research Development of Polypyrrole Electrode Materials in Supercapacitors. Materials Reports, 2018, 32(3): 378-383.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.03.006  或          http://www.mater-rep.com/CN/Y2018/V32/I3/378
图1  聚吡咯的分子结构
图2  PPy的电荷储存机制
图3  聚吡咯的合成机理:(a)阳离子自由基的形成,(b)阳离子自由基结合并释放两个质子,(c)双阳离子自由基的形成,(d、e)链增长
图4  自支撑的PPy纳米管嵌纳米孔阵列材料的制备过程示意图
图5  PPy包覆碳纳米管的PPy/MWNTs复合材料的合成流程
图6  PPy-RGO-fabric复合材料的合成工艺
图7  PPy/HCA的(a)充放电曲线和(b)循环伏安曲线
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