用于超级电容器电极的柚子皮/聚苯胺原位复合碳化材料

doi:10.11896/cldb.201904030

材料导报

2019, Vol. 33

Issue (4): 719-723 https://doi.org/10.11896/cldb.201904030

高分子与聚合物基复合材料

用于超级电容器电极的柚子皮/聚苯胺原位复合碳化材料

杜伟,王小宁,鞠翔宇,孙学勤

烟台大学环境与材料工程学院, 烟台 264000

Pomelo Peel/Polyaniline In-situ Composite Carbonized Material with an Application to Supercapacitor Electrode

DU Wei, WANG Xiaoning, JU Xiangyu, SUN Xueqin

School of Environment and Materials Engineering, Yantai University, Yantai 264000

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 3291KB )
输出: BibTeX | EndNote (RIS)

摘要超级电容器作为一种新兴储能设备,具有充电速度快、功率密度高、使用寿命长、工作温度范围广且绿色环保等优点,弥补了以锂电池为代表的传统化学电池和其他普通电容器在生产使用方面的不足。本工作以生活废弃物柚子皮为碳源,利用生物质热解炭化技术,在氮气保护下高温碳化柚子皮得到活性炭材料,然后采用最优质量比1∶1原位聚合制备活性炭/聚苯胺纳米复合材料,经高温再碳化获得活性炭材料,并将获得的活性炭材料制成电极,研究其电化学性能。结果表明,活性炭/聚苯胺复合材料经碳化后获得的活性炭材料比电容量可达358 F/g,电极经过2 000次的充放电循环后,电容量仍可保持初始值的95%,具有优良的循环稳定性。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	杜伟
	王小宁
	鞠翔宇
	孙学勤

关键词: 柚子皮聚苯胺生物质碳化超级电容器

Abstract: Supercapacitors, as an emerging energy storage device, have many advantages like fast charging, high power density, long service life, wide working temperature range, environment friendly, etc., and surpass the traditional chemical battery such as Li-ion battery and some other ordinary capacitor in terms of manufacture and use. This work aims to prepare a high performance supercapacitor electrode material from pomelo peel, a kind of natural biomass. Firstly, conducted the high-temperature carbonization of pomelo peel under N₂ protection to acquire the activated carbon, and then gained the activated carbon/polyaniline nanocomposite by adopting the optimized mass ratio of 1∶1, through an in-situ polymerization. Subsequently this nanocomposite material experienced a high-temperature recarbonization process, and transformed into the desired activated carbon product. Supercapacitor electrode based on the product was fabricated and its electrochemical properties was determined. The results showed that, the activated carbon material acquired by recarbonizing the pomelo peel carbon/polyaniline composite exhibits a specific capacitance of 358 F/g, and a capacitance retention of 95% after 2 000 charge-discharge cycles, indicating a satisfactory cycle stability.

Key words: pomelo peel polyaniline biomass carbonization supercapacitor

出版日期: 2019-02-25 发布日期: 2019-03-11

ZTFLH:

TM912.9

基金资助: 国家自然科学基金(50802081);山东省优秀中青年科学家奖励基金(2006BS04019)

作者简介: 杜伟,烟台大学环境与材料工程学院,副教授。2005年6月毕业于山东大学晶体所,材料学博士学位。后加入烟台大学环境与材料工程学院工作至今,主要从事多孔碳材料以及在电化学方面的应用研究。

引用本文:

杜伟, 王小宁, 鞠翔宇, 孙学勤. 用于超级电容器电极的柚子皮/聚苯胺原位复合碳化材料[J]. 材料导报, 2019, 33(4): 719-723.
DU Wei, WANG Xiaoning, JU Xiangyu, SUN Xueqin. Pomelo Peel/Polyaniline In-situ Composite Carbonized Material with an Application to Supercapacitor Electrode. Materials Reports, 2019, 33(4): 719-723.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.201904030 或 http://www.mater-rep.com/CN/Y2019/V33/I4/719

Seo M K, Park S J. Current Applied Physics,2010,10(1),241.2 Chmiola J, Yushin G, Gogotsi Y, et al. Science,2006,313(5794),1760.3 Chmiola J, Largeot C, Taberna P L, et al. Angewandte Chemie-International Edition,2008,47(18),3392.4 Thomberg T, Janes A, Lust E. Journal of Electroanalytical Chemistry,2009,630(1-2),55.5 Baumann T F, Worsley M A, Han Y J, et al. Journal of Non-Crystalline Solids,2008,354(29),3513.6 Zhou J, Ji Y, He J, et al. Microporous & Mesoporous Materials,2008,114(1-3),424.7 Banham D, Feng F, Burt J, et al. Carbon,2010,48(4),1056.8 Wang D W, Li F, Liu M, et al. Angewandte Chemie-International Edition,2008,47(2),373.9 Xing W, Huang C, Zhou S P, et al. Carbon,2009,47(7),1715.10 Sun L, Tian C, Li M, et al. Journal of Materials Chemistry A,2013,1,6462.11 Cao Y, Wang K, Wang X, et al. Electrochimica Acta,2016,212(10),839.12 Wang K, Zhao N, Lei S, et al. Electrochimica Acta,2015,166(1),1.13 Li C, Yu J, Xiao C, et al. Journal of Materials Science,2017,52,2816.14 Qian W, Sun F, Xu Y, et al. Energy and Environmental Science,2014,7(1),379.15 Bao L, Li X. Advanced Materials,2012,24(24),3246.16 Teng Y, Liu E, Ding R, et al. Electrochimica Acta,2016,194,394.17 Wang J, Kaskel S. Journal of Materials Chemistry,2012,22(45),23710.18 Zhou J, Zhu T, Xing W, et al. Electrochimica Acta,2015,160,152.19 Yang P, Mai W. Nano Energy,2014,8,274.20 Du W, Wang X N, Ju X Y, et al. Journal of Electroanalytical Chemistry,2017,802,15.

[1]	刘钊, 王纪孝, 孙亚伟. 硫酸掺杂聚苯胺涂层的快速表面光热杀菌性能[J]. 材料导报, 2019, 33(14): 2431-2435.
[2]	刘明, 徐洪峰, 周亚男, 郝宇. 金属有机框架化合物Zn₄O(BDC)₃材料的制备、结构及电容性能[J]. 材料导报, 2019, 33(12): 1955-1958.
[3]	刘敏敏, 蔡超, 张志杰, 刘睿. 纳米碳材料负载过渡金属氧化物用作超级电容器电极材料[J]. 材料导报, 2019, 33(1): 103-109.
[4]	王赫, 王洪杰, 王闻宇, 金欣, 林童. 聚丙烯腈基碳纳米纤维在超级电容器电极材料中的应用研究进展[J]. 《材料导报》期刊社, 2018, 32(5): 730-734.
[5]	吴亚鸽, 冉奋. 纤维素基多孔碳膜的制备及其电化学性能研究[J]. 《材料导报》期刊社, 2018, 32(5): 715-718.
[6]	张苗苗,刘旭燕,钱炜. 聚吡咯电极材料在超级电容器中的研究进展[J]. 《材料导报》期刊社, 2018, 32(3): 378-383.
[7]	夏艺萌, 吴帅, 谭丰, 李卫, 魏清茂, 闵春刚, 杨喜昆. 钴盐阴离子基团对Co-N-C催化剂电催化活性的影响[J]. 《材料导报》期刊社, 2018, 32(3): 362-367.
[8]	杨贺珍, 冉奋. 超级电容器电解质研究进展[J]. 材料导报, 2018, 32(21): 3697-3705.
[9]	史长亮, 邢宝林, 曾会会, 张双杰, 郭晖, 贾建波, 张传祥, 田野, 朱阿辉, 张青山. 梯级孔生物质活性炭的制备及其电容特性研究[J]. 材料导报, 2018, 32(19): 3318-3324.
[10]	肖国庆, 勾黎敏, 丁冬海. 超级电容器用PVDC基碳电极的研究现状/肖国庆等超级电容器用PVDC基碳电极的研究现状[J]. 材料导报, 2018, 32(19): 3309-3317.
[11]	王德玄, 王磊, 于良民. 三维结构聚丙烯酰胺/聚乙烯醇水凝胶的合成及其在超级电容器中的应用[J]. 材料导报, 2018, 32(17): 2907-2911.
[12]	董文举, 孔令斌, 康龙, 冉奋. 超级电容器电极材料及器件的柔性化与微型化[J]. 材料导报, 2018, 32(17): 2912-2919.
[13]	黄文欣, 李军, 徐云鹤. 二氧化锰基超级电容器的研究进展[J]. 材料导报, 2018, 32(15): 2555-2564.
[14]	谭永涛, 孔令斌, 康龙, 冉奋. Nano-Au@PANI蛋黄空心结构电极材料的构筑及超级电容性能[J]. 《材料导报》期刊社, 2018, 32(1): 47-50.
[15]	唐捷, 华青松, 元金石, 张健敏, 赵玉玲. 超级电容器中的二维材料[J]. CLDB, 2017, 31(9): 26-35.

[1]	Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2]	Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3]	Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4]	Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5]	Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6]	XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg_98.5Zn_0.5Y₁ Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7]	ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8]	WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9]	HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10]	YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .

Viewed

Full text

Abstract

Cited

Shared

Discussed