超点阵结构储氢合金研究进展

doi:10.11896/cldb.22040141

材料导报

2023, Vol. 37

Issue (17): 22040141-9 https://doi.org/10.11896/cldb.22040141

金属与金属基复合材料

超点阵结构储氢合金研究进展

邓安强^1,2,3, 罗永春^1,2,*, 袁远¹, 康晓燕¹, 周健飞¹, 谢云丁¹, 沈秉金¹, 王悦¹

1 兰州理工大学材料科学与工程学院,兰州 730050
2 兰州理工大学有色金属先进加工与再利用省部共建国家重点实验室,兰州 730050
3 宁夏大学机械工程学院,银川 750021

Research Progress of Super Lattice Hydrogen Storage Alloys

DENG Anqiang^1,2,3, LUO Yongchun^1,2,*, YUAN Yuan¹, KANG Xiaoyan¹, ZHOU Jianfei¹, XIE Yunding¹, SHEN Bingjin¹, WANG Yue¹

1 School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China
2 State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
3 School of Mechanical Engineering, Ningxia University, Yinchuan 750021, China

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摘要超点阵结构储氢合金是近20年来储氢材料领域的研究热点。本文详细综述了常见超点阵晶体结构的演变规律,超点阵结构由Laves结构单元和CaCu₅结构单元在c轴堆垛而成,该结构均可由CaCu₅结构经过元素替代和平移而获得,有六方2H和菱方3R两种晶体结构类型。文章综述了典型超点阵结构储氢合金的研究进展、超点阵结构合金关键元素占位和亚结构单元体积调控机制。合金电极电化学循环稳定性与电化学循环过程中合金结构演变和相应的表面腐蚀行为等方面有关,文章同时综述了改善超点阵结构合金储氢行为和电化学性能的途径,并对未来超点阵结构储氢合金的发展进行了展望。对超点阵结构储氢合金成分-结构-性能-服役性能的深层次理解有助于开发高性能超点阵结构合金电极材料。

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	邓安强
	罗永春
	袁远
	康晓燕
	周健飞
	谢云丁
	沈秉金
	王悦

关键词: 超点阵结构储氢合金储氢行为电化学性能

Abstract: Superlattice structure alloys have been a hot topic in the field of hydrogen storage materials in recent 20 years. In this paper, the evolution law of common superlattice crystal structures is reviewed in detail. The superlattice alloy is composed of Laves structure and CaCu₅ structure stacked on the c axis. The structure can be obtained by element substitution and translation of CaCu₅ structure. There are two crystal structure types:hexagonal 2H and rhombohedral 3R crystal structures. The research progress of typical superlattice structure hydrogen storage alloys, key element occupancy and volume regulation mechanisms of sub-unit in superlattice alloys are reviewed. The electrochemical cycling performance of alloy electrodes is related to the evolution of alloy structure and the corresponding surface corrosion behavior during electrochemical cycling. The approaches to improve the hydrogen storage behavior and electrochemical performance of superlattice alloys are reviewed at the same time, and the future development of superlattice structure hydrogen storage alloys is prospected. This paper is expected to facilitate deep understanding of the composition-structure-property-service performance of superlattice hydrogen storage alloys, and provide reference for the development of high-performance superlattice alloys electrode material.

Key words: superlattice structure hydrogen storage alloy hydrogen storage behavior electrochemical property

出版日期: 2023-09-10 发布日期: 2023-09-05

ZTFLH:

TG139.7

基金资助: 国家自然科学基金(51761026);宁夏自然科学基金(2022AAC03048;2019AAC03003);兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室开放基金(SKLAB02019004)

通讯作者: *罗永春,兰州理工大学材料科学与工程学院教授、博士研究生导师,研究方向为储氢材料、材料电化学。luoyc@lut.edu.cn

作者简介: 邓安强,宁夏大学副教授,工学博士,研究方向为稀土储氢材料。

引用本文:

邓安强, 罗永春, 袁远, 康晓燕, 周健飞, 谢云丁, 沈秉金, 王悦. 超点阵结构储氢合金研究进展[J]. 材料导报, 2023, 37(17): 22040141-9.
DENG Anqiang, LUO Yongchun, YUAN Yuan, KANG Xiaoyan, ZHOU Jianfei, XIE Yunding, SHEN Bingjin, WANG Yue. Research Progress of Super Lattice Hydrogen Storage Alloys. Materials Reports, 2023, 37(17): 22040141-9.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.22040141 或 http://www.mater-rep.com/CN/Y2023/V37/I17/22040141

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