新型球状Ni/Co-MOFs电极材料的构筑及电化学性能研究

doi:10.11896/cldb.21050021

材料导报

2022, Vol. 36

Issue (14): 21050021-7 https://doi.org/10.11896/cldb.21050021

金属与金属基复合材料

新型球状Ni/Co-MOFs电极材料的构筑及电化学性能研究

牛晓勤^1,†, 康小雅^2,†, 马应霞², 王嘉伟², 陈新权², 田虎², 陈玉红¹, 冉奋²

1 兰州理工大学石油化工学院,兰州 730050
2 兰州理工大学材料科学与工程学院,省部共建有色金属先进加工与再利用国家重点实验室,兰州 730050

Fabrication and Electrochemical Properties of Novel Spherical Ni/Co-MOFs as Electrode Materials

NIU Xiaoqin^1,†, KANG Xiaoya^2,†, MA Yingxia², WANG Jiawei², CHEN Xinquan², TIAN Hu², CHEN Yuhong¹, RAN Fen²

1 School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China
2 State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, School of Materials Science & Engineering, Lanzhou University of Technology, Lanzhou 730050, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 4474KB )
输出: BibTeX | EndNote (RIS)

摘要金属有机框架(Metal-organic frameworks, MOFs)材料作为一种电化学活性材料受到了人们的广泛关注。本工作利用简单的一锅法以1,3,5-苯三甲酸(H₃BTC)为有机配体、六水合氯化镍(NiCl₂·6H₂O)和六水合硝酸钴(Co(NO₃)₂·6H₂O)为金属离子中心来源,通过简单的一步溶剂热法构筑镍/钴金属有机框架材料(Ni/Co-MOFs)。通过扫描电子显微镜 (SEM)、粉末X射线衍射仪 (XRD)、X射线光电子能谱 (XPS)和Brunauer-Emmett-Teller (BET)法等对Ni/Co-MOFs样品的微观形貌、结构组成进行了表征,并采用循环伏安、恒流充放电和电化学阻抗法测试了制备的Ni/Co-MOFs电极材料的电化学性能。结果表明,新型球状Ni/Co-MOFs被成功地构筑。室温下,在6 mol/L KOH电解质中,恒定电流密度为0.5 A/g时,Ni/Co-MOFs电极材料的比电容为779 F/g;当电流密度增大至5 A/g时,Ni/Co-MOFs能够保持初始电容的79%。此外,以Ni/Co-MOFs为正极、活性炭(AC)为负极组装了非对称超级电容器,Ni/Co-MOFs‖AC 非对称超级电容器器件在电流密度为0.5 A/g时的比电容为107 F/g,在功率密度为400 W/kg时的能量密度为38 Wh/kg,经过10 000次连续的充放电循环后,该器件能够保留初始比电容的65.71%。上述研究结果表明,所制备的Ni/Co-MOFs在储能器件领域具有潜在的应用价值。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	牛晓勤
	康小雅
	马应霞
	王嘉伟
	陈新权
	田虎
	陈玉红
	冉奋

关键词: Ni/Co-MOFs 超级电容器电极材料电化学性能

Abstract: Metal-organic frameworks (MOFs) materials have aroused tremendous attention and been used as electrochemically active materials. In this work, a new electrode material of nickel/cobalt metal-organic frameworks (Ni/Co-MOFs) was fabricated by a facile one-pot solvothermal reaction using 1, 3, 5-benzenetricarboxylic acid (H₃BTC) as the organic ligand, and nickel chloride hexahydrate (NiCl₂·6H₂O) and cobalt nitrate hexahydrate (Co(NO₃)₂·6H₂O) as the central of metal ions. The microscopic morphology and structural composition of the Ni/Co-MOFs sample were characterized by SEM, XRD, XPS and BET, and the electrochemical performances were tested by cyclic voltammetry, galvanosta-tic charging-discharging and electrochemical impedance spectra methods. The results indicate that the novel spherical Ni/Co-MOFs is successfully fabricated. The prepared Ni/Co-MOFs exhibits the specific capacitance of 779 F/g at the current density of 0.5 A/g in 6 mol/L KOH electrolyte, and the capacitance retention remains 79% after the current density increases to 5 A/g. Furthermore, the asymmetric supercapacitor of Ni/Co-MOFs‖AC assembled using Ni/Co-MOFs as the positive electrode and activated carbon as the negative electrode possesses the specific capacitance of 107 F/g at the current density of 0.5 A/g. The asymmetric supercapacitors device delivers a satisfied energy storage capacity with the energy density of 38 Wh/kg at the power density of 400 W/kg, and the desired cycling stability of 65.71% after 10 000 cycles sequential charging-discharging. As such, it is believed that the prepared Ni/Co-MOFs have potential applications as electrode materials in the energy storage devices.

Key words: Ni/Co-MOFs supercapacitor electrode material electrochemical performance

发布日期: 2022-07-26

ZTFLH:

O646

基金资助: 沈阳材料科学国家研究中心-有色金属加工与再利用国家重点实验室联合基金(18LHPY005);国家自然科学基金(51763014;52073133)

通讯作者: mayx2011818@163.com; ranfen@163.com

作者简介: ^†共同第一作者。
牛晓勤,博士研究生,2014年在兰州理工大学获得硕士学位。主要研究方向为有机/金属材料的制备及应用研究。
康小雅,2018年6月毕业于兰州理工大学,获得工学学士学位。现为兰州理工大学材料科学与工程学院硕士研究生,在马应霞教授的指导下进行研究。目前主要从事金属有机骨架材料的电化学性能研究。
马应霞,兰州理工大学教授。2012年6月毕业于兰州大学,获得博士学位。主要从事有机/无机纳米杂化材料的构筑、表征和性能研究。主持并完成国家自然科学基金、中国博士后科学基金、甘肃省自然科学基金等科研项目,在Carbon、Journal of Hazardous Materials和Journal of Colloid and Interface Science 等国内外重要刊物发表学术论文30余篇。
冉奋,教授、博士研究生导师、四川大学高分子材料工程国家重点实验室博士, 2013年新加坡国立大学访问研究员、2015年美国加州大学圣克鲁斯分校访问学者。担任中国生物材料学会血液净化材料分会委员,InfoMat、Energy & Environmental Materials、《材料导报》《电子元件与材料》等期刊的青年编委、执行编委或编委。主要从事新型能源材料和生物医用高分子的研究。公开发表学术论文100余篇。

引用本文:

牛晓勤, 康小雅, 马应霞, 王嘉伟, 陈新权, 田虎, 陈玉红, 冉奋. 新型球状Ni/Co-MOFs电极材料的构筑及电化学性能研究[J]. 材料导报, 2022, 36(14): 21050021-7.
NIU Xiaoqin, KANG Xiaoya, MA Yingxia, WANG Jiawei, CHEN Xinquan, TIAN Hu, CHEN Yuhong, RAN Fen. Fabrication and Electrochemical Properties of Novel Spherical Ni/Co-MOFs as Electrode Materials. Materials Reports, 2022, 36(14): 21050021-7.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.21050021 或 http://www.mater-rep.com/CN/Y2022/V36/I14/21050021

1 Liang Z B, Qin T J, Gao S, et al. Advanced Energy Materials, 2021, 12(4), 2003410.
2 Sun H Y, Gao J Y, Pan C. Materials Reports B:Research Papers, 2020, 34(4), 4007(in Chinese).
孙宏宇, 高静怡, 潘超. 材料导报:研究篇, 2020, 34(2), 4007.
3 Pei H B, Mo Z L, Guo R B, et al. Materials Reports A:Review Papers, 2020, 34(11), 21093(in Chinese).
裴贺兵, 莫尊理, 郭瑞斌, 等. 材料导报:综述篇, 2020, 34(11), 21093.
4 Yu C X, Chen J, Zhang Y, et al. Journal of Alloys and Compounds, 2021, 853, 157383.
5 Lashgaria M, Yaria H, Mahdaviana M, et al. Journal of Hazardous Materials, 2021, 404, 124068.
6 Yang H N, Ji S J, Yin J P, et al. Journal of Colloid and Interface Science, 2021, 586, 381.
7 Yin X M, Li H J, Yuan R M, et al. Journal of Colloid and Interface Science, 2021, 586, 219.
8 Zhou J, Yang M L. Materials Reports A:Review Papers, 2020, 34(10), 19043(in Chinese).
周杰, 杨明莉. 材料导报:综述篇, 2020, 34(10), 19043.
9 Deng T, Shi X Y, Zhang W, et al. Nanotechnology, 2021, 32(7), 075402.
10 Xu Y X, Li Q, Xue H G, et al. Coordination Chemistry Reviews, 2018, 376, 292.
11 Yang J, Xiong P X, Zheng C, et al. Journal of Materials Chemistry A, 2014, 2(39), 16640.
12 Choi K M, Jeong M H, Park J H, et al. ACS Nano, 2014, 8(7), 7451.
13 Zhu G L, Wen H, Ma M, et al. Chemical Communications, 2018, 54(74), 10499.
14 Du P C, Donng Y M, Liu C, et al. Journal of Colloid and Interface Science, 2018, 518, 57.
15 Jiao Y, Pei J, Chen D H, et al. Journal of Materials Chemistry A, 2017, 5, 1094.
16 Gao S W, Sui Y W, Wei F X, et al. Journal of Colloid and Interface Science, 2018, 531, 83.
17 Liu X X, Shi C D, Zhai C W, et al. ACS Applied Materials & Interfaces, 2016, 8, 4585.
18 Qu C, Jiao Y, Zhao B T, et al. Nano Energy, 2016, 26, 66.
19 He S H, Li Z P, Wang J Q, et al. RSC Advances, 2016, 6(55), 49478.
20 Xu F, Chen N, Fan Z Y, et al. Applied Surface Science, 2020, 528, 146920.
21 Cheng Q H, Tao K, Han X, et al. Dalton Transactions, 2019, 48, 4119.
22 Meng F L, Fang Z G, Li Z X, et al. Journal of Materials Chemistry A, 2013, 1(24), 7235.
23 He X Y, Li R M, Liu J Y, et al. Chemical Engineering Journal, 2018, 334, 1573.
24 Yang J, Yu C, Fan X M, et al. Advanced Functional Materials, 2015, 25(14), 2109.
25 Ran F T, Xu X Q, Pan D, et al. Nano-Micro Letters,2020,12(1),46.
26 Zhou P, Wan J F, Wang X R, et al. Journal of Colloid and Interface Science, 2020, 575, 96.
27 Chen Y X, Ni D, Yang X W, et al. Electrochimica Acta, 2018, 278, 114.
28 Afzal A, Abuilaiwi F A, Habib A, et al. Journal of Power Sources, 2017, 352, 174.
29 Yang J, Fan X M, Liang S X, et al. Energy & Environmental Science, 2016, 9(4), 1299.
30 Liu F, Zeng L L, Chen Y K, et al. Nano Energy, 2019, 61, 18.
31 Xu X L, Shi W H, Li P, et al. Chemistry of Materials, 2017, 29(14), 6058.
32 Zhang X, Wang J M, Liu J, et al. Carbon, 2017, 115, 134.
33 Zhang X L, Sui Y W, Wei F X, et al. Journal of Materials Science: Materials in Electronics, 2019, 30(19), 18101.
34 Cao F F, Gan M Y, Ma L, et al. Synthetic Metals, 2017, 234, 154.
35 Xia H C, Zhang J N, Yang Z, et al. Nano-Micro Letters, 2017, 9(4), 43.
36 Owusu K A, Qu L B, Li J T, et al. Nature Communications, 2017, 8(1), 14264.
37 Shin S, Shin M W. Applied Surface Science, 2021, 540, 148295.
38 Guan B, Li Y, Yin B Y, et al. Chemical Engineering Journal, 2017, 308, 1165.
39 Azadfalah M, Sedghi A, Hosseini H. Journal of Materials Science: Materials in Electronics, 2019, 30(13), 12351.
40 Xu C, Feng Y, Mao Z M, et al. Journal of Materials Science: Materials in Electronics, 2019, 30(21), 19477.

[1]	刘小伟, 孙宁, 刘湘林, 金芳军. 基于LnBaCo₂O_5+δ双钙钛矿结构SOFC阴极材料的研究进展[J]. 材料导报, 2022, 36(8): 20080292-6.
[2]	侯璞, 张九州, 寻之玉, 霍鹏飞. 聚氨酯基聚合物电解质的应用进展[J]. 材料导报, 2022, 36(5): 20060009-9.
[3]	余剑峰, 罗凌虹, 程亮, 徐序, 王乐莹, 余永志, 夏昌奎. 钙钛矿结构SOFC阴极材料的研究进展[J]. 材料导报, 2022, 36(2): 20030066-11.
[4]	谭洁慧, 邓凌峰, 张淑娴, 李金磊, 王壮, 覃榕荣. 利用微量碳纳米管与石墨烯协同包覆提高LiCoO₂正极材料的性能[J]. 材料导报, 2022, 36(2): 20100058-6.
[5]	李搛倬, 传秀云, 杨扬, 刘芳芳, 齐鹏越. 黄铁矿型FeS₂的制备及其储能应用[J]. 材料导报, 2022, 36(1): 20080005-13.
[6]	李凯旋, 王焕磊. 生物多糖衍生的超级电容器用碳电极材料研究进展[J]. 材料导报, 2022, 36(1): 20080007-13.
[7]	郝娴, 梁峰, 李红霞, 曹云波, 王晓函, 张海军. 纳米碳化钛的制备及在储能领域的应用研究进展[J]. 材料导报, 2021, 35(Z1): 1-8.
[8]	魏满想, 高思睿, 刘宏亮, 王鑫, 付海朋, 何立子. Sn对Al-Mg-Ga-Sn阳极合金电化学性能的影响[J]. 材料导报, 2021, 35(Z1): 311-314.
[9]	王玉娇, 江海涛, 张韵, 王盼盼, 于博文, 徐哲. 镁合金海水电池阳极材料电化学性能研究进展[J]. 材料导报, 2021, 35(9): 9041-9048.
[10]	贾政刚, 张学习, 钱明芳, 耿林, 熊岳平. 全固态锂硫电池中界面问题的研究现状[J]. 材料导报, 2021, 35(9): 9097-9107.
[11]	翟鑫华, 张盼盼, 周建峰, 何亚鹏, 黄惠, 郭忠诚. 锂离子电池用富锂锰基正极材料掺杂改性研究进展[J]. 材料导报, 2021, 35(7): 7056-7062.
[12]	焦齐统, 潘炜, 朱帅, 陈翔宇, 杨宁, 陈建, 顾晨宇, 邱天, 刘晶晶. 相组成对La_0.75Mg_0.25Ni_3.5储氢合金电化学性能的影响[J]. 材料导报, 2021, 35(6): 6140-6145.
[13]	陈浩伟, 余先纯, 张传艳, 李銮玉, 孙德林, 郝晓峰. 木质素基模板炭的制备及电化学性能[J]. 材料导报, 2021, 35(24): 24164-24171.
[14]	唐琴, 周大利, 陈先勇. 清江河虾头胸甲基富氮/氧分级多孔叠炭片的制备及电化学性能[J]. 材料导报, 2021, 35(22): 22016-22021.
[15]	于濂清, 杨钱龙, 朱海丰, 段丽杰, 赵兴雨, 王艳坤. 氢还原氢氟酸刻蚀的TiO₂纳米薄膜光电化学性能[J]. 材料导报, 2021, 35(20): 20001-20004.

[1]	Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO₂/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[2]	Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[3]	Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[4]	Lijing YANG,Zhengxian LI,Chunliang HUANG,Pei WANG,Jianhua YAO. Producing Hard Material Coatings by Laser-assisted Cold Spray:a Technological Review[J]. Materials Reports, 2018, 32(3): 412 -417 .
[5]	Zhiqiang QIAN,Zhijian WU,Shidong WANG,Huifang ZHANG,Haining LIU,Xiushen YE,Quan LI. Research Progress in Preparation of Superhydrophobic Coatings on Magnesium Alloys and Its Application[J]. Materials Reports, 2018, 32(1): 102 -109 .
[6]	Wen XI,Zheng CHEN,Shi HU. Research Progress of Deformation Induced Localized Solid-state Amorphization in Nanocrystalline Materials[J]. Materials Reports, 2018, 32(1): 116 -121 .
[7]	Xing LIANG, Guohua GAO, Guangming WU. Research Development of Vanadium Oxide Serving as Cathode Materials for Lithium Ion Batteries[J]. Materials Reports, 2018, 32(1): 12 -33 .
[8]	Hao ZHANG,Yongde HUANG,Yue GUO,Qingsong LU. Technological and Process Advances in Robotic Friction Stir Welding[J]. Materials Reports, 2018, 32(1): 128 -134 .
[9]	Laima LUO, Mengyao XU, Xiang ZAN, Xiaoyong ZHU, Ping LI, Jigui CHENG, Yucheng WU. Progress in Irradiation Damage of Tungsten and Tungsten AlloysUnder Different Irradiation Particles[J]. Materials Reports, 2018, 32(1): 41 -46 .
[10]	Fengsen MA,Yan YU,Jie ZHANG,Haibo CHEN. A State-of-the-art Review of Cytotoxicity Evaluation of Biomaterials[J]. Materials Reports, 2018, 32(1): 76 -85 .

Viewed

Full text

Abstract

Cited

Shared

Discussed