全固态锂硫电池中界面问题的研究现状

doi:10.11896/cldb.20050229

材料导报

2021, Vol. 35

Issue (9): 9097-9107 https://doi.org/10.11896/cldb.20050229

无机非金属及其复合材料

全固态锂硫电池中界面问题的研究现状

贾政刚¹, 张学习^1,*, 钱明芳¹, 耿林¹, 熊岳平^2,*

1 哈尔滨工业大学材料科学与工程学院,哈尔滨 150001
2 哈尔滨工业大学化工与化学学院,哈尔滨 150001

Interface-related Issues in the Research of All-Solid-State Lithium-Sulfur Batteries: a Review

JIA Zhenggang¹, ZHANG Xuexi^1,*, QIAN Mingfang¹, GENG Lin¹,XIONG Yueping^2,*

1 School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
2 School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China

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摘要由于锂金属负极的理论比容量和固态电解质的安全性高,全固态锂硫电池越来越受到研究者的青睐。与液态锂硫电池相比,全固态锂硫电池最大的不同在于使用固态电解质替换了液态电解质,且固态电解质材料不可燃,因此有着更高的安全性。此外,经过优化处理后的固态电解质有着足够的机械强度,可以有效抑制锂枝晶的产生。同时在产品的制备和运输方面,全固态电池也有着更大的优势。
然而,全固态电池中存在着大量的固固界面,这些固固界面会导致在循环过程中产生界面电阻、体积畸变等一系列问题,会制约全固态锂硫电池的商业应用。因此,近年来学者们对固固界面进行了广泛的研究,不断改进制备工艺,表征界面变化过程,并对离子迁移路径进行了模拟和验证。目前,全固态锂硫电池已经有部分投入了商业应用。
全固态锂硫电池主要包括含硫正极、锂金属负极和固态电解质,而固态电解质主要分为无机固态电解质和有机固态电解质两大类。因此,对固态电解质界面的研究也可以分为两大类:一类是固态电解质内部界面,包括无机电解质与无机电解质之间的界面或者无机电解质与有机电解质之间的界面,该界面主要对离子电导率有着重要影响;另一类主要包括固态电解质与正负极之间的界面,对电池的化学稳定性、体积稳定性和离子电导率等均存在较大的影响。近年来,研究者发现通过改变混合方法、粒径、多孔基体和体积压力等能够有效改善界面。同时,随着表征技术的发展,越来越多的原位界面表征技术能够更加直观地展现界面的变化状态。
本文系统性地阐述了全固态锂硫电池的内、外界面存在的问题和研究现状,并探讨了全固态锂硫电池未来的发展趋势和研究重点,以期为制备稳定、高性能的全固态锂硫电池提供参考。

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关键词: 全固态锂硫电池固固界面固态电解质电化学性能

Abstract: Due to the high theoretical specific capacity of lithium metal anodes and the high safety of solid electrolytes, all-solid-state lithium-sulfur batte-ries (SSLSBs) are increasingly favored by researchers. Compared with liquid lithium-sulfur batteries, the biggest difference of SSLSBs is that the solid electrolyte replaces the liquid electrolyte. The solid electrolyte material is of high safty because of non-flammable of solid electrolyte. In addition, the optimized solid electrolyte exhibits sufficient mechanical strength to effectively suppress the generation of lithium dendrites. SSLSBs also have greater advantages in terms of product preparation and transportation.
However, the high density solid-solid interfaces in SSLSBs may induce a series of problems such as interface resistance and volume distortion during cycling, which restricts the commercial application of SSLSBs. Thus, researchers have conducted extensive research on the solid-solid interfaces in recent years, including continuously improving the preparation process, characterizing the interface evolution process, and simulating and verifying the ion migration path. At present, some SSLSBs have realized commercial application.
SSLSBs mainly include sulfur-containing positive electrodes, lithium metal negative electrodes and solid electrolytes. Solid electrolytes are mainly divided into electrodeless solid electrolytes and organic solid electrolytes. Therefore, the researches on the interface of solid electrolyte can also be categorized in two types. One type is the internal interface of solid electrolyte, including the interface between inorganic electrolyte and inor-ganic electrolyte or the interface between inorganic and organic electrolyte. Another type mainly includes the interface between the solid electrolyte and the electrodes, which has a great influence on the chemical stability, volume stability and electronic ion conductivity of the battery. In recent years, researchers have found that the interface can be effectively improved via changing the mixing method, particle size, porous matrix and volumetric pressure. Besides, with the development of characterization technology, more and more in-situ interface characterization technologies provide more intuitively changing state of the interface.
This article systematically summarizes the problems and research status of the internal and external interfaces of SSLSBs, and discusses the future development trends and research priorities of SSLSBs.

Key words: all-solid-state lithium-sulfur batteries solid-solid interface solid electrolyte electrochemical performance

出版日期: 2021-05-10 发布日期: 2021-05-31

ZTFLH:

TM911

基金资助: 国家重点研发计划(2017YFB0703103);国家自然科学基金(51701052);中国博士后科学基金会(2017M620114)

通讯作者: xxzhang@hit.edu.cn;ypxiong@hit.edu.cn

作者简介: 贾政刚,2016年毕业于哈尔滨工业大学,获得理学学士学位。现为哈尔滨工业大学材料科学与工程学院博士研究生,在张学习教授和熊岳平教授的指导下进行研究。目前主要的研究领域为硫化物全固态电池中的界面行为。
张学习,哈尔滨工业大学教授,博士研究生导师。他于2003年获得哈尔滨工业大学博士学位。他的研究方向包括航天领域应用的能源材料和结构材料。在这些领域发表论文100余篇,申请专利40余项。
熊岳平,哈尔滨工业大学教授,博士研究生导师。作为主要参加者承担完成了NEDO等重大科研课题6项,专注SOFC耐久性问题的研究,承担了Ni/YSZ阳极碳沉积硫毒化及阴极硫毒化铬中毒等单电池性能衰减实验研究,亲身经历了日本SOFC产业化进程,熟知国内外该领域研究进展。

引用本文:

贾政刚, 张学习, 钱明芳, 耿林, 熊岳平. 全固态锂硫电池中界面问题的研究现状[J]. 材料导报, 2021, 35(9): 9097-9107.
JIA Zhenggang, ZHANG Xuexi, QIAN Mingfang, GENG Lin,XIONG Yueping. Interface-related Issues in the Research of All-Solid-State Lithium-Sulfur Batteries: a Review. Materials Reports, 2021, 35(9): 9097-9107.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.20050229 或 http://www.mater-rep.com/CN/Y2021/V35/I9/9097

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