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材料导报  2022, Vol. 36 Issue (8): 20080292-6    https://doi.org/10.11896/cldb.20080292
  无机非金属及其复合材料 |
基于LnBaCo2O5+δ双钙钛矿结构SOFC阴极材料的研究进展
刘小伟, 孙宁, 刘湘林, 金芳军
长春理工大学物理学院,长春 130022
Progress in LnBaCo2O5+δ-based Double Perovskite Cathode Materials for SOFC
LIU Xiaowei, SUN Ning, LIU Xianglin, JIN Fangjun
School of Physics, Changchun University of Science and Technology, Changchun 130022, China
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摘要 随着人类社会的发展,能源与环境问题日益突出,固体氧化物燃料电池(SOFC)作为一种高效环保的发电装置一直以来备受社会各界的广泛关注和重视。阴极作为SOFC的重要组成部分,其性能的优劣直接影响电池的工作效率。近年来,低温化已成为SOFC的发展趋势,具有混合离子-电子导电(MIECs)性质的电极材料因在中低温区(500~800 ℃)具备良好的催化性能而被广泛研究。其中,以钙钛矿为基本单元且有序化的层状结构氧化物LnBaCo2O5+δ作为SOFC阴极,在中低温区表现出优异的电化学性能,受到了国内外众多课题组的关注。本文主要综述了LnBaCo2O5+δ基双钙钛矿型阴极材料过去10年间的研究进展,并总结了不同修饰手段对LnBaCo2O5+δ性能的影响。
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刘小伟
孙宁
刘湘林
金芳军
关键词:  固体氧化物燃料电池  双钙钛矿  阴极  电化学性能    
Abstract: Energy and environmental problems become increasingly prominent with the development of human society. Solid oxide fuel cell (SOFC), as an efficient and environmentally friendly power generation device, has received wide attention from all walks of life. The performance of the cathode as an essential part of SOFC directly affects the efficiency of the battery. In recent years, the low temperature has become the development trend of SOFC. SOFC electrode materials with numerous mixed ionic and electronic conductors (MIECs) have provoked much interest because of their excellent catalytic performance in intermediate-temperature and low-temperature regions (500—800 ℃). Among them, layered LnBaCo2O5+δ perovskites are used as SOFC cathode, due to their excellent electrochemical properties in this temperature region, have been intensively investigated worldwide in recent years. This article focuses on the recent progress of the most actively studied family of layered LnBaCo2O5+δ perovskites in the last decade, and summarizes the influence of different doping methods on the properties of LnBaCo2O5+δ.
Key words:  solid oxide fuel cell (SOFC)    double perovskite    cathode    electrochemical performance
出版日期:  2022-04-25      发布日期:  2022-04-27
ZTFLH:  TB34  
  TM911.4  
基金资助: 国家自然科学基金(21703017);吉林省科技攻关项目(20200201060JC)
通讯作者:  jinfj@cust.edu.cn   
作者简介:  刘小伟,2019年6月在龙岩学院获得学士学位。从2019年9月起,为长春理工大学理学院硕士研究生。在金芳军导师的指导下进行研究,目前主要从事固体氧化物燃料电池研究。
金芳军,长春理工大学讲师,硕士研究生导师。2010年7月本科毕业于临沂大学物理系,2015年6月在吉林大学物理学院凝聚态物理专业取得博士学位。主要从事高温电化学能源材料与器件、光电功能材料领域方面的研究工作,主要研究方向为固体氧化物燃料电池/电解池、高温电化学合成。近年来,在燃料电池领域发表SCI论文30余篇。
引用本文:    
刘小伟, 孙宁, 刘湘林, 金芳军. 基于LnBaCo2O5+δ双钙钛矿结构SOFC阴极材料的研究进展[J]. 材料导报, 2022, 36(8): 20080292-6.
LIU Xiaowei, SUN Ning, LIU Xianglin, JIN Fangjun. Progress in LnBaCo2O5+δ-based Double Perovskite Cathode Materials for SOFC. Materials Reports, 2022, 36(8): 20080292-6.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20080292  或          http://www.mater-rep.com/CN/Y2022/V36/I8/20080292
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