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材料导报  2021, Vol. 35 Issue (18): 18200-18204    https://doi.org/10.11896/cldb.20040157
  高分子与聚合物基复合材料 |
水性醇酸树脂/中空TiO2微球复合涂层的性能
鲍艳1,2, 丁颖1,2, 唐培1,2, 康巧玲1
1 陕西科技大学轻工科学与工程学院,西安 710021
2 轻化工程国家级实验教学示范中心(陕西科技大学),西安 710021
Properties of Water-borne Alkyd Resin/Hollow TiO2 Microsphere Composite Coating
BAO Yan1,2, DING Ying1,2, TANG Pei1,2, KANG Qiaoling1
1 College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China
2 National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science and Technology, Xi'an 710021, China
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摘要 以豆油酸、三羟甲基丙烷、邻苯二甲酸酐和偏苯三酸酐为原料制备水性醇酸树脂,通过物理共混法将中空TiO2微球引入水性醇酸树脂中,研究中空TiO2微球粒径对水性醇酸树脂涂层水接触角、耐盐水性、电化学性能、附着力及铅笔硬度的影响。结果表明:中空TiO2微球粒径对水性醇酸树脂涂层的性能具有重要影响。当中空TiO2微球粒径为200 nm时,所制备的水性醇酸树脂/中空TiO2微球复合涂层的水接触角为106°,耐盐水性能达120 h以上,电化学阻抗较纯水性醇酸树脂涂层提高近两个数量级,具有优异的防腐性能,且复合涂层附着力为0级,铅笔硬度可达5H。
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鲍艳
丁颖
唐培
康巧玲
关键词:  水性醇酸树脂  中空TiO2微球  电化学性能  耐盐水性能    
Abstract: Water-borne alkyd resin was prepared using soybean oleic acid, trimethyl-propane, phthalic anhydride and trimellitic anhydride as raw mate-rials. Hollow TiO2 microspheres with different particle sizes were introduced into water-borne alkyd resin by physical blending method to obtain water-borne alkyd resin/hollow TiO2 microspheres composite coating. The effects of particle size of hollow TiO2 microspheres on water contact angle, salt water resistance, electrochemical properties, adhesion and pencil hardness of water-borne alkyd resin coating were investigated. The results showed that the particle size of hollow TiO2 microspheres was played a vital role for the properties of water-borne alkyd resin coa-ting. When the particle size of hollow TiO2 microspheres was 200 nm, the water contact angle of the composite coating reached 106°, and its salt water resistance reached more than 120 h. Compared with the coating of water-borne alkyd resin, the electrochemical impedance of the composite coating was improved two orders, which exhibited prominent anti-corrosion performance. Moreover, the adhesion and pencil hardness of the composite coating was grade 0 and 5H, respectively.
Key words:  water-borne alkyd resin    hollow TiO2 microspheres    electrochemical property    salt water resistance property
               出版日期:  2021-09-25      发布日期:  2021-09-30
ZTFLH:  TQ323  
基金资助: 国家自然科学基金(21878181);陕西省重点研发计划(2018ZDXM-GY-118)
作者简介:  鲍艳,陕西科技大学轻工科学与工程学院教授,为教育部新世纪优秀人才支持计划入选者,获全国五一巾帼奖状、全国工人先锋号、陕西省“高层次人才特殊支持计划”青年拔尖人才、陕西省中青年科技创新领军人才、陕西省青年科技奖、陕西省青年科技新星、陕西青年五四奖章提名奖、陕西科技大学优秀教师等荣誉称号。主要从事绿色皮革化学品的合成及与胶原纤维的作用、有机/无机纳米复合功能化学品的研究。
引用本文:    
鲍艳, 丁颖, 唐培, 康巧玲. 水性醇酸树脂/中空TiO2微球复合涂层的性能[J]. 材料导报, 2021, 35(18): 18200-18204.
BAO Yan, DING Ying, TANG Pei, KANG Qiaoling. Properties of Water-borne Alkyd Resin/Hollow TiO2 Microsphere Composite Coating. Materials Reports, 2021, 35(18): 18200-18204.
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http://www.mater-rep.com/CN/10.11896/cldb.20040157  或          http://www.mater-rep.com/CN/Y2021/V35/I18/18200
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