固溶温度对Al-Mg-Sn-Ga-Bi合金显微组织及电化学性能的影响

doi:10.11896/cldb.21120010

材料导报

2023, Vol. 37

Issue (14): 21120010-6 https://doi.org/10.11896/cldb.21120010

金属与金属基复合材料

固溶温度对Al-Mg-Sn-Ga-Bi合金显微组织及电化学性能的影响

刘宏亮^1,2, 王月莹^1,2, 沙剑春^1,2, 杨炳林^1,2, 贾志明^1,2, 王鑫^1,2, 高思睿^1,2, 何立子^1,2,*

1 东北大学材料电磁过程教育部重点实验室,沈阳 110819
2 东北大学材料科学与工程学院,沈阳 110819

Effect of Solution Temperature on the Microstructure and Electrochemical Properties of Al-Mg-Sn-Ga-Bi Alloy

LIU Hongliang^1,2, WANG Yueying^1,2, SHA Jianchun^1,2, YANG Binglin^1,2, JIA Zhiming^1,2, WANG Xin^1,2, GAO Sirui^1,2, HE Lizi^1,2,*

1 Key Laboratory of Electromagnetic Processing of Materials of Ministry of Education, Northeastern University, Shenyang 110819, China
2 School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China

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摘要通过扫描电镜、静态腐蚀、电化学腐蚀以及恒流放电测试,研究固溶温度对新型Al-Mg-Sn-Ga-Bi合金显微组织、电化学性能的影响。选择合适温度的固溶处理可以有效调控析出相的形貌、数量和分布,进而显著改善合金的耐蚀性和放电性能。经过540 ℃固溶处理的合金的自腐蚀速率为0.25 mg/(cm²·min),比铸态合金低一个数量级;在以100 mA/cm²的电流密度放电时,放电电压能达到1.157 V,阳极利用率高达89.49%。

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	刘宏亮
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	杨炳林
	贾志明
	王鑫
	高思睿
	何立子

关键词: 固溶处理铝阳极铝空气电池电化学性能放电性能

Abstract: The effects of solution temperature on the microstructure and electrochemical properties of Al-Mg-Sn-Ga-Bi alloys were investigated by microstructure observation, static corrosion, electrochemical corrosion,and constant current discharge tests. The selection of a suitable solid solution temperature can improve the corrosion resistance and discharge properties of the alloys by regulating the morphology, quantity and distribution of the second phase. The alloys after solid solution treatment at 540 ℃ has a self-corrosion rate of 0.25 mg/(cm²·min) which is an order of magnitude lower than that of the as-cast alloy; its discharge voltage and anode utilization can reach 1.157 V and 89.49% at 100 mA/cm².

Key words: solution treatment Al anode Al-air batteries electrochemical property discharge property

出版日期: 2023-07-25 发布日期: 2023-07-24

ZTFLH:

TG146.2+1

通讯作者: *何立子,东北大学材料学院教授。1994年沈阳黄金学院金属压力加工专业学士毕业;1997年东北大学材料加工工程硕士毕业;2001年东北大学材料加工工程博士毕业。研究领域和方向主要聚焦于铝合金的成分设计、成形及热处理工艺开发、材料组织性能控制、金属燃料电池应用基础研究及产业化。在国内外期刊Acta Materialia、Materials Science Engineering A、Materials Letters、Materials Characterization等及国际会议上发表文章50余篇。helizi@epm.neu.edu.cn

作者简介: 刘宏亮,2019年毕业于沈阳理工大学,获得工学学士学位。现为东北大学材料科学与工程学院材料工程专业硕士研究生,主要研究方向为铝空气电池阳极材料的研发。

引用本文:

刘宏亮, 王月莹, 沙剑春, 杨炳林, 贾志明, 王鑫, 高思睿, 何立子. 固溶温度对Al-Mg-Sn-Ga-Bi合金显微组织及电化学性能的影响[J]. 材料导报, 2023, 37(14): 21120010-6.
LIU Hongliang, WANG Yueying, SHA Jianchun, YANG Binglin, JIA Zhiming, WANG Xin, GAO Sirui, HE Lizi. Effect of Solution Temperature on the Microstructure and Electrochemical Properties of Al-Mg-Sn-Ga-Bi Alloy. Materials Reports, 2023, 37(14): 21120010-6.

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http://www.mater-rep.com/CN/10.11896/cldb.21120010 或 http://www.mater-rep.com/CN/Y2023/V37/I14/21120010

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