Research and Applications of Flame Retardants: a Review and Thoughts
XU Jianlin1,2,*, WANG Tao1,2, KANG Chenghu1,2, YANG Wenlong3, NIU Lei1,2
1 School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China 2 State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China 3 School of Physical and Electromechanical Engineering, Hexi University, Zhangye 734000, Gansu, China
Abstract: Polymer materials received much concern in many fields due to their excellent properties. However,most polymer materials are combustible and flammable, which leads to a lot of malignant events such as misfire, death and property loss and limits its application in some fields. In order to solve the flame-retardant problem of polymer materials and meet the needs for people's safe life, the development of new, efficient and environmentally friendly flame retardants has become an important research topic in the field of flame retardant. At present, the flame retardant industry is the stage of vigorous development in China. There are many kinds of flame retardants. However, flame retardants also exposed some problems in the process of their application. A large number of flame retardants will deteriorate the mechanical properties of polymer composites, making it difficult to achieve a balance between flame retardancy and mechanical properties; the smoke and harmful gas produced by flame retardants in the process of exerting flame retardancy will cause serious pollution to the environment, which is not consistent with the environmental requirements; the flame retardant effect is reduced because of the difficulty of dispersing in the polymer and the poor compatibility with the polymer; the addition of flame retardant affects the color of polymer, so that it can not meet the requirements of different properties in actual application. In response to the above problems, the researchers devoted to the development of the integration of environmental protection, high efficiency, flame retardant and smoke suppression of new flame retardant, and improved the dispersion of flame retardants in polymer matrix and two-phase interface design aspects. In order to meet the requirements of the multi-function of flame retardants of polymer, the flame retardants are usually treated via compounding, nano-treatment and surface modification technology. Besides, the quantitative evaluation systems including evaluation theory and model of dispersion and interface compatibility need to be further improved, which has a realistic significance on the design of environment-friendly and excellent comprehensive performance of polymer composites. The research and application progress of flame retardants in environmental protection, dispersion, compatibility, flame retardant efficiency and the influence on the comprehensive performance of polymers are reviewed in this paper. On this basis, the technical problems of flame retardants are discussed. The solutions of related problems and the development trend of flame retardants are introduced.
徐建林, 王涛, 康成虎, 杨文龙, 牛磊. 阻燃剂研究与应用进展及问题思考[J]. 材料导报, 2022, 36(10): 20110227-9.
XU Jianlin, WANG Tao, KANG Chenghu, YANG Wenlong, NIU Lei. Research and Applications of Flame Retardants: a Review and Thoughts. Materials Reports, 2022, 36(10): 20110227-9.
1 Wang Y Z, Chen L. New Industrialization Straregy, 2016,6(1), 38 (in Chinese). 王玉忠, 陈力.新型工业化, 2016,6(1), 38. 2 Costa F R, Wagenknecht U, Heinrich G, et al. Polymer Degradation and Stability, 2007,92(10), 1813. 3 Nyambo C, Wilkie C A. Polymer Degradation and Stability, 2009, 94(4), 506. 4 Bao Z Y, Dong Y M. Intumescent flame retardant technology and application, Harbin Institute of Technology Press, China, 2005(in Chinese). 鲍治宇,董延茂. 膨胀阻燃技术及应用. 哈尔滨工业大学出版社,2005. 5 Peng H Q. Synthesis of phosphorus-containing bicyclic caged flame retardants and their application in intumescent flame retardant polypropy-lene systems. Ph.D. Thesis, Sichuan University, China, 2007(in Chinese). 彭华乔. 不同结构的双环笼状含磷阻燃剂的合成及其在聚丙烯阻燃改性中的应用.博士学位论文, 四川大学, 2007. 6 Reza A, Harintharavimal B, Azman H, et al. Fibers and Polymers, 2018, 19(4), 914. 7 Suparanon T, Surisaeng J, Phusunti N, et al. Chinese Journal of Polymer Science, 2018,36(5), 620. 8 Kong Q, Wu H, Zhang H, et al. Journal of Nanoscience and Nanotech-nology, 2016, 16(8), 8287. 9 Zou J H, Duan H J, Chen Y S, et al. Composites Part B: Engineering, 2020,199, 108228. 10 Jiang Y, Li J, Li B, et al. Polymer Degradationand Stability, 2015,115, 110. 11 Xu W, Wang G J, Zheng X R, et al. Polymer Degradationand Stability, 2015, 111, 142. 12 Qin Z L, Li D H, Li Q, et al. Materials and Design, 2016, 89, 988. 13 Chow W S, Chang L N, Jaafar M, et al. Journal of Composite Materials, 2015, 49(12), 1471. 14 Xu J L, Ma B X, Kang C H, et al. Journal of Lanzhou University of Technology, 2020, 46(2), 24(in Chinese). 徐建林, 马冰雪, 康成虎, 等. 兰州理工大学学报, 2020,46(2), 24. 15 Yan L, Xu Z S, Wang X H, et al. Progress in Organic Coatings,2017,112, 319. 16 Yang Z W, Liang X X, Xu X Q, et al. RSC Advances,2016, 6, 65921. 17 Tannenbaum R, Zubris M, David K, et al. The Journal of Physical Chemistey, 2006, 110(5), 2227. 18 Xiong X S, Zhang Z H, Li Q M, et al, Materials Reports, 2022,36(1), 21010018(in Chinese). 熊小双,张梓豪,李巧敏,等.材料导报, 2022,36(1), 21010018. 19 Zaman I, Phan T T, Kuan H C, et al. Polymer, 2011, 52(7), 1603. 20 Zare Y. Journalof Colloid and Interface Science, 2016,470, 245. 21 Zare Y. Internation Journal of Adhesion and Adhesives, 2016, 70, 191. 22 Chopra S, Deshmukh K A, Peshwe D,et al. Mechanics of Materials, 2017, 109, 11. 23 Li J, Yang Y Q, Luo X, et al. Rare Metal Materials and Engineering, 2013, 42(3), 644(in Chinese). 李健, 杨延清, 罗贤, 等. 稀有金属材料与工程, 2013,42(3), 644. 24 Aso O, Eguiazabal J I, Nazabal J, et al. Composites Science and Technology,2007, 67(13), 2854. 25 Xu J L, Kang C H, Niu L, et al. Materials Research Express,2019, 6(9), 950. 26 Luo Z P, Koo J H. Journal of Microscopy, 2007, 225(2), 118. 27 Liu D, Pourrahimi A M, Olsson R T, et al. European Polymer Journal,2015, 66, 67. 28 Glaskova T, Zarrelli M, Borisova A, et al. Composites Science and Technology, 2011, 71(13), 1543. 29 Zuiderduin W C J, Westzaan C, Huétink J, et al. Polymer, 2003, 44(1), 261. 30 Yang W L, Xu J L, Niu L, et al. Journal of Adhesion Science & Technology,2017, 32(7), 739. 31 Chen W, Liu P, Liu Y, et al. Polymer Chemistry, 2015, 6(24), 4409. 32 Ma M, Wang X P, Liu K, et al. Polymer International, 2020, 69(10), 985. 33 Zhu C, Li H P, Chen S C, et al. Modern Chemical Industry, 2015, 35(4), 116 (in Chinese). 朱超, 李惠萍, 陈世军, 等.现代化工, 2015, 35(4), 116. 34 Guo Y, Li Q. Sichuan Chemical Industry 2015, 18(4), 4(in Chinese). 郭岳,李谦. 四川化工, 2015,18(4), 4. 35 Qu H Q, Wu W H, Jiao Y H, et al. Journal of Chemical Industry and Engineering, 2006,57(5), 1259 (in Chinese). 屈红强, 武伟红, 焦运红, 等.化工学报, 2006, 57(5), 1259. 36 Song Y, Xue B, Wang J. et al. Journal of Polymer Research. 2020,27, 2. 37 Tawiah B, Yu B, Yuen R K K, et al. Carbon, 2019, 150, 8. 38 Qiu S, Wang X, Yu B, et al. Journal of Hazardous Materials,2017, 325, 327. 39 Shi X, Liao F, Ju Y, et al. Fire and Materials, 2017, 41, 362. 40 Ning T Z, Fu L, Zhang J Z, et al. Packaging Engineering, 2020,41(3), 156 (in Chinese). 宁廷州, 付玲, 张敬芝,等. 包装工程, 2020,41(3), 156.
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2022, Vol. 36 
