Research Progress of Polymer Based Composites with Multilayer Film to Improve the Dielectric Energy Storage Density
JI Xumin1, SUN Binzhou1, LI Cong1, HU Penghao1,2,*
1 Institute for Advanced Materials & Technology, University of Science & Technology Beijing, Beijing 100083, China 2 Research Center for New Energy Composite Materials, Foshan (Southern China) Institute for New Materials, Foshan 528200, Guangdong, China
Abstract: Electrostatic capacitor is a component that can store electric charges. It is composed of electrode at both ends and dielectric material in the middle. The energy density that can be stored depends on the dielectric properties of the intermediate dielectric material. Polymer dielectric materials have been widely used due to their ultra-high breakdown strength, easy processing and low cost, but their lower dielectric constant limits the increase in energy density. The introduction of high-permittivity nanofillers into traditional single-layer polymer films can achieve an increase in permittivity, but will significantly deteriorate the breakdown strength of the polymer. In recent years, using the co-extrusion film technology and electrospinning methods to process polymer films into multilayer films has made great progress, which can solve the inverted relationship between dielectric constant and breakdown field strength to a certain extent. The results based on the phase field simulation also proved the excellent performance of the multilayer film. While maintaining the high breakdown strength of the polymer itself, it also achieved an increase in the dielectric constant and improved the discharged energy density of the polymer film. Compared with the energy density of commercial biaxially oriented polypropylene (BOPP) film, that of newly developed materials has increased by 200% or even higher. This paper summarizes the research progress of improving the energy density of composite dielectrics through the design of multilayer structures in recent years, and focuses on the structural design of the interlayer interface in composite materials and the positive effect on hindering carrier transport.
作者简介: 姬旭敏,2018年7月毕业于中北大学,获得工学学士学位。现为北京科技大学新材料技术研究院硕士研究生,在导师胡澎浩的指导下进行研究。目前主要研究方向为聚合物基纳米复合材料的介电储能研究。 胡澎浩,北京科技大学新材料技术研究院副研究员、硕士研究生导师。2006年7月本科毕业于北京航空航天大学材料学院,2011年6月在北京科技大学冶金物理化学专业取得博士学位,2011—2013年在清华大学材料学院进行博士后研究工作。主要从事聚合物基复合材料的介电储能、柔性压电、高频低损的相关研究工作。近年来,在相关领域发表论文50余篇,包括Journal of the American Chemical Society、 Advanced Functional Materials、 Journal of Materials Chemistry A、 Composites Science and Technology等。
引用本文:
姬旭敏, 孙滨洲, 李聪, 胡澎浩. 利用多层薄膜技术提升聚合物基复合材料介电储能密度的研究进展[J]. 材料导报, 2022, 36(9): 20080247-7.
JI Xumin, SUN Binzhou, LI Cong, HU Penghao. Research Progress of Polymer Based Composites with Multilayer Film to Improve the Dielectric Energy Storage Density. Materials Reports, 2022, 36(9): 20080247-7.
1 Chen C, Xie Y C, Liu J J, et al. Composites Science and Technology, 2020, 188, 107968. 2 Li L, Cheng J S, Cheng Y Y, et al. Journal of Materials Chemistry A, 2020, 8(27), 13659. 3 Wang P J, Zhou D, Guo H H, et al. Journal of Materials Chemistry A, 2020, 8(22), 11124. 4 Lu X, Zou X W, Shen J L, et al. Nano Energy, 2020, 70, 104551. 5 Luo S B, Yu J Y, Yu S H, et al. Advanced Energy Materials, 2019, 9(5), 1803204. 6 Zhang T, Guo M F, Jiang J Y, et al. RSC Advances, 2019, 9(62), 35990. 7 Ma Y P, Luo H, Zhou X F, et al. Nanoscale, 2020, 12(15), 8230. 8 Guo M F, Jiang J Y, Shen Z H, et al. Materials Today, 2019, 29, 49. 9 Pan Z B, Xing S, Jiang H T, et al. Journal of Materials Chemistry A, 2019, 7(25), 15347. 10 Pan Z B, Yao L M, Liu J J, et al. Journal of Materials Chemistry C, 2019, 7(2), 405. 11 Zhang Y Y, Liu X R, Yu J Y, et al. Composites Science and Technology, 2019, 184, 107838. 12 Zhang Y, Zhang C F, Feng Y, et al. Nano Energy, 2019, 56, 138. 13 Jiang B B, Iocozzia J, Zhao L, et al. Chemical Society Reviews, 2019, 48(4), 1194. 14 Tian F Q, Yang C, He L J, et al. Transactions of China Electrotechnical Society, 2011, 26(3), 1(in Chinese). 田付强, 杨春, 何丽娟, 等. 电工技术学报, 2011, 26(3), 1. 15 Yang R X, Chen H, Wang X W, et al. Acta Materiae Compositae Sinica, 2018, 35(5), 1050(in Chinese). 杨瑞宵, 陈昊, 王相文, 等. 复合材料学报, 2018, 35(5), 1050. 16 Chen X Y, Yin X Q. Insulating Materials, 2019,52(3), 7(in Chinese). 程相英, 尹训茜. 绝缘材料, 2019, 52(3), 7. 17 Pan Z B, Yao L M, Zhai J W, et al. Journal of Materials Chemistry A, 2016, 4(34), 13259. 18 Wang G Y, Huang X Y, Jiang P K. Scientific Reports, 2017, 7, 43071. 19 Liu S H, Xue S X, Xiu S M, et al. Scientific Reports, 2016, 6, 26198. 20 Bi K, Bi M H, Hao Y N, et al. Nano Energy, 2018, 51, 513. 21 Zhang L Y, Wang Y, Xu M Y, et al. ACS Applied Energy Materials, 2019, 2(8), 5945. 22 Bao Z W, Hou C M, Shen Z H, et al. Advanced Materials, 2020, 32(25), 1907227. 23 Prateek, Thakur V K, Gupta R K. Chemical Reviews, 2016, 116(7), 4260. 24 Baer E, Zhu L. Macromolecules, 2017, 50(6), 2239. 25 Tan D Q. Journal of Applied Polymer Science, 2020, 137(33), 49379. 26 Jiang J Y, Shen Z H, Qian J F, et al. Energy Storage Materials, 2019, 18, 213. 27 Li Y C, Fu X L, Zhan Y H, et al. Materials Reports A:Review Papers, 2017,31(8), 18(in Chinese). 李玉超, 付雪连, 战艳虎, 等. 材料导报:综述篇,2017,31(8),18. 28 Yang T. Fabrication and dielectric properties of barium titanate/polyvinylidene fluoride multi-layered composites. Master's Thesis, Beijing University of Chemical Technology, China, 2009(in Chinese). 杨泰. 钛酸钡/聚偏氟乙烯多层复合材料的制备与介电性能研究. 硕士学位论文, 北京化工大学, 2009. 29 Lin Y, Zhang Y J, Sun C,et al. Ceramics Interntional, 2020, 46(10), 15270. 30 Lin Y, Sun C, Zhan S L, et al. Advanced Materials Interfaces, 2020, 7(9), 2000033. 31 Lin Y, Sun C, Zhan S L, et al. Composites Science and Technology, 2020, 199, 108368. 32 Zha J W, Zheng M S. High Voltage Engineering, 2017, 43(7), 2194(in Chinese). 查俊伟, 郑明胜. 高电压技术, 2017, 43(7), 2194. 33 Pan Z B, Liu B H, Zhai J W, et al. Nano Energy, 2017, 40, 587. 34 Liu F H, Li Q, Cui J, et al. Advanced Functional Materials, 2017, 27(20), 1606292. 35 Wang Y F, Wang L X, Yuan Q B, et al. Nano Energy, 2018, 44, 364. 36 Shen Z H, Wang J J, Lin Y H, et al. Advanced Materials, 2018, 30(2), 1704380. 37 Yin K Z, Zhou Z, Schuele D E, et al. ACS Applied Materials & Interfaces, 2016, 8(21), 13555. 38 Tseng J K, Tang S D, Zhou Z, et al. Polymer, 2014, 55(1), 8. 39 Chen X Y, Tseng K J, Treufeld I, et al. Journal of Materials Chemistry C, 2017, 5(39), 10417. 40 Mackey M, Schuele D E, Zhu L, et al. Macromolecules, 2012, 45(4), 1954. 41 Jiang J Y, Shen Z H, Qian J F, et al. Nano Energy, 2019,62, 220. 42 Jiang J Y, Shen Z H, Cai X K, et al. Advanced Energy Materials, 2019, 9(15), 1803411. 43 Zhang X, Jiang J Y, Shen Z H, et al. Advanced Materials, 2018, 30(16), 1707269. 44 Jiang Y D, Zhang X, Shen Z H, et al. Advanced Functional Materials, 2019, 30(4), 1906112. 45 Wang Y F, Cui J, Yuan Q B, et al. Advanced Materials, 2015, 27(42), 6658. 46 Hu P H, Shen Y, Guan Y H, et al. Advanced Functional Materials, 2014, 24(21), 3172. 47 Wang Y F, Cui J, Wang L X, et al. Journal of Materials Chemistry A, 2017, 5(9), 4710. 48 Zhu Y K, Zhu Y J, Huang X Y, et al. Advanced Energy Materials, 2019, 9(36), 190126. 49 Li Z Y, Liu F H, Li H, et al. Ceramics International, 2019, 45(7), 8216. 50 Wang Y F, Li Y, Wang L X, et al. Energy Storage Materials, 2019, 24, 626. 51 Zhang Y B, Yang H B, Dang Z E, et al. ACS Applied Materials & Interfaces, 2020, 12(19), 22137. 52 Zhang T, Dan Z K, Shen Z H, et al. RSC Advances,2020,10(10),5886. 53 Yin K Z, Zhang J W, Li Z P, et al. Journal of Applied Polymer Science, 2019, 136(20), 47535.