Recent Advancement of Novel Composites Based on Two-dimensional MXene-supported Nano-metals and Its Oxides
LI Hui1, ZHU Gang1,*, ZHANG Jianwei2, KANG Kunyong1, DU Guanben3, LI Yuanyuan1, SUN Ke1
1 College of Material Science and Engineering, Southwest Forestry University, Kunming 650224, China 2 College of Physics Science and Engineering, Tongji University, Shanghai 200092, China 3 Key Laboratory for Forest Resource Conservation and Utilization in the Southwest Mountains of China, Southwest Forestry University, Kunming 650224, China
Abstract: MXene is a novel unique type of two-dimensional layered graphene-liked structural, which exhibits exceptional optical, electrical properties and thermodynamic properties, with large specific surface area, superior hydrophilicity and abundant controllable surface functional groups, as a novel carrier of nano-metals and its oxides, it provides favorable conditions for the microstructure enhancement design of nanocomposites to give better exert the interfacial effects.However, 2D MXene suffers from the difficulties of easy autonomous stacking of lamellae, difficulty in precisely regulating the geometric distribution and composite conformation of nano metals and their oxides in MXene carriers, and weak interfacial bonding of the composites, which leads to the failure to maximize the synergy, coupling and multifunctional response mechanisms between diffe-rent components. Especially for 2D MXene nano-carrier with significant intrinsic functional properties (including thermal and electrical conductivity and mechanical properties), its excellent properties are difficult to fully reflect, which significantly affects the comprehensive properties of the composites. For the above-mentioned issues, preliminary exploration has been carried out on construction of high-performance composites based on 2D MXene-supported nano-metals and their oxides in China and abroad. The related research results have already been applied practically to energy storage, photocatalysis, electromagnetic shielding, microwave absorption, supercapacitors and other frontier fields, and some impressive strides and progress have been made. Hence, this review paper presents the main preparation methods, microstructure and functional properties of 2D MXene supported metal and its oxide nanocomposites. The application and the enhanced mechanism in energy storage, microwave absorption, etc. are summarized. Moreover, some challenges are pointed out, and the future directions of research in this field and their application prospects are forecasted. It is expected to provide a solid theoretical and experimental foundation for the microstructure regulation and perfor-mance optimization design of the novel MXene-based nanocomposites.
作者简介: 李辉,2019年6月毕业于重庆文理学院,获得工学学士学位,现为西南林业大学材料科学与工程硕士研究生,在朱刚副研究员的指导下进行研究,目前主要研究领域为仿生功能复合材料。 朱刚,西南林业大学材料科学与工程学院副研究员,硕士研究生导师。2014年6月在四川大学材料学专业取得博士学位。主要从事仿生功能复合材料的研究工作。近年来,主持或参与国家自然科学基金青年项目、NSFC-云南联合基金项目、云南省自然科学基金面上项目、云南省教育厅协同创新基金、昆明市高层次人才引进项目等8项,发表学术论文30余篇,包括Material Letters、J. Ref. Met. Hard Mater、《稀有金属》和《材料导报》等,获国家发明专利5项。
引用本文:
李辉, 朱刚, 张建卫, 康昆勇, 杜官本, 李园园, 孙呵. 二维MXene负载纳米金属及其氧化物构筑新型复合材料的研究进展[J]. 材料导报, 2022, 36(9): 20090029-9.
LI Hui, ZHU Gang, ZHANG Jianwei, KANG Kunyong, DU Guanben, LI Yuanyuan, SUN Ke. Recent Advancement of Novel Composites Based on Two-dimensional MXene-supported Nano-metals and Its Oxides. Materials Reports, 2022, 36(9): 20090029-9.
1 Shen C J, Wang L B, Zhang H, et al.Materials Reports A:Review Papers, 2016, 30(10), 148(in Chinese). 申长洁, 王李波, 张恒,等. 材料导报:综述篇, 2016, 30(10), 148. 2 Naguib M, Kurtoglu M, Presser V, et al. Advanced Materials, 2011, 23(37), 4248. 3 Naguib M, Mochalin V N, Barsoum M W, et al. Advanced Materials, 2014, 26(7), 992. 4 Barsoum M W,Radovic M. Annual Review of Materials Research, 2011, 41, 195. 5 Xie Y, Naguib M, Mochalin V N, et al. Journal of the American Chemical Society, 2014, 136(17), 6385. 6 Gan L Y, Huang D,Schwingenschlögl U. Journal of Materials Chemistry A, 2013, 1(43), 13672. 7 Enyashin A N,Ivanovskii A L.Journal of Physical Chemistry C, 2013, 117(26), 13637. 8 Dall′Agnese Y, Lukatskaya M R, Cook K M, et al. Electrochemistry Communications, 2014, 48, 118. 9 Lashgari H, Abolhassani M, Boochani A, et al. Solid State Communications, 2014, 195, 61. 10 Zha X H, Zhou J, Zhou Y, et al. Nanoscale, 2016, 8(11), 6110. 11 Han M, Maleski K, Shuck C E, et al. Journal of the American Chemical Society, 2020, 142(45), 19110. 12 Rasheed P A, Pandey R P, Gomez T, et al. Electrochemistry Communications, 2020, 119, 106811. 13 Soomro R A, Jawaid S, Kalawar N H, et al. Biosensors and Bioelectro-nics, 2020, 166, 112439. 14 Shahzad F, Zaidi S A,Naqvi R A.Critical Reviews in Analytical Chemi-stry, 2020, 1. 15 Morales-Garcia A, Calle-Vallejo F,Illas F. ACS Catalysis, 2020, 10, 13487. 16 Lim K R G, Handoko A D, Nemani S K, et al. ACS Nano, 2020, 14(9), 10834. 17 Zha X H, Luo K, Li Q, et al. EPL (Europhysics Letters), 2015, 111(2), 26007. 18 Hu M, Li Z, Li G, et al. Advanced Materials Technologies, 2017, 2(10), 1700143. 19 Zhong Y, Xia X, Shi F, et al. Advanced Science, 2016, 3(5), 1500286. 20 Azofra L M, Li N, MacFarlane D R, et al. Energy & Environmental Science, 2016, 9(8), 2545. 21 Li N, Chen X, Ong W J, et al. ACS Nano, 2017, 11(11), 10825. 22 Deng R, Chen B, Li H, et al. Applied Surface Science, 2019, 488, 921. 23 Wang Y, Gao X, Zhang L, et al. Applied Surface Science, 2019, 480, 830. 24 Zhang X, Wang H, Hu R, et al. Applied Surface Science, 2019, 484(AUG.1), 383. 25 Feng W, Luo H, Wang Y, et al. RSC Advances, 2018, 8(5), 2398. 26 Liu X, Wu J, He J, et al.Materials Letters, 2017, 205(oct.15), 261. 27 Liu Y T, Zhang P, Sun N, et al. Advanced Materials, 2018, 30(23), 1707334. 28 Peng C, Kuai Z, Zeng T, et al. Journal of Alloys and Compounds, 2019, 810, 151928. 29 Zou R, Quan H, Pan M, et al. Electrochimica Acta, 2018, 292, 31. 30 Zhuang Y, Liu Y,Meng X. Applied Surface Science, 2019, 496, 143647. 31 Zhang H, Man L, Cao J, et al. Ceramics International, 2018, 44, 19958. 32 Li Y, Deng X, Tian J, et al. Applied Materials Today, 2018, 13, 217. 33 Zhu L, Lv J, Yu X, et al. Applied Surface Science, 2020, 502(Feb.1), 144171.1. 34 Li N, Xie X, Lu H, et al. Ceramics International, 2019, 45(17), 22880. 35 Chen L, Ye X, Chen S, et al. Ceramics International, 2020, 46(16), 25895. 36 Ding M, Chen W, Xu H, et al. Journal of Hazardous Materials, 2019, 382, 121064. 37 Rajavel K, Hu Y, Zhu P, et al.Chemical Engineering Journal, 2020, 399, 125791. 38 Tan L, Lv J, Xu X, et al. Ceramics International, 2019, 45(5), 6597. 39 Mo R, Lei Z, Sun K, et al. Advanced Materials, 2014, 26(13), 2084. 40 Xin X, Zhou X, Wu J, et al. ACS Nano, 2012, 6(12), 11035. 41 Li W, Wang F, Liu Y, et al. Nano Letters, 2015, 15(3), 2186. 42 Ye R, Peng Z, Wang T, et al. ACS Nano, 2015, 9(9), 9244. 43 Chattopadhyay S, Maiti S, Das I, et al. Advanced Materials Interfaces, 2016, 3(23), 1600761. 44 Ye F, Zhao B, Ran R, et al. Chemistry-A European Journal, 2014, 20(14), 4055. 45 Halim J, Cook K M, Naguib M, et al. Applied Surface Science, 2016, 362, 406. 46 Fujihara S, Maeda T, Ohgi H, et al. Langmuir, 2004, 20(15), 6476. 47 Zhang X Y, Kang J L. Materials Reports, 2020, 34(Z2), 1030(in Chinese). 张曦元, 康建立.材料导报, 2020, 34(Z2), 1030. 48 Cheng J, Hu Z, Lv K, et al. Applied Catalysis B: Environmental, 2018, 232, 330. 49 Mu R, Ao Y, Wu T, et al. Journal of Hazardous Materials, 2020, 382, 121083. 50 Tiwari A, Mondal I, Ghosh S, et al. Physical Chemistry Chemical Phy-sics, 2016, 18(22), 15260. 51 Gao Y, Wang L, Zhou A, et al. Materials Letters, 2015, 150, 62. 52 Chen R, Wang P, Chen J, et al. Applied Surface Science, 2019, 473(APR.15), 11. 53 Ran J, Guo W, Wang H, et al. Advanced Materials, 2018, 30(25), 1800128. 54 Li Y, Yin Z, Ji G, et al. Applied Catalysis B: Environmental, 2019, 246, 12. 55 Low J, Zhang L, Tong T, et al. Journal of Catalysis, 2018, 361, 255. 56 Peng C, Yang X, Li Y, et al. ACS Applied Materials & Interfaces, 2016, 8(9), 6051. 57 Ran J, Gao G, Li F T, et al. Nature Communications, 2017, 8(1), 1. 58 Shi R,Chen Y. ChemCatChem, 2019, 11(9), 2270. 59 Sun X Y, Zhang X, Sun X, et al. Beilstein Journal of Nanotechnology, 2019, 10(1), 2116. 60 Dang A L, Fang C L, Zhao Z, et al. Journal of Materials Engineering, 2020, 48(4), 1(in Chinese). 党阿磊, 方成林, 赵曌,等. 材料工程, 2020, 48(4), 1. 61 Kumar K S, Choudhary N, Jung Y, et al. ACS Energy Letters, 2018, 3(2), 482. 62 Brousse T, Belanger D,Long J W. Journal of the Electrochemical Society, 2015, 162(5), A5185. 63 Chu J, Lu D, Wang X, et al. Journal of Alloys and Compounds, 2017, 702, 568. 64 Lei T, Guan M, Liu J, et al. Proceedings of the National Academy of Sciences, 2017, 114(20), 5107. 65 Irimia-Vladu M, Głowacki E D, Voss G, et al. Materials Today, 2012, 15(7-8), 340. 66 Zhang X, Li L, Fan E, et al. Chemical Society Reviews, 2018, 47(19), 7239. 67 Reck B K,Graedel T E. Science, 2012, 337(6095), 690. 68 Ordoñez J, Gago E J,Girard A. Renewable and Sustainable Energy Reviews, 2016, 60, 195. 69 Hu Y, Zhang T, Cheng F, et al.Angewandte Chemie, 2015, 127(14), 4412. 70 Yang Q, Huang Z, Li X, et al. ACS Nano, 2019, 13(7), 8275. 71 Shahzad F, Alhabeb M, Hatter C B, et al. Science, 2016, 353(6304), 1137. 72 Zhao B, Guo X, Zhao W, et al. ACS Applied Materials & Interfaces, 2016, 8(42), 28917. 73 Esfahani A N, Katbab A, Taeb A, et al. European Polymer Journal, 2017, 95, 520. 74 Yin X W, Cheng L F, Zhang L T, et al. International Materials Reviews, 2017, 62(3), 117. 75 Feng A, Ma M, Jia Z, et al. RSC Advances, 2019, 9(44), 25932. 76 Yin X, Kong L, Zhang L, et al. International Materials Reviews, 2014, 59(6), 326. 77 Song S, Liu J, Zhou C, et al. Journal of Alloys and Compounds, 2020, 843, 155713. 78 Zhao B, Shao G, Fan B, et al. Powder Technology, 2015, 270, 20. 79 Zhang Y, Huang Y, Zhang T, et al. Advanced Materials, 2015, 27(12), 2049. 80 Li X J, Fan G Y, Zeng C.International Journal of Hydrogen Energy, 2014, 39(27), 14927. 81 Zhao B, Liang L, Deng J, et al. CrystEngComm, 2017, 19(44), 6579. 82 He Y, Wang L B, Wang X L, et al. Journal of Synthetic Crystals, 2019, 48(5), 787(in Chinese). 何艳, 王李波, 王晓龙,等. 人工晶体学报, 2019, 48(5), 787. 83 Chang C, Huang X Y, Wang Q. Journal of Chongqing University of Technology (Natural Science), 2021, 35(12), 198(in Chinese). 常春, 黄心悦, 王琼.重庆理工大学学报(自然科学), 2021, 35(12), 198. 84 Zhang Z,Yates J T. Chemical Reviews, 2012, 112(10), 5520. 85 Zheng W, Yang L, Zhang P G, et al. Materials Reports A:Review Papers, 2018, 32(8), 2513(in Chinese). 郑伟, 杨莉, 张培根,等. 材料导报;综述篇, 2018, 32(8), 2513. 86 Qi X, Chen X, Peng S K, et al. Journal of Materials Engineering, 2019, 47(12), 10(in Chinese). 齐新, 陈翔, 彭思侃,等. 材料工程, 2019, 47(12), 10. 87 Jiang H, Wang Z, Yang Q, et al. Electrochimica Acta, 2018, 290, 695. 88 Xie X, Zhao M Q, Anasori B, et al. Nano Energy, 2016, 26, 513. 89 Tao M, Zhang Y, Zhan R, et al. Materials Letters, 2018, 230, 173. 90 Liu Z, Yu Q, Zhao Y, et al. Chemical Society Reviews, 2019, 48(1), 285. 91 Zhang R, Xue Z, Qin J, et al. Journal of Energy Chemistry, 2020, 50, 143. 92 Wang Y, Li Y, Qiu Z, et al. Journal of Materials Chemistry A, 2018, 6(24), 11189.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2022, Vol. 36 
