二维纳米材料MXene及其在锂离子电池中的应用研究进展

doi:10.11896/cldb.20030032

材料导报

2021, Vol. 35

Issue (15): 15047-15055 https://doi.org/10.11896/cldb.20030032

无机非金属及其复合材料

二维纳米材料MXene及其在锂离子电池中的应用研究进展

孙丹, 李伟, 刘峥

桂林理工大学化学与生物工程学院,桂林 541004

Two-dimensional Nanomaterial MXene and Its Research Advances on Applications in Lithium-ion Batteries

SUN Dan, LI Wei, LIU Zheng

College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China

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摘要自20世纪90年代可充电锂离子电池商业化以来,其研究与开发迅速发展。然而研究表明,在锂离子电池中,高速率充电/放电过程会降低锂离子电池的电化学性能。因此,众多研究者致力于开发具有优异的电化学性能、高能量密度和高功率密度的先进电极材料,以进行更好的能量存储和转换。二维(2D)材料由于其独特的性能而表现出巨大的储能潜力。
近年来,衍生自MAX相前驱体的2D过渡金属碳化物/氮化物新系列MXene引起了广泛关注。MXene具有化学和结构多样性,因此与其他2D材料相比,在高功率锂离子电池应用中具有竞争力。研究发现,MXene具有优异的物理及化学性质,其中包括非凡的机械强度、出色的导电性、多种可能的表面终止、优异的比表面积以及容纳嵌入剂的能力。当用作锂基电池的电极材料时,MXene已表现出卓越的电化学性能。
文中对MXene材料制备路线、结构类型及性质进行介绍,并进一步介绍了MXene材料的储锂机理,归纳总结了MXene在锂离子电池中应用研究的最新进展,最后概述了用于锂基能量存储设备的MXene和MXene基复合材料的挑战和前景,并提出杂原子掺杂、插层以及与其他电极材料复合正成为改善MXene材料在LIB中电化学性能的新方向。

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	孙丹
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关键词: MXene 锂离子电池电极材料储能

Abstract: The research and development of rechargeable lithium-ion battery have developed rapidly since its commercialization in the 1990s. However, the research on lithium-ion batteries indicated that the high-rate charge/discharge process reduced the electrochemical performance of lithium-ion batteries. Therefore, many researchers are dedicated to develope advanced electrode materials with excellent electrochemical performance, high energy density and high power density for better energy storage and conversion. Two-dimensional (2D) materials show great energy storage potential due to their unique properties.
MXene, a new series of 2D transition metal carbides/nitrides derived from MAX phase precursors has attracted widespread attention recently. Due to its wide chemical and structural diversity, MXene is competitive with other 2D materials in high-power lithium-ion battery applications. It has been found that MXene has excellent physical and chemical properties, including extraordinary mechanical strength, excellent electrical conductivity, a variety of possible surface terminations, excellent specific surface area and the ability to accommodate intercalants. And it shows excellent electrochemical performance when using as an electrode material for lithium-based batteries.
Herein, the preparation route, structure type and properties of MXene materials are introduced. The lithium storage mechanism of MXene materials and the latest advances in the applications of MXene in lithium-ion batteries are also reported. Finally, the challenges and prospects of MXene and MXene-based composite materials for lithium-based energy storage devices are summarized. And it is proposed that the heteroatom doping, intercalation, and composite with other electrode materials are becoming new directions for improving the electrochemical performance of MXene materials in LIB.

Key words: MXene lithium-ion battery electrode material energy storage

出版日期: 2021-08-10 发布日期: 2021-08-31

ZTFLH:

TM912

基金资助: 广西自然科学基金项目(2018GXNSFBA281114);国家自然科学基金项目(52004076)

作者简介: 孙丹,桂林理工大学硕士研究生,主要研究方向为纳米材料的制备及应用。
李伟,桂林理工大学化学与生物工程学院助理研究员,博士生在读,2012年硕士毕业于桂林理工大学化学与生物工程学院应用化学专业。目前主要从事新能源环境材料方面的研究,主持国家青年基金1项,省部级基金2项。
刘峥,桂林理工大学化学与生物工程学院教授,博士研究生导师,2006年博士毕业于湘潭大学高分子化学与物理专业。目前主要从事能源材料、耐腐蚀材料等功能材料的制备及应用研究。

引用本文:

孙丹, 李伟, 刘峥. 二维纳米材料MXene及其在锂离子电池中的应用研究进展[J]. 材料导报, 2021, 35(15): 15047-15055.
SUN Dan, LI Wei, LIU Zheng. Two-dimensional Nanomaterial MXene and Its Research Advances on Applications in Lithium-ion Batteries. Materials Reports, 2021, 35(15): 15047-15055.

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http://www.mater-rep.com/CN/10.11896/cldb.20030032 或 http://www.mater-rep.com/CN/Y2021/V35/I15/15047

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