无机非金属及其复合材料
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基于共晶系相变材料的研究进展
王成君, 段志英, 王爱军, 王志超, 崔璐娟, 苏琼*
西北民族大学化工学院,甘肃省高校环境友好复合材料及生物质利用省级重点实验室,兰州 730030
Research Progress of Eutectic Phase Change Materials
WANG Chengjun, DUAN Zhiying, WANG Aijun, WANG Zhichao, CUI Lujuan, SU Qiong*
Key Laboratory of Utility of Environmental Friendly Composite Materials and Biomass in Universities of Gansu Province, School of Chemical Engineering, Northwest Minzu University, Lanzhou 730030, China
摘要 基于相变材料的热能储存技术已被公认为是提高可再生能源利用效率和保护环境的先进能源技术之一。相变材料(PCMs)可以作为储能介质,在熔融或凝固过程中,PCMs可以在几乎恒定的温度下储存或释放大量的能量,被广泛应用于潜热储能系统和热管理系统中。相变温度是对相变材料进行选择的一个重要参数。通常具有特定要求相变温度的PCMs不存在,并且单一相变材料的相变温度和潜热比较固定,也难以同时满足对潜热、相变温度等的要求。因此,许多学者开展了二元或多元共晶相变体系的研究。文中介绍了近年来国内外共晶相变储能材料及其复合材料的研究进展及应用;探讨了共晶相变储能材料的相变理论推测及热力学建模;针对共晶体系在应用过程中存在的过冷、相分离、热导率低及相变时易泄露等问题,详述了解决这些问题的方法及进展,并提出了相关建议;最后对共晶系相变材料的热力学模型的建立与设计、热传导及循环稳定性等研究重点进行了展望。
关键词:
共晶
相变材料
储能
复合材料
Abstract: Thermal energy storage technology based on phase change materials has been recognized as one of the advanced energy technologies to improve the utilization efficiency of renewable energy and protect the environment. Phase change materials (PCMs) can be used as energy storage medium. In the process of melting or solidification, PCMs can store or release a large amount of energy at almost constant temperature, so it is widely used in latent energy storage system and thermal management system. Phase transition temperature is an important parameter for the selection of phase change materials. Usually, there is no PCMs with specific phase transition temperature, and the phase transition temperature and latent heat of a single phase change material are relatively fixed, so it is difficult to meet the requirements of latent heat and phase transition temperature at the same time. Therefore, many scholars have carried out the study of binary or multicomponent eutectic phase transition systems. This paper introduces the research progress and application of eutectic phase change energy storage materials and their composites at home and abroad in recent years. The phase transformation theory and thermodynamic modeling of eutectic phase change energy storage mate-rials are discussed. In view of the problems existing in the application of eutectic system, such as undercooling, phase separation, low thermal conductivity and easy leakage during phase transformation, the methods and progress to solve these problems are described in detail, and relevant suggestions are put forward. Finally, the establishment and design of thermodynamic model, heat conduction and cycle stability of eutectic phase change materials are prospected.
Key words:
eutectic
phase change material
thermal energy storage
composite material
出版日期: 2021-07-10
发布日期: 2021-07-14
基金资助: 中央高校基本科研业务费专项资金(31920210063);甘肃省教育厅创新基金(2021B-065);国家自然科学基金(21968032;51563022)
作者简介: 王成君,西北民族大学化工学院讲师,2012年在兰州理工大学化学工艺专业取得硕士学位,先后主持甘肃省青年科技基金一项,中央高校基本科研业务项目一项,参与国家自然基金一项,甘肃省自然科学基金一项。近年来,在相变材料储能领域发表论文8篇。 苏琼,西北民族大学化工学院教授,2009年在兰州大学有机化学专业取得硕士学位,先后主持国家自然科学基金2项,甘肃省自然科学基金1项,中央高校基本科研业务项目4项。近年来,在功能及复合材料领域发表论文20余篇。
引用本文:
王成君, 段志英, 王爱军, 王志超, 崔璐娟, 苏琼. 基于共晶系相变材料的研究进展[J]. 材料导报, 2021, 35(13): 13058-13066.
WANG Chengjun, DUAN Zhiying, WANG Aijun, WANG Zhichao, CUI Lujuan, SU Qiong. Research Progress of Eutectic Phase Change Materials. Materials Reports, 2021, 35(13): 13058-13066.
链接本文:
http://www.mater-rep.com/CN/10.11896/cldb.20040110
或
http://www.mater-rep.com/CN/Y2021/V35/I13/13058
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