Advances in Catalyst Materials for the Hydrogen Peroxide Production by Electrocatalytic Oxygen Reduction
LEI Jing1, CHEN Zixi1, LI Yizhao1,2,*, CAO Yali1,*
1 Key Laboratory of Energy Materials Chemistry of Ministry of Education, Key Laboratory of Advanced Functional Materials(Autonomous Region), Institute of Applied Chemistry, College of Chemistry, Xinjiang University, Urumqi 830046, China 2 College of Chemical Engineering, Xinjiang University, Urumqi 830046, China
Abstract: H2O2 shows strong oxidizing properties and is widely used in papermaking, sewage treatment, and disinfection. The global demand for H2O2 is increasing, but the anthraquinone method for production of H2O2 is complicated, high cost, and low efficient. The direct hydrogen-oxygen synthesis is great safety risks. Therefore, electrocatalytic oxygen reduction reaction, as an emerging, green and safe in-situ synthesis of H2O2, has attracted widespread attention in recent years. Oxygen reduction reaction (ORR) is a multi-electron reaction, the intermediates are complex and difficult to measure, which makes it hard to study the mechanism. There are two competing reaction paths in ORR, two electron paths get H2O2, and four electron paths generate H2O. The efficiency of two-electron oxygen reduction reaction (2e- ORR) depends on the activity, selectivity, and stability of catalyst. At present, the noble metal catalysts, such as Au and Pd, show good performance in 2e- ORR to produce H2O2, but they are expensive and rare. Therefore, three strategies have been proposed. (Ⅰ) Decreasing the loading of noble metal. Integrating the inert metals with the active me-tals to obtain many high-performance alloy materials, such as Pt-Hg. (Ⅱ) Developing noble metal-free catalysts. The defects, surface oxygenic functional groups (C=O, C-O), heteroatom doping (N-, S-) and transition metal doping (Co, Fe) in carbon-based catalysts can all improve the selectivity and catalytic activity towards H2O2. (Ⅲ) Developing non-noble metal composite catalysts. Non-noble metal composite catalysts (such as MnO2/C, CoS2/C) can promote electron transfer and improve H2O2 selectivity. Herein, the mechanism and test methods of 2e- ORR are systematically introduced. The catalysts included noble metal-based catalysts, carbon-based catalysts, and non-noble metal composite catalysts in 2e- ORR for generation of H2O2 in the recent years are summarized. The outlook of future research directions of electrochemical generation of hydrogen peroxide is also suggested.
作者简介: 雷静,2019年6月毕业于新疆大学,获得理学学士学位。现为新疆大学化学学院硕士研究生,在曹亚丽教授和李怡招副教授的指导下进行研究。目前主要研究领域为电催化氧还原。 李怡招,新疆大学化工学院副教授,硕士研究生导师,中国青少年科技创新奖获得者,入选新疆维吾尔自治区“天池博士”人才计划。目前承担国家自然科学基金、新疆维吾尔自治区自然科学基金等多项课题,在J. Mater. Chem. A、Sensor. Actuat. B、J. Colloid Interf. Sci.、Ind. Eng. Chem. Res.、ChemCatChem等期刊发表论文30余篇。主要从事功能纳米材料制备与催化应用研究。曹亚丽,博士,教授,博士研究生导师,2009年取得西安交通大学材料科学与工程专业博士学位,主要从事无机功能材料的化学合成、性能及应用研究。2014年入选“新疆杰出青年”,2015年入选“国家基金委-新疆联合基金”本地优青,主持包括4项国家自然科学基金在内的省部级科研项目10余项,先后在Appl. Catal. B、 J. Mater. Chem. A、 Green Chem.、 J. Power Sources、 Carbon、 ACS Appl. Mater. Interf.、 Chem. Eng. J.、 J. Colloid Interf. Sci.、 Electrochimica Acta、 Inorg. Chem.、 Sensors Actuat.B-Chem.等重要学术期刊上发表SCI论文百余篇,SCI他引近两千余次,授权中国发明专利16件。曾获2007年、2013年新疆维吾尔自治区科技进步一等奖,2006年、2010年、2014年、2016年、2018年自治区自然科学优秀论文奖,2012年新疆大学自然科学优秀成果奖特等奖,2016年新疆大学自然科学奖特等奖,2019年第九届新疆青年科技奖。
引用本文:
雷静, 陈子茜, 李怡招, 曹亚丽. 用于电催化氧还原制备双氧水的催化剂的研究进展[J]. 材料导报, 2021, 35(9): 9140-9149.
LEI Jing, CHEN Zixi, LI Yizhao, CAO Yali. Advances in Catalyst Materials for the Hydrogen Peroxide Production by Electrocatalytic Oxygen Reduction. Materials Reports, 2021, 35(9): 9140-9149.
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