Abstract: TinO2n-1 are considered to be a kind of high-performance conductive ceramic material, which have broad application prospect and crucial research value due to its unique physical, chemical and electrochemical properties. In addition to its own ceramic characteristics, the oxygen defects in the crystal structure endow it with the metal-like conductive properties, which break up the limitation on further application of ceramic materials because of its poor conductivity. Ti4O7 exhibits the best conductivity among TinO2n-1 materials, what’s more, it also have many other remarkable properties such as outstanding photoresponse, strong acid and alkali corrosion resistance and better electrochemical stability, which has aroused great concern of material researchers and has been widely used in the field of electrochemistry, thermoelectric materials, energy storage material, photocatalytic degradation and so on. Currently, by virtue of its distinguished electron conductivity and chemical stability, Ti4O7 was mainly used as battery electrodes and electrocatalytic support materials. The production process has been mature and commercialized. The preparationprocess of Ti4O7 still have many defects. Particle size, porosity, crystallinity and other factors all exert a great influence on the performance of Ti4O7. The method of revivifying titanium precursor at high temperature has been commonly applied to industry. However, the Ti4O7 which was treated at high temperature would come out a series problems such as particle agglomeration, serious sintering and high specific surface area, resulting in the poor performance of Ti4O7. Therefore, researchers are trying to optimize the preparation process, and explore other synthetic methods at low temperature, but there are still some unsolved problems such as low product purity and high energy consumption. The details of the process need to be further studied. At present, three main issues consititute the majority of the research upon: Ⅰ. improving the purity of the product; Ⅱ. refining grain size and controlling particle size, Ⅲ. preparation of powder with controlled morphology.Researchers constantly introduce new technologies into the preparationprocess of Ti4O7. On the basis of the sol-gel method, the core-shell hollow pipe material with high specific surface area was successfully prepared via electrospining technology, while the sintering temperature was reduced by nearly 20%. The microwave heating method was firstly adopted to obtained Ti4O7 with controlled structures by radiating only 30 minutes under microwave. In recent two years, with the deepening of research, various excellent properties of Ti4O7 have been further developed and utilized. Ti4O7 shows superior rapid charge and discharge properties and cycle stability in lithium-ion batteries, lithium-sulfur batteries, metal-air batteries, fuel cells. What’s more, it has been applied in energy storage materials, thermoelectricity materials, photoelectricity materials and many other new energy fields. This paper introduces the composition, structure and physicochemical properties of Ti4O7, summarizes the main preparation methods and typical applications of Ti4O7 ceramic, analyzes the advantages and disadvantages of various preparation methods and application requirements. And outlooks the future research directions and development trends in the field, which provide some references for the popularization and application of Ti4O7 functional ceramic material.
王译文, 王海斗, 马国政, 陈书赢, 何鹏飞, 丁述宇. Ti4O7功能陶瓷材料研究与应用现状[J]. 材料导报, 2019, 33(1): 143-151.
WANG Yiwen, WANG Haidou, MA Guozheng, CHEN Shuying, HE Pengfei, DING Shuyu. Research Progress and Application Status of Ti4O7, the Functional Ceramic Material. Materials Reports, 2019, 33(1): 143-151.
Andersson S. Acta Chemica Scandinavica,1957,11(10),1641.2 Han W Q, Zhang Y. Applied Physics Letters,2008,92(20),37.3 Graves J E, Pletcher D, Clarke R L, et al. Journal of Applied Electrochemistry,1992,22(3),200.4 Bartholomew R F, Frankl D R. Physical Review,1969,187(3),828.5 Gusev A A, Avvakumov E G, Medvedev A Z H, et al. Science of Sintering,2007,39(1),51.6 Walsh F C, Wills R G A. Electrochimica Acta,2010,55(22),6342.7 Smith J R, Walsh F C, Clarke R L. Journal of Applied Electrochemistry,1998,28(10),1021.8 Ioroi T, Senoh H, Yamazaki S I, et al. ECS Transactions,2008,11(1),1041.9 Wang G, Liu Y, Ye J, et al. Journal of Alloys & Compounds,2017,704,18.10 Cass R B. U.S. patent, US4931213,1990. 11 Hayfield P C S. Development of a new material-monolithic Ti4O7 ebonex® ceramic, Royal Society of Chemistry,2001.12 Guan Dongbo, Ma Jian. Acta Physica Sinica,2012(1),397(in Chinese).管东波,毛健.物理学报,2012(1),397.13 Han W Q, Zhang Y. Applied Physics Letters,2008,92(20),37.14 Zhu R, Liu Y, Ye J, et al. Journal of Materials Science: Materials in Electronics,2013,24(12),4853.15 Zhang X, Liu Y, Ye J, et al. Micro & Nano Letters,2013,8(5),251.16 Harada S, Tanaka K, Inui H. Journal of Applied Physics,2010,108,804.17 Houlihan J F, Mulay L N. Materials Research Bulletin,1971,6(8),737.18 Weast R C. CRC handbook of chemistry and physics,CRC Press,1989.19 Clarke R L, Harnsberger S K. American Laboratory,1988,20,8.20 Nagasawa K, Kato Y, Bando Y, et al. Journal of the Physical Society of Japan,1970,29(1),241.21 Walsh F C, Wills R G A. Electrochimica Acta,2010,55(22),6342.22 Pang Q, Kundu D, Cuisinier M, et al. Nature Communications,2014,5,4759.23 Schlenker C, Buder R, Schlenker M, et al. Physica Status Solidi,2010,54(1),247.24 Weissmann M, Weht R. Physical Review B,2011,271(3 Pt 2),F552.25 Watanabe M, Ueno W, Hayashi T. Journal of Luminescence,2007,122(1),393.26 Gusev A A, Avvakumov E G, Vinokurova O B. Science of Sintering,2003,35(3),141.27 Watanabe M. Physica Status Solidi,2009,6(1),260.28 Kao W H, Patel P, Haberichter S L. Journal of the Electrochemical Society,1997,144(6),1907.29 Li X, Zhu A L, Qu W, et al. Electrochimica Acta,2010,55(20),5891.30 Babić B, Gulicovski J, Gajić -Krstajić L, et al. Journal of Power Sources,2009,193(1),99.31 Igartua A, Fernández X, Areitioaurtena O, et al. Tribology International,2009,42(4),561.32 Gardos M N. Tribology Letters,2000,8(2-3),79.33 Graves J E, Pletcher D, Clarke R L, et al. Journal of Applied Electrochemistry,1991,21(10),848.34 Hayfield P C S, Hill A. Restoration of Buildings & Monuments,2000,6(6),647.35 Han W Q, Wang X L. Applied Physics Letters,2010,97(24),862.36 Andersson S, Magnéli A. Naturwissenschaften,1956,43(21),495.37 Chen G, Bare S R, Mallouk T E. Journal of the Electrochemical Society,2002,149(8),A109238 Graves J E, Pletcher D, Clarke R L, et al. Journal of Applied Electrochemistry,1992,22(3),200.39 Yang Fan. Preparation of catalystsupport material by reduction from transition metal (Ti, Mo) oxide and electrochemical performance of the catalysts. Doctor’s thesis, Beijing University of Technology,2013(in Chinese).杨帆.过渡金属(Ti,Mo)氧化物还原制备载体及电催化性能研究.博士论文,北京工业大学,2013.40 Wang Yizhi. Primary investigations of Magnéli phase compounds and the Magnéli compounds based composites for some electrochemical applications. Doctor’s thesis, Beijing University of Technology,2016(in Chinese).王义智.Magnéli相化合物及其复合材料电化学应用初探.博士论文,北京工业大学,2016.41 Kolbrecka K, Przyluski J. Electrochimica Acta,1994,39(11-12),1591.42 Zhang X, Liu Y, Ye J, et al. Micro & Nano Letters,2013,8(5),251.43 Yao S, Xue S, Zhang Y, et al. Journal of Materials Science: Materials in Electronics,2017,28(10),7264.44 Tang C, Zhou D, Zhang Q. Materials Letters,2012,79(23),42.45 Sen W, Sun H, Yang B, et al. International Journal of Refractory Metals and Hard Materials,2010,28(5),628.46 Li X, Liu Y, Ye J. Journal of Materials Science Materials in Electronics,2016,27(4),3683.47 Kitada A, Hasegawa G, Kobayashi Y, et al. Journal of the American Chemical Society,2012,134(26),10894.48 Tian Man, Li Xueming, He Hongyun, et al. Journal of Functional Materials,2017,48(2),2177(in Chinese).田嫚,黎学明,贺洪云,等.功能材料,2017,48(2),2177.49 Lu Y, Matsuda Y, Sagara K, et al. Advanced Materials Research,2011,415-417(1),1291.50 Toyoda M, Yano T, Tryba B, et al. Applied Catalysis B Environmental,2009,88(1-2),160.51 Portehault D, Maneeratana V, Candolfi C, et al. ACS Nano,2011,5(11),9052.52 Maneeratana V, Portehault D, Chaste J, et al. Advanced Materials,2014,26(17),2654.53 Pang Q, Kundu D, Cuisinier M, et al. Nature Communications,2014,5,4759.54 Takeuchi T, Fukushima J, Hayashi Y, et al. Catalysts,2017,7(2),65.55 Lee H, Su J H, Seshadri R C, et al. Scientific Reports,2016,6,36581.56 Mei S, Jafta C J, Lauermann I, et al. Advanced Functional Materials,2017,27(26),1701176.57 Zhang X, Zhong X, Xu W, et al. Ionics,2017,1-6.58 Nazar L F, Kundu D, Black R, et al. Energy & Environmental Science,2014,8(4),1292.59 Krstajic N V, Vracar L M, Radmilovic V R, et al. Surface Science,2007,601(9),1949.60 Escalante-Garcia I L, Duron-Torres S M, Cruz J C, et al. Minerva Anes-tesiologica,2010,33(10),736.61 Duma A D, Wu Y C, Su W N, et al. Chemcatchem,2017,5(10),1155.62 Tang B, Wei H, Zhao D, et al. Solar Energy Materials & Solar Cells,2017,161,183.63 Zaky A M, Chaplin B P. Environmental Science & Technology,2013,47(12),6554.64 Geng P, Chen G. Separation & Purification Technology,2017,185,61.65 Marinkovski M, Paunović P, Blaževska Gilev J, et al. Advances in Natural Science: Theory and Applications,2012,1(3),215.66 Tsumura T, Hattori Y, Kaneko K, et al. Desalination,2004,169,269.67 Kwon D H, Kim K M, Jang J H, et al. Nature Nanotechnology,2010,5(2),148.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2019, Vol. 33 
