通过与氧化石墨烯复合增强金属有机框架材料MOF(Ni)-74的电催化析氢性能

doi:10.11896/j.issn.1005-023X.2018.09.004

《材料导报》期刊社

2018, Vol. 32

Issue (9): 1417-1422 https://doi.org/10.11896/j.issn.1005-023X.2018.09.004

材料与可持续发展(一)—— 面向洁净能源的先进材料

通过与氧化石墨烯复合增强金属有机框架材料MOF(Ni)-74的电催化析氢性能

褚梅,李曦,李娜,侯美静,李小争,董永志,王璐

武汉理工大学化学化工与生命科学学院,武汉 430070

Improved Electrocatalytic Hydrogen-evolution Performance of Metal-Organic Framework MOF(Ni)-74 by Using Graphene Oxide Decorations

CHU Mei, LI Xi, LI Na, HOU Meijing, LI Xiaozheng, DONG Yongzhi, WANG Lu

School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, Wuhan 430070

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摘要采用溶剂热法制备了金属有机框架材料MOF(Ni)-74及其与氧化石墨烯(GO)的复合材料MOF(Ni)-GO,并利用线性伏安扫描(LSV)等电化学方法在N₂饱和的0.5 mol/L H₂SO₄溶液中对材料的电催化性能进行了检测。实验结果表明, GO的掺杂能显著提升金属有机框架材料MOF(Ni)-74的电催化活性。其中GO含量为8%时,所得复合材料表现出最好的电催化析氢活性,起始电势仅为-0.462 V,塔菲尔斜率为110 mV/dec,同时该材料也表现出很好的电化学稳定性。

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	王璐

关键词: 金属有机框架(MOFs) MOF(Ni)-74 镍氧化石墨烯电催化析氢反应

Abstract: Using a solvothermal method, the metal-organic framework MOF(Ni)-74 and a series of its derivatives MOF(Ni)-GO(w%) differing in graphene oxide (GO) content (w%) were synthesized, and subsequently the linear sweep voltammetry (LSV) test was conducted in a N₂-saturated 0.5 mol/L H₂SO₄ solution in order to determine the electrocatalytic performance of the products to hydrogen evolution reaction (HER). Our experiment confirmed the significantly improved electrocatalytic activity of the GO-decorated MOF(Ni)-74 catalysts, among which the MOF(Ni)-GO(8%) exhibited the best electrochemical catalytic performance towards HER with the lowest onset potential (-0.462 V), the smallest Tafel slope (110 mV/dec), as well as an excellent electrochemical stability.

Key words: metal-organic frameworks (MOFs) MOF(Ni)-74 niobium graphene oxide electrocatalysis hydrogen evolution reaction

出版日期: 2018-05-10 发布日期: 2018-07-06

ZTFLH:

O646

基金资助: 国家自然科学基金(51273155);中央高校基本科研业务费专项资金(2016IB005;2017IB007)

通讯作者: 李曦:通信作者,女,1968年生,教授,主要从事电化学研究 E-mail:chemlixi@whut.edu.cn

作者简介: 褚梅:女,1992年生,硕士研究生,从事电化学研究 E-mail:chumei943472820@whut.edu.cn

引用本文:

褚梅, 李曦, 李娜, 侯美静, 李小争, 董永志, 王璐. 通过与氧化石墨烯复合增强金属有机框架材料MOF(Ni)-74的电催化析氢性能[J]. 《材料导报》期刊社, 2018, 32(9): 1417-1422.
CHU Mei, LI Xi, LI Na, HOU Meijing, LI Xiaozheng, DONG Yongzhi, WANG Lu. Improved Electrocatalytic Hydrogen-evolution Performance of Metal-Organic Framework MOF(Ni)-74 by Using Graphene Oxide Decorations. Materials Reports, 2018, 32(9): 1417-1422.

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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.09.004 或 http://www.mater-rep.com/CN/Y2018/V32/I9/1417

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