Please wait a minute...
材料导报  2021, Vol. 35 Issue (8): 8076-8081    https://doi.org/10.11896/cldb.20010151
  金属与金属基复合材料 |
氧化铝陶瓷表面连续导电金膜的制备工艺及性能
刘炘城, 邵海成, 乔冠军, 陆浩杰, 于刘旭, 张相召, 刘桂武
江苏大学材料科学与工程学院,镇江 212013
Preparation Process and Performance of Continuous Conductive Au Film on Surface of Al2O3 Ceramic
LIU Xincheng, SHAO Haicheng, QIAO Guanjun, LU Haojie, YU Liuxu, ZHANG Xiangzhao, LIU Guiwu
School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China
下载:  全 文 ( PDF ) ( 7695KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 以Al2O3陶瓷作为基底,采用磁控溅射和丝网印刷两种工艺在其表面制备导电Au膜,并通过控制变量法制备不同参数下不同厚度的Au膜,对两种制备工艺进行了系统性的深入研究。通过高精度电阻测量仪、扫描电子显微镜(SEM)、能谱仪(EDS)分析热处理前后Au膜的导电性能及微观形貌,采用激光共聚焦显微镜(CLSM)表征Au膜表面的粗糙度。结果表明:磁控溅射制备的纳米Au膜的导电膜厚阈值为30 nm,膜层对基底面粗糙度改变较小。对纳米Au膜进行600 ℃热处理后,Au发生固态润湿,导致电阻值急剧增大,导电性能下降。借助丝网印刷工艺,采用40%(质量分数)的金浆和200目丝网即可印刷得到导电性良好的Au膜,该工艺能够有效节约成本和金浆。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
刘炘城
邵海成
乔冠军
陆浩杰
于刘旭
张相召
刘桂武
关键词:  磁控溅射  丝网印刷  Au膜  导电性    
Abstract: Two methods of magnetron sputtering and screen printing were used to prepare conductive Au films on the Al2O3 ceramics surface. Under different parameters, Au films with different thicknesses were prepared by the controlled variable method. A systematic and in-depth study of the two preparation processes was carried out. Through the high-precision resistance measuring instrument, scanning electron microscope (SEM), and energy dispersive spectrometer (EDS), the conductive properties and micro-morphology of Au film before and after heat treatment were studied. The roughness of Au film surface was characterized by Confocal laser scanning microscope (CLSM). The results show that the nano-Au prepared by magnetron sputtering has a conductive film thickness threshold of 30 nm, and its film has a small change in the roughness of the substrate surface. After the nano-Au film is heat-treated at 600 ℃, Au undergoes solid state wetting, resulting in a sharp increase in its resistance value and a decrease in its electrical conductivity. By the method of screen printing, the conductive Au film is obtained by screen printing with a 200-mesh and the Au content of 40wt%, and the cost can be significantly reduced.
Key words:  magnetron sputtering    screen printing    Au film    conductivity
               出版日期:  2021-04-25      发布日期:  2021-05-10
ZTFLH:  O484.1  
基金资助: 国家重点研发计划项目(2017YFB0310400);国家自然科学基金(51572112);先进耐火材料国家重点实验室开放基金(SKLAR201903)
通讯作者:  shaohaicheng311@163.com   
作者简介:  刘炘城,现就读于江苏大学材料科学与工程学院硕士学位,主要从事电极膜层构建和压力传感器器件领域的研究。
邵海成,江苏大学材料科学与工程学院,高级工程师。2013年11月毕业于西安交通大学,材料学博士专业学位。2014年6月加入江苏大学无机材料与器件研究所工作至今,主要从事陶瓷/金属复合材料的研究以及压力传感器的工艺研发,现重点研究陶瓷电容式压力传感器结构及器件的制备、表征以及应用研究。在国内外重要期刊发表文章数十篇,申报发明专利10余项。
引用本文:    
刘炘城, 邵海成, 乔冠军, 陆浩杰, 于刘旭, 张相召, 刘桂武. 氧化铝陶瓷表面连续导电金膜的制备工艺及性能[J]. 材料导报, 2021, 35(8): 8076-8081.
LIU Xincheng, SHAO Haicheng, QIAO Guanjun, LU Haojie, YU Liuxu, ZHANG Xiangzhao, LIU Guiwu. Preparation Process and Performance of Continuous Conductive Au Film on Surface of Al2O3 Ceramic. Materials Reports, 2021, 35(8): 8076-8081.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20010151  或          http://www.mater-rep.com/CN/Y2021/V35/I8/8076
1 Fu X C, Wang Y, Quan X L, et al. Chinese Journal of Vacuum Science and Technology,2019,39(5),396(in Chinese).
付学成,王英,权雪玲,等.真空科学与技术学报,2019,39(5),396.
2 Wilkens H L, Nikroo A, Wall D R, et al. Physics of Plasmas,2007,14(5),056310.
3 Huang N K, Wang M H, Shen Y, et al. Electric Power Technology,1987(6),42(in Chinese).
黄宁康,王明华,申勇,等.电力技术,1987(6),42.
4 Choi H W, Kim E J, Hahn S H. Chemical Engineering Journal,2010,161(1-2),285.
5 Li H, Hu W B, Wu S L, et al. Chinese Journal of Vacuum Science and Technology,2014,34(8),842(in Chinese).
李亨,胡文波,吴胜利,等.真空科学与技术学报,2014,34(8),842.
6 Dong D Y, Pan A Q, Li P G, et al. Journal of Zhejiang Sci-Tech University,2015,33(11),882(in Chinese).
董大银,潘傲秋,李培刚,等.浙江理工大学学报,2015,33(11),882.
7 Jiang X S, Song X P, Sun Z Q. Journal of Instrumental Analysis,2009,28(7),780(in Chinese).
江锡顺,宋学萍,孙兆奇.分析测试学报,2009,28(7),780.
8 Quintero J H, Ospina R, Mello A. Journal of Physics Conference,2016,687(1),012006.
9 Luo J, Tian G L, Zhang L L, et al. Chinese Academic Journal Electronic Publishing House,2019,43(10),1656(in Chinese).
罗军,田刚领,张柳丽,等.电源技术,2019,43(10),1656.
10 Sun X B, Gao Y B, Xu P. Chinese Journal of High Pressure Physics,2019(5),1(in Chinese).
孙晓波,高玉波,徐鹏.高压物理学报,2019(5),1.
11 Zhou M, Zhang Q M, Chen J Y, et al. Chinese Journal of Rare Metals,2021,45(2),210(in Chinese).
周敏,张庆猛,陈均优,等.稀有金属,2021,45(2),210.
12 Zhou B B, Zhang N, Zhao J N, et al. Powder Metallurgy Industry,2019,29(2),73(in Chinese).
周彬彬,张宁,赵介南,等.粉末冶金工业,2019,29(2),73.
13 Liu X C, Guo R. Materials Science and Engineering of Powder Metallurgy,2019,24(1),58(in Chinese).
刘咸超,郭容.粉末冶金材料科学与工程,2019,24(1),58.
14 Xin C L, Li N, Yan J Z. Transactions of the China Welding Institution,2018,39(9),45(in Chinese).
辛成来,李宁,颜家振.焊接学报,2018,39(9),45.
15 He L F. Defect generation mechanism in sputtered Au films on PMMA substrates. Master's Thesis, Dalian University of Technology, China,2018(in Chinese).
何柳丰.溅射在PMMA基片上的金薄膜缺陷产生机理.硕士学位论文,大连理工大学,2018.
16 Huang Z K. High temperature wetting and interfacial behavior of Al-Si-X/(Pd-)SiC system. Master's Thesis, Jiangsu University, China,2018(in Chinese).
黄志坤.Al-Si-X/(Pd-)SiC体系的高温润湿与界面行为研究.硕士学位论文,江苏大学,2018.
17 Wang W. Synthesis of Au functionalized ZnO nano composite materials for improved gas sensing performance. Master's Thesis, Henan Normal University, China,2012(in Chinese).
王卫.Au修饰ZnO纳米复合材料的合成及其气敏性能研究.硕士学位论文,河南师范大学,2012.
18 Dong Y, Wang Y, Xing H H, et al. Journal of Electrochemistry,2015,21(1),85(in Chinese).
董莹,王勇,邢欢欢,等.电化学,2015,21(1),85.
19 Yin Z W, Kang Y X, Zhao H, et al. Chinese Journal of Luminescence,2014,35(8),964(in Chinese).
殷子文,康艺馨,赵赫,等.发光学报,2014,35(8),964.
20 Kashin A S, Ananikov V P. Russian Chemical Bulletin,2011,60(12),2602.
21 Gu T P, Gan G Y, Yu X L, et al. Nonferrous Metals Engineering,2019,9(10),7(in Chinese).
谷天鹏,甘国友,余向磊,等.有色金属工程,2019,9(10),7.
[1] 郦其乐, 杨勇, 魏玉全, 刘盟, 周洪军, 霍同林, 黄政仁. 不同B/C摩尔比碳化硼薄膜的光学性能[J]. 材料导报, 2021, 35(2): 2006-2011.
[2] 孙绍琦, 王景芹, 朱艳彩, 张广智, 包志舟. 第一性原理分析La、W共掺杂SnO2的导电性[J]. 材料导报, 2020, 34(Z1): 48-52.
[3] 赵秋萍, 钱庆一, 张斌, 牟志星, 张兴凯. 质子交换膜燃料电池金属双极板表面碳基防护镀层研究进展[J]. 材料导报, 2020, 34(Z1): 395-399.
[4] 梁康, 任玉荣, 唐有根, 孙旦, 贾树勇, 王海燕, 黄小兵. 钛酸锂用于钠离子电池负极的研究进展[J]. 材料导报, 2020, 34(9): 9041-9047.
[5] 王鑫, 仲崇贵, 李桦, 董正超. 超导薄膜FeSe和FeS0.5Se0.5的磁性与电子特性的研究[J]. 材料导报, 2020, 34(4): 4068-4072.
[6] 余登德, 张仁耀, 沈月, 闻明, 刘洪喜1,. 混合表面纳米化制备钛表面Ru/Ti薄膜的结构及耐蚀性能[J]. 材料导报, 2020, 34(24): 24086-24091.
[7] 吴珊妮, 赵远, 姜宏, 文峰, 熊春荣. 具有优良隔热和力学性能的低热导率W/Al2O3纳米多层功能膜的构建[J]. 材料导报, 2020, 34(2): 2023-2028.
[8] 闫美佳, 顾灵雅, 刘江浩, 辛智青. 可拉伸导体的印刷制备概述[J]. 材料导报, 2020, 34(19): 19122-19127.
[9] 黄勇, 冉小龙, 严晓娟. 压缩量对单晶铜冷压焊接接头组织及性能的影响[J]. 材料导报, 2020, 34(12): 12110-12114.
[10] 汪国军, 白煜, 胡少杰, 张敏, 王书蓓, 万飞. 退火工艺对磁控溅射生长的Pt薄膜微观结构及电性能的影响[J]. 材料导报, 2019, 33(Z2): 56-60.
[11] 赵笑昆, 李博研, 张增光. 磁控溅射沉积制备Al掺杂ZnO薄膜的棒状晶粒生长[J]. 材料导报, 2019, 33(z1): 112-115.
[12] 周超, 李得天, 周晖, 张凯锋, 曹生珠. MEMS器件真空封装用非蒸散型吸气剂薄膜研究概述[J]. 材料导报, 2019, 33(3): 438-443.
[13] 季鑫, 张朝民. CIGS叠层太阳能电池的中间层及稳定性的研究进展[J]. 材料导报, 2019, 33(23): 3915-3920.
[14] 杨秀钰, 陈诺夫, 张航, 陶泉丽, 徐甲然, 陈梦, 陈吉堃. 对非晶硅薄膜进行快速磷扩散以获得本征薄层异质结[J]. 材料导报, 2019, 33(20): 3353-3357.
[15] 孙科学, 常月欣, 成谢锋. xBiInO3-(1-x)PbTiO3薄膜的横向压电特性[J]. 材料导报, 2019, 33(14): 2299-2304.
[1] Wei ZHOU, Xixi WANG, Yinlong ZHU, Jie DAI, Yanping ZHU, Zongping SHAO. A Complete Review of Cobalt-based Electrocatalysts Applying to Metal-Air Batteries and Intermediate-Low Temperature Solid Oxide Fuel Cells[J]. Materials Reports, 2018, 32(3): 337 -356 .
[2] Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO2/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[3] Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[4] Dongyong SI, Guangxu HUANG, Chuanxiang ZHANG, Baolin XING, Zehua CHEN, Liwei CHEN, Haoran ZHANG. Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials[J]. Materials Reports, 2018, 32(3): 368 -372 .
[5] Huanchun WU, Fei XUE, Chengtao LI, Kewei FANG, Bin YANG, Xiping SONG. Fatigue Crack Initiation Behaviors of Nuclear Power Plant Main Pipe Stainless Steel in Water with High Temperature and High Pressure[J]. Materials Reports, 2018, 32(3): 373 -377 .
[6] Miaomiao ZHANG,Xuyan LIU,Wei QIAN. Research Development of Polypyrrole Electrode Materials in Supercapacitors[J]. Materials Reports, 2018, 32(3): 378 -383 .
[7] Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[8] Yunzi LIU,Wei ZHANG,Zhanyong SONG. Technological Advances in Preparation and Posterior Treatment of Metal Nanoparticles-based Conductive Inks[J]. Materials Reports, 2018, 32(3): 391 -397 .
[9] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[10] Lanyan LIU,Jun SONG,Bowen CHENG,Wenchi XUE,Yunbo ZHENG. Research Progress in Preparation of Lignin-based Carbon Fiber[J]. Materials Reports, 2018, 32(3): 405 -411 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed