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材料导报  2023, Vol. 37 Issue (20): 22030247-12    https://doi.org/10.11896/cldb.22030247
  高分子与聚合物基复合材料 |
碳纤维增强聚合物基复合材料界面特性研究进展
李美琪1, 李晓飞1, 王瑞涛2, 聂林峰1, 张润1, 张冬海1,*, 陈运法1,3,*
1 中国科学院过程工程研究所多相复杂系统国家重点实验室,北京 100190
2 天津大学浙江研究院,浙江 宁波 315201
3 中国科学院大学材料与光电研究中心,北京 100049
Research Progress on the Interface Properties of Carbon Fiber Reinforced Polymer Matrix Composites
LI Meiqi1, LI Xiaofei1, WANG Ruitao2, NIE Linfeng1, ZHANG Run1, ZHANG Donghai1,*, CHEN Yunfa1,3,*
1 State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
2 Zhejiang Institute of Tianjin University, Ningbo 315201, Zhejiang, China
3 Center of Materials Science and Optoelectronics Engineering, University of the Chinese Academy of Sciences, Beijing 100049, China
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摘要 与传统金属材料相比,碳纤维增强聚合物基复合材料(Carbon fiber reinforced polymer matrix composites,CFRPMC)在比强度、密度等方面优势明显,已广泛应用于机械制造、交通运输、航空航天等领域。除了碳纤维和聚合物基体,二者相互间的界面特性也对CFRPMC的理化性能有着重要影响,并成为复合材料技术领域倍受关注的研究热点。
CFRPMC界面层是碳纤维与聚合物基体间的过渡区域,其受碳纤维表面特性、聚合物分子链极性等众多因素影响,目前尚不能对其直接定量、定性分析。但随着材料检测技术的进步,CFRPMC界面特性研究不断深入,相关技术如SEM、TEM、AFM、各种光谱、宏观表面分析和力学性能测试等已大量用于复合材料界面组成、结构形态和微观力学特性的研究。 本文综述了碳纤维增强聚合物基复合材料界面特性研究的进展,详细论述了碳纤维和聚合物基体的界面理论、界面分析表征方法及界面性能的影响因素。通过对比与分析,总结了CFRPMC界面研究的最新进展,并对其未来的发展趋势进行了展望。
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李美琪
李晓飞
王瑞涛
聂林峰
张润
张冬海
陈运法
关键词:  碳纤维  复合材料  界面  表征    
Abstract: Compared with traditional metal materials, carbon fiber reinforced polymer matrix composites(CFRPMC) have obvious advantages in specific strength and density, and have been widely used in machinery manufacturing, transportation, aerospace and other fields. In addition to carbon fiber and polymer matrix, the interfacial properties between the two also have an important impact on the physical and chemical properties of CFRPMC, and have become a research hotspot in the field of composite material technology.
The physical and chemical properties of CFRPMC are not only closely related to the properties of carbon fiber and polymer matrix, but also affected by the interface properties between them. CFRPMC is gaining more and more interest due to the rapid development of the composite material industry, mainly focusing on the study of its interface properties. In addition to carbon fiber and the polymer matrix, the interfacial properties of them also have an important impact on the physical and chemical properties of CFRPMC, and have become a research hotspot in the field of composite materials technology.
The CFRPMC interface is the transition region between the carbon fiber and the polymer matrix, which is affected by many factors such as the surface characteristics of the carbon fiber and the polarity of the polymer molecular chain. At present, it can’t be directly quantitatively and qualitatively analyzed. However, with the development of material detection technology, related technologies such as SEM, TEM, AFM, various spectroscopy, macroscopic surface analysis and mechanical property testing, have been widely used in the interface composition, structural morphology and mechanical properties of composites. In this paper, the research progress of the interface of CFRPMC is reviewed, and the interface theory, interface analysis and characterization methods and the influencing factors of interface properties of carbon fiber and polymer matrix are discussed in detail. Through comparison and analysis, the latest progress of CFRPMC interface research is summarized, and the future development trends are outlooked.
Key words:  carbon fiber    composite    interface    characterization method
出版日期:  2023-10-25      发布日期:  2023-10-19
ZTFLH:  O6-1  
基金资助: “科技助力经济2020”重点专项“高性能绿色水性工业涂料涂装应用及产业化”项目(2020ZLHJ02);中国科学院过程工程研究所多相复杂系统国家重点实验室开放基金资助(MPCS-2021-D-11)
通讯作者:  *张冬海,中科院过程工程研究所正高级工程师,博士研究生导师,全国专业标准化技术委员会委员。主要研究方向为无机/有机复合功能材料,通过有机基体结构修饰及无机颗粒的制备、表/界面设计等制备高性能的功能化复合材料。dhzhang@ipe.ac.cn
陈运法,中科院过程工程研究所研究员、博士研究生导师。1984年本科毕业于河北矿冶学院,1987年获中国科学院化工冶金所硕士学位,1993年获法国斯特拉斯堡路易-巴斯德大学博士学位。主要从事纳米功能材料与组装技术、环境净化材料及工程应用等研究工作,发表SCI论文280余篇,申请发明专利100余项,出版专著3部,获国家发明奖、国家专利奖各1项。chenyf@ipe.ac.cn   
作者简介:  李美琪,2020年6月于河北工业大学获得工学学士学位。现为中科院过程工程研究所硕士研究生。主要研究方向为有机/无机复合材料。
引用本文:    
李美琪, 李晓飞, 王瑞涛, 聂林峰, 张润, 张冬海, 陈运法. 碳纤维增强聚合物基复合材料界面特性研究进展[J]. 材料导报, 2023, 37(20): 22030247-12.
LI Meiqi, LI Xiaofei, WANG Ruitao, NIE Linfeng, ZHANG Run, ZHANG Donghai, CHEN Yunfa. Research Progress on the Interface Properties of Carbon Fiber Reinforced Polymer Matrix Composites. Materials Reports, 2023, 37(20): 22030247-12.
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http://www.mater-rep.com/CN/10.11896/cldb.22030247  或          http://www.mater-rep.com/CN/Y2023/V37/I20/22030247
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