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材料导报  2023, Vol. 37 Issue (1): 21040316-9    https://doi.org/10.11896/cldb.21040316
  无机非金属及其复合材料 |
固体绝缘材料中空间电荷的主要影响因素及抑制方法
孟兆通, 张昌海, 迟庆国, 张天栋*
哈尔滨理工大学电气与电子工程学院,哈尔滨 150080
Main Influence Factors and Suppression Methods of Space Charge in Solid Insulation Materials
MENG Zhaotong, ZHANG Changhai, CHI Qingguo, ZHANG Tiandong*
School of Electrical and Electronic Engineering, Harbin University of Science and Technology, Harbin 150080, China
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摘要 空间电荷一直是影响固体绝缘材料电气性能的关键因素。空间电荷的存在会造成聚合物中电场分布不均匀,加速绝缘材料老化,甚至导致材料发生击穿破坏。本文论述了固体绝缘材料中空间电荷积聚的影响因素,指出空间电荷的积累与外加电场(电场强度、电场类型、预电压效应、极性反转等)、温度(高温、温度梯度、低温)、应力、介质结构(交联程度、绝缘厚度)等密切相关,从电极材料、表面改性、掺杂填料(形貌、尺寸、种类、含量)等方面总结了空间电荷积聚的抑制方法,还论述了空间电荷积聚与抑制的相关机制,其中基于陷阱理论的空间电荷输运机理仍需进一步深入研究。
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孟兆通
张昌海
迟庆国
张天栋
关键词:  空间电荷  极性反转  电荷积聚  表面改性  电极材料    
Abstract: The space charge has been a key factor to affect the electrical properties of solid insulation materials. The existence of space charge can cause uneven electric field distribution in polymer, accelerate the aging of insulating materials, and even lead to the breakdown of materials. This paper summarizes the influence factors of space charge accumulation in solid insulation materials, and points out that the accumulation of space charge is closely related to the applied electric field(effects of electric field, electric field type, pre-applied voltage and polarity reversal, etc.), temperature(high temperature, temperature gradient, low temperature), stress, and structure of the dielectrics(such as crosslinking degree, insulation thickness). The suppressed methods to space charge accumulation were summarized from the aspects of electrode materials, surface modification and doping fillers(morphology, size, type and content). The relevant mechanisms of space charge accumulation and suppression are discussed, and the space charge transport mechanism based on trap theory still needs to be further studied.
Key words:  space charge    polarity reversal    charge accumulation    surface modification    electrode material
出版日期:  2023-01-10      发布日期:  2023-01-31
ZTFLH:  TM215  
基金资助: 黑龙江省自然科学基金(ZD2020E009)
通讯作者:  * 张天栋,2017年获得哈尔滨工业大学材料物理与化学专业工学博士学位。现为哈尔滨理工大学电气与电子工程学院副教授。研究领域主要为电工绝缘材料的结构设计与性能优化研究,以第一作者或通信作者发表学术论文60余篇。tdzhang@hrbust.edu.cn   
作者简介:  孟兆通,2021年获得哈尔滨理工大学电气工程专业硕士学位,现为哈尔滨理工大学电气工程(高电压与绝缘技术)专业博士研究生,研究方向为电缆附件用绝缘材料、储能电介质结构设计等。
引用本文:    
孟兆通, 张昌海, 迟庆国, 张天栋. 固体绝缘材料中空间电荷的主要影响因素及抑制方法[J]. 材料导报, 2023, 37(1): 21040316-9.
MENG Zhaotong, ZHANG Changhai, CHI Qingguo, ZHANG Tiandong. Main Influence Factors and Suppression Methods of Space Charge in Solid Insulation Materials. Materials Reports, 2023, 37(1): 21040316-9.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21040316  或          http://www.mater-rep.com/CN/Y2023/V37/I1/21040316
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