REVIEW PAPER |
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Progress in Application of Porous Materials in VOCs Adsorption During Wood Drying |
Xia WANG1(),Liping AN1,Xiaotao ZHANG1,2,Ximing WANG2
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1 College of Science, Inner Mongolia Agricultural University, Hohhot 010018 2 College of Material Science and Art Design, Inner Mongolia Agricultural University, Hohhot 010018 |
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Abstract A series of volatile organic compounds (VOCs) will be produced in drying process of wood, which will seriously endanger human body and destroy the ecological environment. Currently, it has been an universal concern to control the release and adsorption of VOCs in drying process of wood industry and seek the eco-friendly, highly effective adsorbents. This review firstly summarized the VOCs adsorption on the activated carbon, activated carbon fiber, activated carbon nanofiber, molecular sieves and montmorillonite mesoporous materials. Secondly, the utilization of the novel and appropriate MOFs in the VOCs adsorption during drying process of wood is introduced. Finally, the application of MOFs materials based on the achievements is proposed.
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Published: 10 January 2018
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Compound | Formaldehyde | Acetaldehyde | Acraldehyde+butanone | Carbinol | Formic acid | Benzoic acid | The total release amount/(mg·m-3) | 7 505 | 7 606 | 284 | 46 468 | 14 369 | 74 |
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The release amount of part VOCs in wood drying process
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Sample | SBET/(m2·g-1) | Smic/(m2·g-1) | Smeso/(m2·g-1) | Adsorption capacity/(mg·g-1) | AC-1 | 941.07 | 769.11 | 171.96 | 151.3 | AC-2 | 1 314.94 | 978.93 | 336.00 | 198.9 | AC-3 | 1 072.84 | 510.36 | 562.48 | 148.1 | AC-4 | 1 381.76 | 256.02 | 1 125.74 | 63.3 |
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The adsorption effects on activated carbons
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Sample | SBET/(m2·g-1) | Smic/(m2·g-1) | Mass fraction/% | | C | O | N | C-C | C-O | C=O | O-C=O | AC-2 | 1 314.94 | 978.93 | 95.170 | 4.259 | 0.571 | 53.37 | 15.78 | 12.83 | 13.19 | AC-2-HNO3 | 989.92 | 735.59 | 92.846 | 6.078 | 1.077 | 46.66 | 15.98 | 14.11 | 16.09 | AC-2-H2O2 | 1 088.78 | 784.79 | 94.132 | 5.631 | 0.237 | 49.04 | 15.55 | 15.23 | 15.01 | AC-2-NH3-NH4Cl | 1 079.85 | 803.46 | 95.544 | 3.840 | 0.616 | 61.78 | 10.45 | 12.14 | 11.38 |
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The characteristic parameters and surface element content on activated carbon after HNO3, H2O2, NH3-NH4Cl treatment
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Activated carbon | Theoretical effective adsorption of pore volume/(mL·g-1) | Methylbenzene | Dimethylbenzene | Acetone | Carbinol | 1,2-Dichloroethane | AC-1 | 0.326 17 | 0.332 98 | 0.378 61 | 0.356 66 | 0.311 42 | AC-2 | 0.278 78 | 0.273 08 | 0.431 48 | 0.411 05 | 0.271 81 | AC-3 | 0.306 73 | 0.317 8 | 0.447 98 | 0.439 17 | 0.303 13 |
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The competitive adsorption effects on different activated carbons
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Adsorbate | Saturation of adsorbance mg·g-1 | Penetration of adsorbance mg·g-1 | Saturation time min | Penetration time min | Methylbenzene | 32.469 8 | 0.359 3 | 190 | 110 | Acetic ether | 52.290 7 | 0.674 6 | 295 | 150 | Acetone | 86.404 1 | 0.963 3 | 400 | 210 |
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The related parameters of different VOCs in the fixed bed
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Schematic diagram of montmorillonite silicon oxygen tetrahedron and aluminium oxygen octahedron
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The XRD patterns of montmorillonite and sulfuric acid activated montmorillonite
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Diagram of BTEXs into MIL-101 pore
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The simple combination of lanthanum ion and glucose
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[1] | Milota M R . Emissions from wood drying[J]. Forest Products Journal, 2000,50(6):10. | [2] | Zhang G J, Li K, Lin Q , et al. Research progress of removing atmospheric pollutions by non-thermal plasma technology Materials Review B: Research Papers, 2015,29(1):137(in Chinese). | [2] | 张贵剑, 李凯, 林强 , 等. 低温等离子体技术脱除大气污染物的研究进展[J]. 材料导报:研究篇, 2015,29(1):137. | [3] | 龙玲 . 木材及其制品挥发性有机化合物释放及评价[M]. 北京: 科学出版社, 2012: 148. | [4] | Britt D, Tranchemontagne D, Yaghi O M . Metal-organic frameworks with high capacity and selectivity for harmful gases[J]. Proceedings of the National Academy of Sciences, 2008,105(33):11623. | [5] | Ferey G, Draznieks C M, Serre C , et al. A chromium terephthalate-based solid with unusually large pore volumes and surface area[J]. Science, 2005,309(5743):2040. | [6] | Zhao L Y, Lu J M, Li Q L , et al. Present situation and progress in preparation of activated carbon Science Technology and Engineering, 2008,8(11):2914(in Chinese). | [6] | 赵丽媛, 吕剑明, 李庆利 , 等. 活性碳制备及应用研究进展[J]. 科学技术与工程, 2008,8(11):2914. | [7] | Bao Y Z . Study on preparation and adsorption performance of activated carbon from Salix psammophyla[D]. Hohhot: Inner Mongolia Agricultural University, 2012(in Chinese). | [7] | 鲍咏泽 . 沙柳活性碳的制备及吸附性能研究[D]. 呼和浩特:内蒙古农业大学, 2012. | [8] | Tang J H, Liang X Y, Long D H , et al. Effects of micropore and functional groups of activated carbon on adsorption behavior of formaldehyde Carbon Techniques, 2007,26(3):21(in Chinese). | [8] | 汤进华, 梁晓怿, 龙东辉 , 等. 活性碳孔结构和表面官能团对吸附甲醛性能影响[J]. 碳素技术, 2007,26(3):21. | [9] | Sun Z . Research on selective adsorption of VOCs on activated carbon[D]. Changsha: Central South University, 2011(in Chinese). | [9] | 孙政 . 活性碳对有机气体的选择性吸附研究[D]. 长沙:中南大学, 2011. | [10] | LiuJ, Han X, Shi Y . Study on microstructure of activated carbon for acetone recovery[J]. Chemistry and Industry of Forest Products, 2003,23(1):55. | [11] | HuangZ H, Kang F Y, Yang J B , et al. Experimental and modeled results describing the adsorption of trace VOCs on activated carbon fibers Ion Exchange and Adsorption, 2001,17(6):487(in Chinese). | [11] | 黄正宏, 康飞宇, 杨骏兵 , 等. 活性碳纤维对挥发性有机的吸附及其等温线的拟合[J]. 离子交换与吸附, 2001,17(6):487. | [12] | XueW P, Sun H, Jiang L L , et al. Adsorption performance of VOCs onto activated carbon fiber Journal of Dalian Institute of Light Industry, 2007,26(2):152(in Chinese). | [12] | 薛文平, 孙辉, 姜莉莉 , 等. VOCs在活性碳纤维上吸附性能的研究[J]. 大连轻工业大学学报, 2007,26(2):152. | [13] | HuangZ H, Kang F Y, Wu H , et al. Adsorption of benzene and methyl-ethyl-ketone vapors at low concentration by wet oxidized porous carbons Journal of Tsinghua University(Science and Technology), 2000,40(10):111(in Chinese). | [13] | 黄正宏, 康飞宇, 吴慧 , 等. 湿氧化改性多孔碳对低浓度苯和丁酮蒸汽的吸附[J]. 清华大学学报(自然科学版), 2000,40(10):111. | [14] | ChenL P, Hong S G, Zhou X P , et al. Novel Pd-carrying composite carbon nanofibers based on polyaerylonitrile as a catalyst for Sonogashira coupling reaction[J]. Catalysis Communications, 2008,9(13):2221. | [15] | KimS K, Jeon S . Simultaneous determination of serotonin and dopamine at the PEDOP/MWCNTs-Pd nanoparticle modified glassy carbon electrode[J]. Journal of Nanoscience and Nanotechnology, 2012,12(3):1903. | [16] | ShirtliffV J, Hench L L . Bioactive materials for tissue engineering, regeneration and repair[J]. Journal of Materials Science, 2003,38(23):4697. | [17] | DuJ, Ye X Y, Zou G L . Adsorption Performance of Carbon Nanofiber for VOC Journal of University of Jinan(Science and Technology), 2012,26(4):337(in Chinese). | [17] | 杜婕, 叶孝勇, 邹光龙 . 活性碳纳米纤维对VOC的吸附性能[J]. 济南大学学报(自然科学版), 2012,26(4):337. | [18] | GuoZ Y, Huang J T, Xue Z H , et al. Electrospun graphene oxide/carbon composite nanofibers with welldeveloped mesoporous structure and their adsorption performance for benzene and butanone[J]. Chemical Engineering Journal, 2016,306:99. | [19] | WangQ F, Li F, Li L , et al. Study on preparation of a composite desulfurizer from biomass waste Materials Review B: Research Papers, 2016,30(4):21(in Chinese). | [19] | 王奇飞, 李芬, 李梁 , 等. 基于生物质废弃物制备复合脱硫剂的研究[J]. 材料导报:研究篇, 2016,30(4):21. | [20] | YangQ, Zhang J X, Yang J . Adsorption of VOCs on activated carbon modified by Mn Chinese Journal of Environmental Engineering, 2015,9(6):2963(in Chinese). | [20] | 杨全, 张俊香, 杨俊 . Mn改性活性炭吸附VOCs性能[J]. 环境工程学报, 2015,9(6):2963. | [21] | HaoL N, Xie Q, Li L T , et al. Catalytical preparation of mesoporous coal-based activated carbon by nitrate copper and nitrate manganese Carbon Techniques, 2008,27(4):26(in Chinese). | [21] | 郝丽娜, 解强, 李兰廷 , 等. 金属盐催化制备煤基中孔活性碳的研究[J]. 碳素技术, 2008,27(4):26. | [22] | QiaoW M, Song Y, Yoon S H , et al. Modification of commercial activated carbon through gasification by impregnated metal salts to develop mesoporous structures[J]. New Carbon Materials, 2005,20(3):198. | [23] | PeiB. Improvement of activated carbon adsorption of low concentration toluene gas purification process[D]. Shanghai: Tongji Universtiy, 2008(in Chinese). | [23] | 裴冰 . 活性碳吸附净化低浓度甲苯气体工艺改进研究[D]. 上海:同济大学, 2008. | [24] | DavisM E, Lobo R F . Zeolite and molecular sieve synjournal[J]. Chemistry of Materials, 1992,4(4):756. | [25] | ZhaoX S, Lu G Q, Millar G J . Advances in mesoporous molecular sieve MCM-41[J]. Industrial and Engineering Chemistry Research, 1996,35(7):2075. | [26] | HartmannM, Kunz S, Chandrasekar G , et al. Shaping of mesoporous molecular sieves[J]. Studies in Surface Science and Catalysis, 2007,165(5):181. | [27] | LiangX X, Bo L L, Liu J D , et al. Adsorption characteristics of typical VOCs on Cu-Mn-Ce/ZSM adsorbent fixed-bed Chinese Journal of Environmental Engineering, 2016,10(6):3152(in Chinese). | [27] | 梁欣欣, 卜龙利, 刘嘉栋 , 等. 分子筛负载型吸附剂对典型VOCs的吸附行为特性[J]. 环境工程学报, 2016,10(6):3152. | [28] | . LinX Q, , Preparation and characterization of montmorillonite based mesoporous materials and their adsorption performance for VOCs[D]. Guangzhou: Graduate University of Chinese Academy of Sciences( Guangzhou Institute of Geochemistry), 2015(in Chinese). | [28] | 林小琴 . 蒙脱石基介孔材料(MPMs)的制备与表征及其对VOCs的吸附性能研究[D].广州:中国科学院研究生院(广州地球化学研究所), 2015. | [29] | MadhusoodanaC D, Kameshima Y, Nakajima A , et al. Synjournal of high surface area Al-containing mesoporous silica from calcined and acid leached kaolinites as the precursors[J]. Journal of Collid and Interface Science, 2006,297(2):724. | [30] | GonzalezE B, Jones W, Bahranowski K , et al. ESR characterization of vanadium centers supported on Al-containing mesoporous silica[J]. Microporous and Mesoporous Materials, 2001,50(1):61. | [31] | YangH M, Deng Y H, Du C F , et al. Novel synjournal of ordered mesoporous materials Al-MCM-41 from bentonite[J]. Applied Clay Science, 2010,47(3):351. | [32] | HuC B, Yang M L, Xian X F , et al. Correlation between structural characteristics and adsorption behaviors of porous metal-organic coordination polymers Materials Review, 2008,22(1):45(in Chinese). | [32] | 胡传彬, 杨明莉, 鲜学福 , 等. 多孔金属-有机络合聚合物结构特征与其吸附行为关系[J]. 材料导报, 2008,22(1):45. | [33] | HanS S, Goddard W A, William A , et al. High H2 storage of hexagonal metal-organic frameworks from first-principles-based grand canonical monte carlo simulations[J]. Journal of Physical Chemistry C, 2008,112(35):13431. | [34] | ChenB, Eddaoudi M, Hyde S T , et al. Interwoven metal-organic framework on a periodic minimal surface with extra-large pores[J]. Science, 2001,291(5506):1021. | [35] | MuC Z, Xu F, Lei W . Application of functional metal-organic framework materials Progess in Chemistry, 2007,19(9):1345(in Chinese). | [35] | 穆翠枝, 徐峰, 雷威 . 功能金属-有机骨架材料的应用[J]. 化学进展, 2007,19(9):1345. | [36] | YanB, Ma R, Chu Z , et al. 2D Cationic metal-organic frameworks of Ag+ with mixed ligands(semi-rigid dipyridyl, 3-pmpmd, and diphosphine, dppe)[J]. Journal of Inorganic Organometallic Polymers and Materials, 2010,10(4):809. | [37] | WuH, Simmons J M, Liu Y , et al. Metal-organic frameworks with exceptionally high methane uptake: Where and how is methane stored?[J]. Chemistry, 2010,16(17):5205. | [38] | FuK, Huang S S, Zhao Z X , et al. Progress of the synjournal of metal organic frameworks materials and its application in organic gas adsorption New Chemical Materials, 2013,41(8):4(in Chinese). | [38] | 符瞰, 黄思思, 赵祯霞 . MOFs材料合成及其对有机气体吸附研究进展[J]. 化工新型材料, 2013,41(8):4. | [39] | LiY, Zhang H X, Yan K L , et al. Research progress on VOCs adsorption of metal-organic frameworks(MOFs) Guangzhou Chemical Industry, 2016,44(8):27(in Chinese). | [39] | 李莹, 张红星, 闫柯乐 , 等. MOFs材料对挥发性有机物(VOCs)的吸附研究[J]. 广州化工, 2016,44(8):27. | [40] | YaghiO M, Li G, Li H . Selective binding and removal of guests in a microprous metal-organic framework[J]. Nature, 1995,378(6558):703. | [41] | EddaoudiM, Li H, Yaghi O M . Highly porous and stable metal-organic frameworks: Structure design and sorption properties[J]. Journal of American Chemistry Society, 2000,122(7):1391. | [42] | MillwardA R, Yaghi O M . Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature[J]. Journal of American Chemistry Society, 2005,127(51):17998. | [43] | YangK, Sun Q, Xue F , et al. Adsorption of volatile organic compounds by metal-organic frameworks MIL-101: Influence of molecular size and shape[J]. Journal of Hazardous Materials, 2011,195(1):124. | [44] | YangK, Xue F, Sun Q , et al. Adsorption of volatile organic compounds by metal-organic frameworks MOF-177[J]. Journal of Environmental Chemical Engineering, 2013,1(4):713. | [45] | JhungS H, Lee J H, Yoon J W , et al. Microwave synjournal of chromium terephthalate MIL-101 and its benzene sorption ability[J]. Advanced Materials, 2010,19(19):121. | [46] | SahaD, Wei Z J, Deng S G . Hydrogen adsorption equilibrium and kinetics in metal-organic framework(MOF-5) synthesized with DEF approach[J]. Separation and Purification Technology, 2009,64(3):280. | [47] | RowsellJ L C, Yaghi O M . Metal-organic frameworks: A new class of porous materials[J]. Microporous and Mesoporous Materials, 2004,73(1-2):3. | [48] | GuZ Y, Yan X P . Metal Organic framework MIL101 for high-resolution gas-chromatographic separation of xylene isomers and ethylbenzene[J]. Angewandte Chemie, 2010,49(8):1477. | [49] | XueF. Preparation of metal-organic frameworks(MOF-177)and adsorption of VOCs[D]. HangZhou: ZheJiang University, 2013(in Chinese). | [49] | 薛峰 . 金属-有机骨架材料(MOF-177)制备及其吸附典型VOCs性能研究[D]. 杭州:浙江大学, 2013. | [50] | WangT L, Zhang Y, Wang X H , et al. Research progress in zeoliticimidazolate frameworks(ZIFs) Chemical Industry and Engineering Progress, 2015,34(11):3959(in Chinese). | [50] | 王天龙, 张燕, 王新红 , 等. 类沸石咪唑酯骨架材料(ZIFs)的研究进展[J]. 化工进展, 2015,34(11):3959. | [51] | HuangC Y, Song M, Gu Z Y , et al. Probing the adsorption characteristic of metal-organic framework MIL-101 for volatile organic compounds by quartz crystal microbalance[J]. Environme-ntal Science and Technology, 2011,45(10):4490. | [52] | YangR H, Zhang C, Huo J C , et al. Preparation and study of a novel glucoside aromatic ester based metal organic material Chinese Journal of Inorganic Chemistry, 2014,30(5):1073(in Chinese). | [52] | 杨瑞环, 张驰, 霍冀川 , 等. 基于糖苷芳香酸酯的金属有机材料的制备与研究[J]. 无机化学学报, 2014,30(5):1073. | [53] | 张瑜, 姜春明, 张红星 , 等. 挥发性有机物吸附材料研究进展[J]. 安全、健康和环境, 2016,16(6):1. | [54] | ZhangL, Peng Y X, Zhang J , et al. Adsorptive and catalytic properties in the removal of volatile organic compounds over zeolite-based materials[J]. Chinese Journal of Catalysis, 2016,37(6):800. |
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