1 Third Institute of Oceanography, Ministry of Natural Resources, Xiamen 361005, China 2 College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
Abstract: The introductions of nanomaterials into traditional membrane materials are expected to overcome the key technical problems such as tradeoff effect between selectivity and permeability, membrane fouling and chemical stability. Zero-dimensional graphene quantum dots (GQDs) have outstanding advantages of ultra-small size, large specific surface area and strong hydrophilicity. In this paper, the latest research progress about introducing GQDs or modified GQDs into membrane matrix via conventional membrane preparation methods are summarized to manipulate and optimize structures and separation performance. The influence mechanisms of GQDs or modified GQDs on the “reaction-diffusion” of interfacial polymerization process, thermodynamics of casting solution and kinetics of phase inversion, as well as the interlayer spacing of laminated membranes are discussed. The reasons why GQDs or modified GQDs endow separation membranes with new functionalities such as antibacte-rial, self-cleaning and fluorescence detection are elaborated. Finally, the opportunities and challenges of developing novel GQDs-incorporated membranes are prospected.
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