Research Progress on Structure Regulation and Surface Modification of Graphite Anode Materials for Lithium Ion Batteries
XING Baolin1,2, BAO Ti'ao1, LI Xusheng1,2, SHI Changliang1,2, GUO Hui2, WANG Zhenshuai1, HOU Lei1, ZHANG Chuanxiang1,2, YUE Zhihang1
1 Henan Key Laboratory of Coal Green Conversion, College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454000, China 2 Collaborative Innovation Center of Coal Work Safety, Jiaozuo 454000, China
Abstract: Lithium ion batteries (LIBs), which are new generation of green energy storage and conversion devices, have wide application and huge economic value. The performance of LIBs is determined by many factors with one of them being the type of anode material. Specifically, the microstructure and surface properties of the anode play a significant role in determining the performance for the battery. Among all reported carbon-based anode materials, graphite materials are the most widely used for commercial LIBs. However, the inherent disadvantages of graphite anode materials such as low reversible capacity, poor ion diffusion dynamics and electrolyte compatibility as well as high volume expansion prevent further improvement on the energy density, high current multiplier performance and cycle stability for LIBs. Therefore, it is desirable to improve the properties of graphite anode materials in order to produce high performance LIBs. Many research efforts have been made to modify the graphite anode through surface coating, chemical modification, element doping and microcrystalline structure optimization. The main methods are: ⅰ. using surface coating to build core-shell construction, and improve the compatibility between anode mate-rials and electrolyte; ⅱ. using chemical modification to control interface chemical properties, enhance the stability of SEI film (electrode/electrolyte interface film) on the surface of negative electrode material; ⅲ. doping other element in materials to adjust the electronic state and electrical conductivity of graphite microcrystalline surface, and strengthen the behavior of lithium-ion's intercalation and deintercalation of anode materials; ⅳ. optimizing microcrystalline structure to build 3D cascade nanometer channels, improve the transmission path of lithium ions, and improve the energy storage capacity and rate capability of anode materials. In this paper, the current research status and development of graphite anode materials in structural regulation and surface modification are reviewed and the development trend of such anode materials is prospected. This short review is expected to provide some guidance for the development of new carbon-based anode materials, particularly graphite based materials, for high-performance LIBs.
Zubi G, Dufo-López R, Carvalho M, et al. Renewable and Sustainable Energy Reviews, 2018, 89, 292.2 Tan Y, Wang K. Journal of Inorganic Materials. 2019,34(4), 349(in Chinese).谭毅, 王凯. 无机材料学报, 2019, 34(4), 349.3 Lu Y, Yu L, Lou X W. Chem, 2018, 4(5), 972.4 Goriparti S, Miele E, De Angelis F, et al. Journal of Power Sources, 2014, 257, 421.5 Han F, Lu A H, Li W C, et al. Progress in Chemistry, 2012, 24(12), 2443 (in Chinese). 韩飞, 陆安慧, 李文翠.化学进展, 2012, 24(12), 2443.6 Shi J, Liu Q, Zang H Y, et al. New Chemical Materials, 2019, 47(1), 42 (in Chinese). 时杰, 刘庆, 臧浩宇, 等.化工新型材料, 2019, 47(1), 42.7 Yu Y L. Improved performance of silicon-based anode materials for Li-ion batteries by buffer structure design. Ph.D. Thesis, Beijing University of Chemical Technology, China, 2018 (in Chinese).于永利. 基于缓冲结构设计改善锂离子电池硅基负极材料电化学性能的研究. 博士学位论文, 北京化工大学, 2018.8 Yan L J. Synthesis and electrochemical properties of silicon based mate-rials as anodes for lithium-ion batteries. Ph.D. Thesis, Zhejiang University, China, 2018(in Chinese). 严立京. 锂离子电池硅基负极材料制备及其电化学性能研究. 博士学位论文, 浙江大学, 2018.9 Zuo L. The preparation and performance of porous carbon and carbon composite as lithium ion battery anodes. Master's Thesis, Jiangxi Normal University, China, 2015 (in Chinese).左莉. 多孔碳材料以及碳复合物负极材料的制备及锂离子电池性能的研究. 硕士学位论文, 江西师范大学, 2015.10 De Las Casas C, Li W. Journal of Power Sources, 2012, 208, 74.11 Li H, Zhou H. Chemical Communications, 2012, 48(9), 1201.12 Nozaki H, Nagaoka K, Hoshi K, et al. Journal of Power Sources, 2009, 194(1), 486.13 Zou L, Kang F, Zheng Y, et al. Electrochimica Acta, 2009, 54(15), 3930.14 Wang C, Zhao H, Wang J, et al. Ionics, 2013, 19(2), 221.15 Liu S, Ying Z, Wang Z, et al. New Carbon Materials, 2008, 23(1), 30.16 Han H, Park H, Kil K C, et al. Electrochimica Acta, 2015, 166, 367.17 Lin Y, Huang Z, Yu X, et al. Electrochimica Acta, 2014, 116, 170.18 Zhao Z, Jia X C, Li J, et al. New Carbon Materials, 2013, 28(5), 385 (in Chinese). 赵琢, 贾晓川, 李晶, 等.新型炭材料, 2013, 28(5), 385.19 Guérin K, Dubois M, Houdayer A, et al. Journal of Fluorine Chemistry, 2012, 134, 11.20 Lee C, Han Y, Seo Y D, et al. Carbon, 2016, 103, 28.21 Abdelkader-Fernández V K, Morales-Lara F, Melguizo M, et al. Applied Surface Science, 2015, 357, 1410.22 Shim J, Striebel K A. Journal of Power Sources, 2007, 164(2), 862.23 Ma Z H. Surface modification of nature graphite for anode of Lithium-ion battery. Master's Thesis, Henan Normal University, China, 2011 (in Chinese).马志华. 天然石墨负极材料表面改性研究. 硕士学位论文, 河南师范大学, 2011.24 Fu L J, Liu H, Li C, et al. Solid State Sciences, 2006, 8(2), 113.25 Lin Y, Huang Z, Yu X, et al. Electrochimica Acta, 2014, 116, 170.26 Guérin K, Dubois M, Houdayer A, et al. Journal of Fluorine Chemistry, 2012, 134, 11.27 Matsumoto K, Li J, Ohzawa Y, et al. Journal of Fluorine Chemistry, 2006, 127(10), 1383.28 Abdelkader-Fernández V K, Morales-Lara F, Melguizo M, et al. Applied Surface Science, 2015, 357, 1410.29 Lee C, Han Y, Seo Y D, et al. Carbon, 2016, 103, 28.30 Nakajuma T. In: Advanced Fluoride-based materials for energy conversion. Netherlands, 2015, pp. 203.31 Chen J, Xu H. Materials Review A:Review Papers, 2017, 31(5), 36 (in Chinese).陈坚, 徐晖. 石材料导报:综述篇, 2017, 31(5), 36.32 Bloom I, Dietz Rago N, Sheng Y, et al. Journal of Power Sources, 2019, 432, 73.33 Kim J G, Liu F, Lee C, et al. Solid State Sciences, 2014, 34, 38.34 Liu C, Liu X, Tan J, et al. Journal of Power Sources, 2017, 342, 157.35 Zhou Y, Zeng Y, Xu D, et al. Electrochimica Acta, 2015, 184, 24.36 Bai A, Wang L, Li J, et al. Journal of Power Sources, 2015, 289, 100.37 Li Y, Chang B, Li T, et al. Electrochemistry Communications, 2016, 72, 69.38 Zhang Y, Jiang Y, Li Y, et al. Journal of Power Sources, 2015, 281, 425.39 Zhang T L, Wang C M, Song Z H, et al. Advanced Ceramics, 2014, 35(5), 5 (in Chinese). 张田丽, 王春梅, 宋子会.现代技术陶瓷, 2014, 35(5), 5.40 Zhu K, Qi H, Sun X, et al. Electrochimica Acta, 2019, 299, 853.41 Goriparti S, Miele E, De Angelis F, et al. Journal of Power Sources, 2014, 257, 421.42 Trifonova A, Winter M, Besenhard J O. Journal of Power Sources, 2007, 174, 800.43 Xu K S. The preparation and impoved characteristics of silicon carbon composite materials for Lithium ion batteries. Master's Thesis, Harbin Institute of Technology, China, 2011 (in Chinese).许可松. 锂离子电池硅碳复合材料的制备及改性研究. 硕士学位论文, 哈尔滨工业大学, 2011.44 Tao T, He L, Li J, et al. Journal of Alloys and Compounds, 2014, 615, 1052.45 Wang X, Wen Z, Lin B, et al. Journal of Power Sources, 2008, 184(2), 508.46 Wang Y, Yang L, Hu R, et al. Electrochimica Acta, 2014, 125, 421.47 Jin B, Liu A, Liu G, et al. Electrochimica Acta, 2013, 90, 426.48 Zou Z, Jiang C. Journal of Materials Science & Technology, 2019, 35(4), 644.49 Han F. Design of porous carbon-modified hybrid anodes and its electrochemical performance for Lithium ion batteries. Ph.D. Thesis, Dalian University of Technology, China, 2014 (in Chinese).韩飞. 炭修饰锂离子电池负极材料的设计及性能研究.博士学位论文,大连理工大学, 2014. 50 Huang S, Li Z, Wang B, et al. Advanced Functional Materials, 2018, 28(10), 1706294.51 Tian M, Wang W, Liu Y, et al. Nano Energy, 2015, 11, 500.52 Zheng C, Hu X, Sun X, et al. Electrochimica Acta, 2019, 306, 339.53 Yue X, Sun W, Zhang J, et al. Journal of Power Sources, 2016, 331, 10.54 Ni L, Wang R, Wang H, et al. Microporous and Mesoporous Materials, 2019, 282, 197.55 Cuesta N, Cameán I, Ramos A, et al. Electrochimica Acta, 2016, 222, 264.56 Hu Y S, Adelhelm P, Smarsly B M, et al. Advanced Functional Mate-rials, 2007, 17(12), 1873.57 Xing B L, Zhang C X, Cao Y J, et al. Fuel Processing Technology, 2018, 172, 162.58 Canal-Rodríguez M, Arenillas A, Menéndez J A, et al. Carbon, 2018, 137, 384.59 Shi M R, Li M Y, Duan X C, et al. Chinese Journal of Power Sources, 2011, 35(11), 1346 (in Chinese). 石美荣, 李孟元, 段兴潮, 等.电源技术, 2011, 35(11), 1346.60 Xing B L, Zhang C X, Liu Q R, et al. Journal of Alloys and Compounds, 2019, 795, 91.61 Wang Z, Zhang F, Lu Y, et al. Materials Research Bulletin, 2016, 83, 590.62 Kakunuri M, Sharma C S. Electrochimica Acta, 2015, 180, 353.63 Ma H F, Jiang H, Jin Y, et al. Carbon, 2016, 105, 586.64 Zhang H, Sun X, Zhang X, et al. Journal of Alloys and Compounds, 2015, 622, 783.65 Shan H, Xiong D, Li X, et al. Applied Surface Science, 2016, 364, 651.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2020, Vol. 34 
