柔性储能器件的电极设计研究进展

doi:10.11896/cldb.19110021

材料导报

2020, Vol. 34

Issue (1): 1177-1186 https://doi.org/10.11896/cldb.19110021

柔性储能器件的电极设计研究进展

李一帆^1,,刘宇航^1,,孙晋蒙¹,吴乾鑫¹,龚昕¹,杜洪方¹,艾伟^1,,黄维^1,2,3,

1 西北工业大学陕西柔性电子研究院,西安710072
2 南京工业大学先进材料研究院,南京 211816
3 南京邮电大学信息材料与纳米技术研究院,南京 210023

Progress of Electrode Designs for Flexible Energy Storage Devices

LI Yifan^1,,LIU Yuhang^1,,SUN Jinmeng¹,WU Qianxin¹,GONG Xin¹,DU Hongfang¹,AI Wei^1,,HUANG Wei^1,2,3,

1 Shaanxi Institute of Flexible Electronics,Northwestern Polytechnical University,Xi'an 710072,China
2 Institute of Advanced Materials,Nanjing Tech University,Nanjing 211816,China
3 Institute of Advanced Materials,Nanjing University of Posts and Telecommunications,Nanjing 210023,China

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摘要随着制造技术的飞速发展,便携式电子设备正朝着柔性化、轻质化、微型化及智能化方向发展,能够弯曲、折叠、扭曲、拉伸等协调变形的柔性电子设备应运而生。作为柔性电子设备的关键部件,储能器件的设计成为柔性电子实际应用必须攻克的难题。传统储能器件是刚性的,难以与柔性电子设备相适配,在变形时易造成电极材料与集流体分离,严重影响了电化学性能,甚至造成短路,产生重大的安全隐患。基于此,开发新型柔性储能器件,如柔性锂离子电池、柔性锂硫电池、柔性锂金属电池、柔性超级电容器等,已成为当今学术界和产业界研究的热点。
近年来,基于本征柔性材料组装以及刚性材料柔性化设计两种方式获得的柔性储能器件取得了很大进展。金属纤维(如铝、铜)、聚合物纤维(如聚吡咯、聚苯胺)和碳基材料(如碳纳米纤维、碳纳米管、石墨烯及其复合材料)等因具有本征柔性的特征,在柔性储能器件中扮演着重要角色。其他诸如钴酸锂、钛酸锂等无机刚性材料的脆性较大,需通过合理的结构设计实现柔性。此外,柔性储能系统还需具备高容量、高效率、轻薄、安全等综合性能来满足实际的应用需求。
本综述围绕本征和非本征柔性储能器件,探讨材料微观结构与器件宏观性能的构效关系,重点阐述各类柔性电极材料的制备方法、力学性能和电化学性能,并对未来柔性储能器件发展、电极材料设计面临的挑战提出了一些见解。

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	李一帆
	刘宇航
	孙晋蒙
	吴乾鑫
	龚昕
	杜洪方
	艾伟
	黄维

关键词: 柔性电子电化学储能电极材料本征柔性非本征柔性

Abstract: In light of the rapid development of electronic technologies, portable electronic devices are promoted to evolve with fascinating flexibility, mi-niaturization and intellectualization. Flexible electronics with the features of bent, folded, twisted, stretched and coordinated deformations are now the booming fields of research. As a crucial component of flexible electronic devices, the design of reliable energy storage systems has become the key challenges towards the applications of flexible electronics. Traditional energy storage devices are rigid, which is easy to break under applied deformations. Accordingly, the separation of electrode materials and current collector seriously deteriorates the electrochemical perfor-mances and even causes a short circuit, resulting in safety issues. To this end, flexible energy storage devices, such as flexible Li-ion batteries, flexible Li-S batteries and flexible lithium metal batteries, have gained paramount interests in academia and industry.
In recent years, great progress has been made in flexible energy storage devices based on intrinsic flexible materials assembly andrigid mate-rials flexible designs. Metal fibers (e.g., Al and Cu), polymer fibers (e.g., polypyrrole and polyaniline), and carbon-based materials (e.g., carbon nanofibers, carbon nanotubes and graphene) have so far been widely applied in flexible energy storage devices because of their intrinsic fle-xibility. While the other materials with the characteristics of brittleness, for example, lithium cobaltate and lithium titanate, can achieve a certain degree of flexibility after reasonable structural design. In addition, the practical application of flexible energy storage systems must meet the crite-rions in terms of high capacity, high efficiency, light weight, high safety and so on.
This review dedicates to discuss the relationships between the microstructure of nanomaterials and the performance of devices. The preparation methods, mechanical properties and electrochemical performances of current flexible systems are briefly overviewed. Moreover, instructive perspectives are provided so that to enlighten more insightful contributions to flexible electronics.

Key words: flexible electronics electrochemical energy storage electrode materials intrinsic flexibility extrinsic flexibility

发布日期: 2020-01-15

ZTFLH:

TB34

基金资助: 国家自然科学基金委青年项目(51902261);陕西省自然科学基础研究计划资助项目(2019JQ-025);中央高校基本科研业务费专项(31020180QD094;31020180QD116)

通讯作者: iamwai@nwpu.edu.cn; iamwhuang@nwpu.edu.cn

作者简介: 李一帆,2019年6月毕业于太原科技大学,获得材料成型及控制工程专业工学学士学位。现为西北工业大学柔性电子研究院硕士研究生,在艾伟教授的指导下从事新能源器件及柔性储能研究。
刘宇航,2018年6月毕业于兰州大学物理科学与技术学院,获得工学硕士学位。现为西北工业大学柔性电子研究院博士研究生,在黄维院士和艾伟教授的指导下开展高能锂离子/锂金属电池用碳纳米复合纤维电极的设计及研究。
艾伟,新加坡南洋理工大学理学博士,2018年3月加盟西北工业大学柔性电子研究院,任教授、博士研究生导师。目前担任柔性电子材料与器件工业和信息化部重点实验室学术秘书,先进能源研究所副所长,入选西北工业大学“翱翔海外学者引进计划”A类资助。主要研究方向:电化学能源材料与技术、新能源器件及其柔性智能。近年来,在Advanced Materials、Advanced Energy Materials、Advanced Functional Materials等国际著名学术期刊上发表SCI收录论文35篇,其中第一/通讯作者论文15篇,ESI高被引论文4篇、热点论文1篇,他引1700余次,H指数为18。申请国际国内发明专利8项,其中已授权中国发明专利3项。曾获得朗坤奖教金惟实(贡献)奖(2018年)、国家优秀自费留学生奖学金(2015年)等多项奖励。
黄维,中国科学院院士,俄罗斯科学院外籍院士、名誉博士,亚太材料科学院院士、东盟工程与技术科学院外籍院士、巴基斯坦科学院院士,西北工业大学常务副校长,教授、博导,有机电子学/柔性电子学家。教育部“长江学者”特聘教授,国家杰出青年科学基金获得者,“千人计划”(溯及既往)国家特聘专家,科技部“973”项目首席科学家。亚太地区工程组织联合会(FEIAP)主席、英国谢菲尔德大学名誉博士、英国皇家化学学会会士、美国光学学会会士、国际光学工程学会会士,中国科协常委,中国化学会副理事长,中国化工学会副理事长,Research、npj Flexible Electronics和Advanced Materials等国际权威学术杂志主编或(顾问)编委。长期从事有机光电、柔性电子等相关领域的研究,并取得了大量系统性、创新性的研究成果,以第一或通信作者身份在Nature、Nature Materials、Nature Photonics、Nature Nanotechnology、Nature Electronics、Nature Communications、Advanced Materials、Journal of the American Chemical Society等SCI学术期刊发表研究论文760余篇,H因子为121,国际同行引用70 000余次,是材料科学与化学领域全球高被引学者,获授权美国、新加坡和中国等国发明专利380余项,出版了《有机电子学》《生物光电子学》《有机薄膜晶体管材料器件和应用》《OLED显示技术》等学术专著。曾获国家自然科学奖二等奖和何梁何利基金科技进步奖等奖励,成果入围中国高等学校十大科技进展。

引用本文:

李一帆,刘宇航,孙晋蒙,吴乾鑫,龚昕,杜洪方,艾伟,黄维. 柔性储能器件的电极设计研究进展[J]. 材料导报, 2020, 34(1): 1177-1186.
LI Yifan,LIU Yuhang,SUN Jinmeng,WU Qianxin,GONG Xin,DU Hongfang,AI Wei,HUANG Wei. Progress of Electrode Designs for Flexible Energy Storage Devices. Materials Reports, 2020, 34(1): 1177-1186.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.19110021 或 http://www.mater-rep.com/CN/Y2020/V34/I1/1177

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