CeO2掺杂Si-B复合涂层的制备及氧化行为

doi:10.11896/cldb.19070218

材料导报

2020, Vol. 34

Issue (18): 18035-18038 https://doi.org/10.11896/cldb.19070218

机非金属及其复合材料

CeO₂掺杂Si-B复合涂层的制备及氧化行为

张勇^1,2,3, 张耿飞¹, 张宇涛¹, 宁璠¹, 晁奕¹, 冯鹏发³

1 长安大学材料科学与工程学院,西安 710064
2 长安大学机械工程博士后科研流动站,西安 710064
3 金堆城钼业股份有限公司技术中心,西安 710077

Preparation and Oxidation Behavior of CeO₂ Doped Si-B Composite Coatings

ZHANG Yong^1,2,3, ZHANG Gengfei¹, ZHANG Yutao¹, NING Fan¹, CHAO Yi¹, FENG Pengfa³

1 School of Material Science and Engineering, Chang'an University, Xi'an 710064, China
2 Postdoctoral Scientific Research Station of Mechanical Engineering, Chang'an University, Xi'an 710064, China
3 Technical Center, Jinduicheng Molybdenum Co., Ltd., Xi'an 710077, China

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摘要采用两步包埋渗的方法在钼基体表面制备了不同CeO₂掺杂量的Si-B复合涂层,通过XRD、EDS和SEM分析了CeO₂掺杂对Si-B复合涂层在1 150℃氧化前后表面物相和截面形貌的影响,并采用失重法研究了CeO₂掺杂前后Si-B复合涂层在1 150℃下氧化160 h的氧化动力学行为。结果表明:适量CeO₂的掺杂对Si具有一定的催渗效果,当CeO₂掺杂量为1%(质量分数)时,所制备的Si-B复合涂层的厚度最大且均匀致密,但随着CeO₂掺杂量的增加,涂层厚度有所减小。CeO₂掺杂Si-B复合涂层在1 150℃下氧化前70 h的氧化速率常数值(1.48×10^-4 mg²/(cm⁴·h))较未掺杂时明显降低,这表明CeO₂掺杂Si-B复合涂层的高温抗氧化性能较好。

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	张勇
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关键词: 钼两步包埋渗 Si-B复合涂层 CeO₂掺杂

Abstract: The Si-B composite coatings with different doping amount of CeO₂ were prepared on the surface of molybdenum substrate by two-step pack cementation methods. The effect of CeO₂ doping on phase structure and cross-section morphology of Si-B composite coatings before and after oxidation at 1 150℃ were analyzed by XRD, EDS and SEM. The oxidation kinetics of Si-B composite coatings before and after CeO₂ doping oxidized at 1 150℃ for 160 h were studied by mass-loss method. The results showed that appropriate doping amount of CeO₂ had certain per-meation effect on Si element in pack cementation process. The Si-B composite coatings with thick, uniform and dense structure were obtained when the doping amount of CeO₂ was fixed at 1wt%. However, the thickness of Si-B composite coatings decreased with the further increase of CeO₂ doping amount. The oxidation rate constant (1.48×10^-4 mg²/(cm⁴·h))of the doped Si-B composite coating oxidized at 1 150℃ for 70 h was significantly lower than that without CeO₂ doping, which indicated that the Si-B composite coating doped with CeO₂ has better high temperature oxidation resistance.

Key words: molybdenum two-step pack cementation Si-B composite coating CeO₂ doping

发布日期: 2020-09-12

ZTFLH:

TG174.44

基金资助: 陕西省科技计划(2020GY-278;2020ZDLGY12-07);中央高校基本科研业务费专项资金(300102318206);国家自然科学基金 (51301023);国家级大学生创新创业训练计划(201910710152)

通讯作者: chdzhangyong@chd.edu.cn

作者简介: 张勇,2012年7月毕业于中南大学,获工学博士学位。现为长安大学材料学院副教授。主要研究方向为金属表面先进陶瓷涂层材料的制备与表征,在该领域共计发表学术论文30余篇,申请发明专利5项,先后主持10余项包括国家自然科学基金项目、陕西省自然科学基金项目、国家重点实验室开放课题项目等在内的国家级、省部级、校企合作项目等。

引用本文:

张勇, 张耿飞, 张宇涛, 宁璠, 晁奕, 冯鹏发. CeO₂掺杂Si-B复合涂层的制备及氧化行为[J]. 材料导报, 2020, 34(18): 18035-18038.
ZHANG Yong, ZHANG Gengfei, ZHANG Yutao, NING Fan, CHAO Yi, FENG Pengfa. Preparation and Oxidation Behavior of CeO₂ Doped Si-B Composite Coatings. Materials Reports, 2020, 34(18): 18035-18038.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.19070218 或 http://www.mater-rep.com/CN/Y2020/V34/I18/18035

1 Xing K Y, Wang X, Li Z X, et al. Materials Protection, 2018, 51(12), 111(in Chinese).
邢开源, 汪欣, 李争显, 等. 材料保护, 2018, 51(12), 111.
2 Modec B, Košmrlj J. Inorganica Chimica Acta, 2019, 486, 766.
3 Niu F, Wang Y, Abbas I, et al. Ceramics International, 2017, 43(3), 3238.
4 Zhang Y, Wang X Y, Yu J, et al. Materials Reports A: Review Papers, 2017, 31(3), 83(in Chinese).
张勇, 王雄禹, 于静, 等. 材料导报:综述篇, 2017, 31(3), 83.
5 Yang K M, Wang J X, Yang S Y, et al. Surface and Coatings Technology, 2018, 354, 324.
6 Sun J, Li T, Zhang G P. Corrosion Science, 2019, 155, 146.
7 Riedl H, Vieweg A, Limbeck A, et al. Surface & Coatings Technology, 2015, 280, 282.
8 Sun R, Wang K S, Hu P,et al. Materials Reports A: Review Papers, 2016, 30(3),69(in Chinese).
宋瑞, 王快社, 胡平, 等. 材料导报:综述篇, 2016, 30(3),69.
9 Jiang J, Zhou T, Shao W, et al. Journal of Alloys and Compounds, 2019, 786, 920.
10 Sahu J N, Sasikumar C. Journal of Materials Processing Technology, 2019, 263, 285.
11 Jonnalagadda K P, Eriksson R, Li X H, et al. Journal of the European Ceramic Society, 2019, 39(5),1869.
12 Boissonnet G, Bonnet G, Pasquet A, et al. Journal of the European Ceramic Society, 2019. 39(6), 2111.
13 Sun J, Fu Q G, Guo L P, et al. Materials & Design, 2016, 92, 602.
14 Zhang P, Guo X, Zhang C, et al. International Journal of Refractory Metals & Hard Materials, 2017, 67, 32.
15 Dai L, Yu Y, Zhou H, et al. Ceramics International, 2015, 41(10), 13663.
16 Xiao L R, Zhang B, Cai Z Y, et al. Rare Metal Materials and Enginee-ring, 2018, 47(11), 141(in Chinese).
肖来荣, 张贝, 蔡圳阳, 等. 稀有金属材料与工程, 2018, 47(11), 141.
17 Kuznetsov S A, Rebrov E V, Mies M J M, et al. Surface and Coatings Technology, 2006, 201(3-4), 971.
18 Lange A, Heilmaier M, Sossamann T A, et al. Surface & Coatings Technology, 2015, 266, 57.
19 Wang Y, Yan J, Wang D. International Journal of Refractory Metals & Hard Materials, 2017, 68,60.
20 Tian X, Guo X, Sun Z, et al. Journal of Rare Earths, 2016, 34(9),952.
21 Ning F, Zhang Y, Wang X Y, et al. Hot Working Technology, 2019, 48(4), 141(in Chinese).
宁璠, 张勇, 王雄禹, 等. 热加工工艺, 2019, 48(4), 141.
22 Castano C E, O'Keefe M J, Fahrenholtz W G. Current Opinion in Solid State and Materials Science, 2015, 19(2),69.
23 Wang X Y, Zhang Y, Zhi L, et al. Hot Working Technology, 2018, 47(6),161(in Chinese).
王雄禹, 张勇, 支龙, 等. 热加工工艺, 2018, 47(6),161.
24 Zhu L C, Tang G B, Shi Q, et al. Chinese Journal of Applied Chemistry, 2005, 22(7), 715(in Chinese).
朱连超, 唐功本, 石强, 等. 应用化学, 2005, 22(7), 715.
25 Wang Y, Wang D Z, Yan J H. Journal of Alloys and Compounds, 2014, 589(9), 384.
26 Wang Y. Preparation and properties of Mo-based alloys oxidation resis-tance coatings at elevated temperature.Ph.D. Thesis, Central South University, China, 2014(in Chinese).
汪异. 钼基合金高温抗氧化涂层的制备及其性能研究. 博士学位论文, 中南大学, 2014.
27 Ouyang G Y, Ray P K, Thimmaiah S. Applied Surface Science, 2019, 470, 289.
28 Alam M Z, Venkataraman B, Sarma B, et al. Journal of Alloys and Compounds, 2009, 487(1-2), 335.
29 Yoon J, Kim G, Byun J, et al. Surface & Coatings Technology, 2001, 148(2), 129.
30 Li M S. High temperature corrosion of metals, Metallurgical Industry Press, China, 2001(in Chinese).
李美栓. 金属的高温腐蚀, 冶金工业出版社, 2001.

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[14]	程亮, 张鹏程. 典型事故容错轻水堆燃料包壳候选材料SiC_f/SiC复合材料和Mo合金的研究进展[J]. 材料导报, 2018, 32(13): 2161-2166.
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