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材料导报  2020, Vol. 34 Issue (6): 6156-6160    https://doi.org/10.11896/cldb.19010178
  高分子与聚合物基复合材料 |
磁场作用下十二烷基苯磺酸钠对阳极铝箔的缓蚀性能及比电容的影响
赵静, 王天鹏, 张淮浩
扬州大学化学化工学院,扬州 225002
Effect of SDBS Coupled with Magnetic Field on Corrosion Inhibition Performance and Specific Capacitance of Anodic Aluminum Foil
ZHAO Jing, WANG Tianpeng, ZHANG Huaihao
College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
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摘要 以十二烷基苯磺酸钠(SDBS)为缓蚀剂,通过在扩面增容过程中引入磁场,系统研究了磁致涡流(MHD,Magnetohydrodynamics)效应对腐蚀箔缓蚀性能及比电容的影响规律。通过XRD、扫描电镜(SEM)、EDS、Tafel极化曲线以及交流阻抗曲线等手段对腐蚀箔的表面晶相、表面/截面形貌、S元素分布以及耐蚀性能进行研究。结果表明,MHD效应提高了电解液中DBS-、NO3-向箔面及孔内的传质速率,腐蚀箔表面SDBS吸附量及分布均一性提高,腐蚀箔失重降低,耐蚀性能增强;同时蚀孔内NO3-含量增加,平均蚀孔长度及比表面积增大。对应的腐蚀箔缓蚀效率提高至62.36%,比电容增大至65.39μF·cm-2。与无MHD作用下制备的腐蚀箔相比,MHDT作用下所得腐蚀箔的缓释效率及比电容分别提高了15.10%和10.03%。
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赵静
王天鹏
张淮浩
关键词:  缓蚀剂  磁场  耐蚀性能  比电容    
Abstract: By introducing magnetic field into the extending surface area process, combined with SDBS as corrosion inhibitor, the effect of magnetohydrodynamics (MHD) on corrosion inhibition performance and specific capacitance of etched foils is studied in detail. The crystalline phase, the surface/cross-section morphology, distribution of S element and corrosion resistance quality of samples were characterized and analyzed by means of XRD, SEM, EDS, Tafel curve and EIS (electrochemical impedance spectra). The results show that MHD effect increases the mass transfer rate of DBS-/NO3- to the etched foil surface/hole in electrolyte, the surface adsorption capacity and distribution uniformity of SDBS. Meanwhile, the NO3- content in etched hole, the average hole depth and specific surface area are also obviously improved. The corrosion inhibition efficiency of the optimal foil sample increases up to 62.36% as well as the high specific capacitance 65.39 μF·cm-2. Compared to the etched foil without MHD, its corrosion inhibition efficiency increases by 15.10%, accompanying by 10.03% increment of specific capacitance.
Key words:  corrosion inhibitor    magnetic field    corrosion resistance    specific capacitance
                    发布日期:  2020-03-12
ZTFLH:  TG172.8  
基金资助: 江苏高校优势学科建设工程资助项目(PAPD);江苏高校品牌专业建设一期工程资助项目(TAPP,PPZY2015B112);山东省自然科学基金(ZR2017MEM019)
作者简介:  赵静,实验师。研究方向为电化学储能;张淮浩,教授,博士研究生导师。研究方向为电化学储能。
引用本文:    
赵静, 王天鹏, 张淮浩. 磁场作用下十二烷基苯磺酸钠对阳极铝箔的缓蚀性能及比电容的影响[J]. 材料导报, 2020, 34(6): 6156-6160.
ZHAO Jing, WANG Tianpeng, ZHANG Huaihao. Effect of SDBS Coupled with Magnetic Field on Corrosion Inhibition Performance and Specific Capacitance of Anodic Aluminum Foil. Materials Reports, 2020, 34(6): 6156-6160.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19010178  或          http://www.mater-rep.com/CN/Y2020/V34/I6/6156
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