Please wait a minute...
《材料导报》期刊社  2017, Vol. 31 Issue (4): 30-35    https://doi.org/10.11896/j.issn.1005-023X.2017.04.008
  材料研究 |
基于四羟甲基甘脲前驱体的新型含氮富微孔活性炭制备及其性能研究
黄凯兵, 杨秀文, 王智健, 姚异渊
湖南大学材料科学与工程学院, 长沙 410082
Study on Synthesis and Electrochemical Behavior of New Nitrogen-enriched
Microporous Carbon Based on Tetramethylol Acetylenediurea
HUANG Kaibing, YANG Xiuwen, WANG Zhijian, YAO Yiyuan
College of Material Science and Engineering, Hunan University, Changsha 410082
下载:  全 文 ( PDF ) ( 1719KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 以四羟甲基甘脲为碳前驱体,采用KOH活化法处理得到双电层电容器用多孔活性炭材料。考察了不同碳化、活化温度对活性炭比电容的影响。结果表明,在850 ℃碳化,650 ℃活化处理时其电容性能最好,SEM和比表面与孔径分布测试说明TA-850-650表面富集微孔;恒流充放电与循环伏安测试结果表明TA-850-650的比电容在电流密度为0.2 A/g时可达527 F/g。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
黄凯兵
杨秀文
王智健
姚异渊
关键词:  四羟甲基甘脲  双电层电容器  活化温度  微孔  比电容    
Abstract: The porous carbon, prepared from tetramethylol acetylenediurea by activation of KOH, were applied in electric double-layer capacitor (EDLC). The carbonization and activated temperature had a significant influence both on porosity structure and electrochemical performances. Results showed that the micropores enriched on the surface of TA-850-650.The specific capacitance of TA-850-650 could reach 527 F/g at 0.2 A/g.
Key words:  tetramethylol acetylenediurea    electric double-layer capacitor (EDLC)    activated temperature    micro-porosity    specific capacitance
               出版日期:  2017-02-25      发布日期:  2018-05-02
ZTFLH:  TM53  
作者简介:  黄凯兵:男,1966年生,硕士,副教授,主要研究方向为功能高分子材料 E-mail:Huangkaibing8888@163.com
引用本文:    
黄凯兵, 杨秀文, 王智健, 姚异渊. 基于四羟甲基甘脲前驱体的新型含氮富微孔活性炭制备及其性能研究[J]. 《材料导报》期刊社, 2017, 31(4): 30-35.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.04.008  或          http://www.mater-rep.com/CN/Y2017/V31/I4/30
1 Lu M, Beguin F, Frackowiak E. Supercapacitors: Materials, systems and applications [M]. John Wiley & Sons,2013.
2 Arbizzani C, Mastragostino M, Soavi F. New trends in electroche-mical supercapacitors [J].J Power Sources,2001,100(1):164.
3 Nomoto S, Nakate H,Yoshika K,et al. Advanced capacitors and their application [J].J Power Sources,2001,97:807.
4 Tian Yanhong,Fu Xutao,Wu Borong.Development of porous carbon materials for electric double-layer capacitor[J].Chin J Power Sources,2002,26(6):466(in Chinese).
田艳红,付旭涛,吴伯荣. 超级电容器用多孔碳材料的研究进展[J].电源技术,2002,26(6):466.
5 Li W, Chen D,Li Z,et al. Nitrogen-containing carbon spheres with very large uniform mesopores: The superior electrode materials for EDLC in organic electrolyte [J].Carbon,2007,45(9):1757.
6 Zhao L, Fan L Z,Zhou M Q,et al. Nitrogen-containing hydrothermal carbons with superior performance in supercapacitors [J].Adv Mater,2010,22(45):5202.
7 Brousse T, Toupin M, Belanger D. A hybrid activated carbon-manganese dioxide capacitor using a mild aqueous electrolyte [J].J Electrochem Soc,2004,151(4):A614.
8 Geng Xin,Li Lixiang,An Baigang,et al.Influence of activated temperature on electrochemical behavior of activated carbon based on phenol resin for supercapcitors[J].Electron Compon Mater,2013,32(5):30(in Chinese).
耿新,李莉香,安百刚,等. 活化温度对超级电容器用酚醛树脂基活性炭电化学性能的影响[J].电子元件与材料,2013,32(5):30.
9 Yang X, et al. Activated nitrogen-doped carbon nanofibers with hierarchical pore as efficient oxygen reduction reaction catalyst for microbial fuel cells [J].J Power Sources,2014,266:36.
10 藤岛昭,陈震,姚建年. 电化学测定方法[M]. 北京:北京大学出版社,1995.
11 Ma C, Song Y,Shi J,et al. Preparation and one-step activation of microporous carbon nanofibers for use as supercapacitor electrodes [J].Carbon,2013,51:290.
12 Chen C M,Zhang Q,Huang C H,et al. Macroporous ‘bubble’graphene film via template-directed ordered-assembly for high rate supercapacitors [J].Chem Commun,2012,48(57):7149.
[1] 刘明, 徐洪峰, 周亚男, 郝宇. 金属有机框架化合物Zn4O(BDC)3材料的制备、结构及电容性能[J]. 材料导报, 2019, 33(12): 1955-1958.
[2] 王明, 李星. 超临界二氧化碳技术制备的聚丙烯/三元乙丙橡胶开孔发泡材料的吸油行为[J]. 《材料导报》期刊社, 2018, 32(8): 1236-1240.
[3] 应建行, 刘智峰, 贺登峰, 陈忠仁. LLDPE/EPDM共混物的超临界CO2微孔发泡研究[J]. 《材料导报》期刊社, 2018, 32(4): 616-620.
[4] 鲁云华, 郝继璨, 李琳, 宋晶, 肖国勇, 胡知之, 王同华. 自具微孔聚合物PIM-1基热致刚性膜材料的制备及气体分离性能[J]. 材料导报, 2018, 32(16): 2876-2881.
[5] 葛胜涛, 邓先功, 毕玉保, 王军凯, 李赛赛, 韩磊, 张海军. 多级孔材料研究进展[J]. 《材料导报》期刊社, 2018, 32(13): 2195-2201.
[6] 李祥,郑峰,罗援,罗泳梅. 超级电容器活性炭/MnO2复合电极材料的制备及性能[J]. 《材料导报》期刊社, 2018, 32(12): 1949-1954.
[7] 张鸿宇,李治应,曾蓉,. 高效温和制备纳米片状β-Co(OH)2用于超级电容器电极[J]. 材料导报编辑部, 2017, 31(22): 15-20.
[8] 宋晓岚, 刘汉俊, 王海波, 段海龙, 张颖, 刘时超, 周永鑫, 周志海. 预活化时间对稻壳基活性炭结构和电化学性能的影响*[J]. 《材料导报》期刊社, 2017, 31(20): 25-29.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed