电解液配方对纯镁微弧氧化膜层耐蚀性的影响

doi:10.11896/cldb.21100085

材料导报

2023, Vol. 37

Issue (15): 21100085-10 https://doi.org/10.11896/cldb.21100085

金属与金属基复合材料

电解液配方对纯镁微弧氧化膜层耐蚀性的影响

王占营, 马颖^*, 安守静, 孙乐

兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室,兰州 730050

Effect of Electrolyte Formulation on the Corrosion Resistance of Micro-arc Oxidation Coating of Pure Magnesium

WANG Zhanying, MA Ying^*, AN Shoujing, SUN Le

State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China

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摘要基于单纯形重心设计改变Na₂SiO₃、NaOH、KF和NaAlO₂四种组分的搭配,在纯镁基体上制备微弧氧化膜层,研究了电解液各组分及其搭配对膜层耐蚀性能的影响。结果表明,拟合得到的回归方程的显著性较好,预测精度高。通过标准化回归系数及帕累托分析可知,KF对膜层点滴及电化学耐蚀性的影响均较大。由响应面分析可知,KF有助于膜层点滴耐蚀性的提高,但高浓度的KF反而不利于电化学耐蚀性的提升。主盐Na₂SiO₃和NaAlO₂可以明显提高膜层的电化学耐蚀性。膜层点滴耐蚀性与电化学耐蚀性的腐蚀机制不同是导致电解质对二者的影响有所区别的根本原因。

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关键词: 纯镁微弧氧化电解液单纯形重心设计回归分析

Abstract: Based on simplex-centroid mixture design, micro-arc oxidation coatings were prepared on pure magnesium by changing the collocation of Na₂SiO₃, NaOH, KF and NaAlO₂. The effects of electrolyte composition on the corrosion resistance of the coating were studied. The results show that the regression equations are very significant and the prediction accuracy is high. According to the standardized regression coefficient and Pareto analysis, KF has a great influence on the corrosion resistance corresponding to spot test and electrochemical of the coating. The response surface analysis shows that KF can improve the dropping corrosion resistance of the coating. However, high concentration of KF is not conducive to the improvement of electrochemical corrosion resistance. The main salt Na₂SiO₃ and NaAlO₂ can obviously improve the electrochemical corrosion resistance of the coating. It can be seen that the difference in the corrosion mechanism between the spotting and electrochemical corrosion resistance is the primary reason for the difference in the effect of the electrolytes on the two indicators.

Key words: pure magnesium micro-arc oxidation electrolyte simplex-centroid mixture design regression analysis

出版日期: 2023-08-10 发布日期: 2023-08-07

ZTFLH:

TG174.45

基金资助: 甘肃省创新研究群体计划(1111RJDA011)

通讯作者: * 马颖,兰州理工大学材料科学与工程学院教授、博士研究生导师。1987年重庆大学本科毕业,1997年甘肃工业大学研究生毕业。1997.9—1999.2新西兰Waikato大学学习,2001.3—2001.6日本JICA项目研修,2005.2—2006.8新西兰Auckland大学访问学者。2009年入选国家新世纪百千万人才工程,2010年入选甘肃省领军人才第一层次,2012年成为国务院政府特殊津贴获得者。主要从事有色金属表面改性与防护、新材料研发和先进成形的科研及应用推广工作。主持并参加近30项国家和省部级科研项目,获省部级科技奖4项,授权发明专利7项。发表论文近100篇,其中40余篇被SCI、EI收录。maying@lut.cn

作者简介: 王占营,2012年6月毕业于兰州理工大学,获得工学学士学位。现为兰州理工大学材料科学与工程学院博士研究生,在马颖教授的指导下进行研究。目前主要研究领域为轻金属表面改性。

引用本文:

王占营, 马颖, 安守静, 孙乐. 电解液配方对纯镁微弧氧化膜层耐蚀性的影响[J]. 材料导报, 2023, 37(15): 21100085-10.
WANG Zhanying, MA Ying, AN Shoujing, SUN Le. Effect of Electrolyte Formulation on the Corrosion Resistance of Micro-arc Oxidation Coating of Pure Magnesium. Materials Reports, 2023, 37(15): 21100085-10.

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http://www.mater-rep.com/CN/10.11896/cldb.21100085 或 http://www.mater-rep.com/CN/Y2023/V37/I15/21100085

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