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《材料导报》期刊社  2018, Vol. 32 Issue (8): 1294-1299    https://doi.org/10.11896/j.issn.1005-023X.2018.08.017
  材料研究 |
纳米TiO2微粒对2214铝合金微弧氧化膜微观结构及耐磨性能的影响
李振伟, 狄士春
哈尔滨工业大学机电工程学院,哈尔滨 150001
Influence of Nano TiO2 Particles on Microstructure and Wear Resistance of Microarc Oxidation Coatings on 2214 Aluminum Alloy
LI Zhenwei, DI Shichun
School of Mechatronics Engineering, Harbin Institute of Technology, Harbin 150001
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摘要 在含有不同浓度纳米TiO2 微粒的硅酸盐体系电解液中对2214铝合金进行微弧氧化处理,以在2214铝合金表面制备包含TiO2的复合陶瓷膜。分别使用SEM、EDS、激光共聚焦显微镜、XRD、维氏硬度计、划痕仪和球盘式摩擦磨损试验机对复合陶瓷膜的微观结构、表面粗糙度、相成分、硬度、粘结强度、耐磨性能进行分析。结果表明:复合陶瓷膜主要由γ-Al2O3、α-Al2O3、莫来石、锐钛矿型TiO2和金红石型TiO2组成,且随着电解液中TiO2 微粒浓度的增加,复合陶瓷膜表面的微孔数量显著减少,微孔尺寸显著减小。与不含TiO2成分的微弧氧化陶瓷膜相比,复合陶瓷膜通过更低的摩擦系数和更小的磨损率展示了更好的耐磨性能。
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李振伟
狄士春
关键词:  2214铝合金  微弧氧化  纳米TiO2微粒  粘结强度  耐磨性能    
Abstract: 2214 aluminum alloy was treated by micro-arc oxidation in the silicate system electrolyte with different concentrations of nano TiO2 particles and the MAO composite coatings containing TiO2 were prepared on 2214 aluminum alloy. The microstructure, surface roughness, phase composition, hardness, adhesion strength and wear resistance of MAO composite coatings were analyzed by SEM, EDS, laser confocal microscope, XRD, Vickers hardness tester, scratch tester and ball-on-disc abrasive tester, respectively. The results revealed that the MAO composite coatings were mainly composed of γ-Al2O3, α-Al2O3, mullite, anatase-TiO2 and rutile-TiO2. With the increasing content of TiO2 microparticles in the electrolyte, the size and number of pores on MAO composite coatings surface decreased significantly. Compared to the MAO coatings without TiO2, the MAO composite coatings exhibited better wear resistance as demonstrated by the lower friction coefficient and the lower wear rate.
Key words:  2214 aluminum alloy    micro-arc oxidation    nano TiO2 particles    adhesion strength    wear resistance
               出版日期:  2018-04-25      发布日期:  2018-05-11
ZTFLH:  TG174.451  
通讯作者:  狄士春:通信作者,男,1965年生,教授,主要从事金属表面改性研究 E-mail:dishichun@126.com   
作者简介:  李振伟:男,1986年生,博士研究生,主要从事金属表面改性研究 E-mail:lizhenwei20071212@163.com
引用本文:    
李振伟, 狄士春. 纳米TiO2微粒对2214铝合金微弧氧化膜微观结构及耐磨性能的影响[J]. 《材料导报》期刊社, 2018, 32(8): 1294-1299.
LI Zhenwei, DI Shichun. Influence of Nano TiO2 Particles on Microstructure and Wear Resistance of Microarc Oxidation Coatings on 2214 Aluminum Alloy. Materials Reports, 2018, 32(8): 1294-1299.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.08.017  或          http://www.mater-rep.com/CN/Y2018/V32/I8/1294
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